无机枪击残留物的转移、持久性、污染和背景水平

IF 2.6 3区 医学 Q2 CHEMISTRY, ANALYTICAL Forensic Chemistry Pub Date : 2024-04-09 DOI:10.1016/j.forc.2024.100577
Jonas Malmborg , Magnus Larsson , Lars Jaeger , Anders Nordgaard
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引用次数: 0

摘要

本文总结了有关无机枪弹残留物 (IGSR) 转移(196 项实验)、持久性(63 个时间序列)、污染(1515 个样本)和背景流行率(2158 个样本)等证据评估主题的现有文献数据。我们还提供了有关 IGSR 转移以及 IGSR 在不同类型手套上的流行率和持久性的内部数据:IGSR 转移率的中位数为 11%,接触转移的概率分布采用 Beta 分布模型。IGSR 在手上的半衰期估计为 52 分钟。手套上的衰减过程分为两个阶段,与手部相比,衰减速度较慢(t1/2,slow = 77 分钟)。使用广义帕累托模型 (GPM) 模拟了警官手部发生特征性 IGSR 的情况。结合患病率和转移概率模型,建立了一个乘积概率分布模型。乘积模型估计了逮捕后在之前干净的手上发现任何数量 IGSR 的概率,估计非零转移概率为 8%。在普通公众(阳性率为 1%)、高危人群(阳性率为 2%)和公共场所(阳性率为 0%)中检测到的特征 IGSR 本底水平较低。在普通公众(包括高危人群)身上发现任何数量 IGSR 的可能性是通过 GPM 模拟得出的,在普通公众身上发现至少一种 IGSR 的可能性为 1.3%,发现三种以上特征 IGSR 的可能性为 0.2%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Transfer, persistence, contamination and background levels of inorganic gunshot residues

This paper summarises the available literature data for the evidential evaluation topics of transfer (196 experiments), persistence (63 time series), contamination (1515 samples), and background prevalence (2158 samples) of inorganic gunshot residues (IGSR). In-house data on IGSR transfer, and the prevalence and persistence of IGSR on different types of glove are also contributed.

Combining new and previously published data in a meta-analysis, we report the following findings: The median transfer rate of IGSR was 11 % and the probability distribution of contact transfer was modelled using a Beta distribution. The half-life of IGSR on hands was estimated at 52 min. On gloves, decay followed a two-phase process with the slower process proceeding at a decreased rate compared to on hands (t1/2,slow = 77 min). The occurrence of characteristic IGSR on the hands of police officers was modelled using a generalised Pareto model (GPM). Combining the prevalence and the transfer probability models, a product probability distribution model was established. The product model estimates the probability of finding any amount of IGSR post-arrest on previously clean hands, estimating 8 % probability of non-zero transfer. Characteristic IGSR detected on the general public (1 % positives), on at-risk individuals (2 % positives), and in public places (0 % positives) showed low background levels. The likelihood of finding any amount of IGSR on the general public (at-risk included) was modelled using a GPM giving a 1.3 % probability of finding at least one, and 0.2 % probability to find more than three characteristic IGSR on the general public.

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来源期刊
Forensic Chemistry
Forensic Chemistry CHEMISTRY, ANALYTICAL-
CiteScore
5.70
自引率
14.80%
发文量
65
审稿时长
46 days
期刊介绍: Forensic Chemistry publishes high quality manuscripts focusing on the theory, research and application of any chemical science to forensic analysis. The scope of the journal includes fundamental advancements that result in a better understanding of the evidentiary significance derived from the physical and chemical analysis of materials. The scope of Forensic Chemistry will also include the application and or development of any molecular and atomic spectrochemical technique, electrochemical techniques, sensors, surface characterization techniques, mass spectrometry, nuclear magnetic resonance, chemometrics and statistics, and separation sciences (e.g. chromatography) that provide insight into the forensic analysis of materials. Evidential topics of interest to the journal include, but are not limited to, fingerprint analysis, drug analysis, ignitable liquid residue analysis, explosives detection and analysis, the characterization and comparison of trace evidence (glass, fibers, paints and polymers, tapes, soils and other materials), ink and paper analysis, gunshot residue analysis, synthetic pathways for drugs, toxicology and the analysis and chemistry associated with the components of fingermarks. The journal is particularly interested in receiving manuscripts that report advances in the forensic interpretation of chemical evidence. Technology Readiness Level: When submitting an article to Forensic Chemistry, all authors will be asked to self-assign a Technology Readiness Level (TRL) to their article. The purpose of the TRL system is to help readers understand the level of maturity of an idea or method, to help track the evolution of readiness of a given technique or method, and to help filter published articles by the expected ease of implementation in an operation setting within a crime lab.
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