从独居石中提取稀土元素的环境友好型加工路线的技术经济评估

IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Cleaner Engineering and Technology Pub Date : 2024-04-08 DOI:10.1016/j.clet.2024.100742
Reiza Z. Mukhlis , Jin-Young Lee , Hee Nam Kang , Nawshad Haque , Mark I. Pownceby , Warren J. Bruckard , M. Akbar Rhamdhani , Rajesh Kumar Jyothi
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引用次数: 0

摘要

在从独居石中提取稀土元素的过程中,如果不加处理,独居石中相对较高的钍和铀浓度会造成严重的环境问题。本文根据对韩国独居石样品的分析和处理,提出了一种以氧化物形式回收钍和铀的新工艺路线,并对其经济可行性进行了分析。此外,还与现有的酸性和碱性路线进行了比较评估。据估计,新工艺运营成本的最大部分与材料和试剂成本有关。敏感性分析预测,氧化钕的价值对收入的影响很大,其次是重稀土氧化物(HREO)和氧化镨。将全部稀土氧化物的平均篮子价格提高 1.5 倍,将使拟议路线的收入达到 1.588 亿美元/年,而碱性和酸性路线的收入分别为 1.615 亿美元/年和 1.563 亿美元/年。贴现现金流分析和得出的净现值(NPV)表明,拟议的加工路线实际上是唯一经济上可行的工艺,投资回收期预计约为 4.5 年。拟议路线的氧化钍和氧化铀副产品的销售为正贴现净现值做出了贡献。另据估计,要确保所有工艺都能产生正贴现净现值,最低销售价格必须达到 20 美元/千克稀土氧化物总量。这些结果表明,拟议的新加工路线估计在经济上是可行的。
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Techno-economic evaluation of an environmental-friendly processing route to extract rare earth elements from monazite

The relatively high concentration of thorium and uranium in monazite poses significant environmental issues in the extraction process of rare earth elements from monazite if left untreated. A new process route that recovers both thorium and uranium as oxides has been proposed, and an analysis of its economic feasibility is presented in the current paper, based on analysis and processing of a Korean monazite sample. Comparative evaluations with existing acidic and alkaline routes have also been carried out. It was estimated that the largest proportion of the operational cost for the new process related to the materials and reagent costs. Sensitivity analysis predicted that the value of neodymium oxide followed by Heavy Rare Earth Oxides (HREO) and praseodymium oxide affect the revenue significantly. Increasing the average basket price of the total rare earths oxide by 1.5 times would result in revenues of US$158.8 million/year for the proposed route, compared to US$161.5 and US$156.3 million/year for the alkaline and acidic routes, respectively. The discounted cash flow analysis and the resulted Net Present Value (NPV) suggested that the proposed processing route was in fact the only process estimated to be economically feasible with the payback period expected to be around 4.5 years. The sale of thorium oxide and uranium oxide by-products of the proposed route contributed to the positive discounted NPV. It was also estimated that a minimum sale price of US$20/kg total rare earth oxide is required to ensure all the processes generate a positive discounted NPV. These results shown that the proposed new processing route is estimated to be economically feasible.

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来源期刊
Cleaner Engineering and Technology
Cleaner Engineering and Technology Engineering-Engineering (miscellaneous)
CiteScore
9.80
自引率
0.00%
发文量
218
审稿时长
21 weeks
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