评估安全头盔用高密度聚乙烯复合材料中热固性聚合物废料的回收潜力

IF 3.2 3区 化学 Q2 POLYMER SCIENCE e-Polymers Pub Date : 2024-04-04 DOI:10.1515/epoly-2023-0080
Diwahar Periasamy, Prakalathan Karuppiah, Bharathi Manoharan, Felix Sahayaraj Arockiasamy, Sathish Kannan, Vinayagam Mohanavel, Palanivel Velmurugan, Natarajan Arumugam, Abdulrahman I. Almansour, Subpiramaniyam Sivakumar
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引用次数: 0

摘要

热固性聚合物需求的不断增长导致产生了大量的工业废物。废物填埋带来的环境问题以及新产品开发所需的原材料成本增加,促使人们开发创新的回收方法。本研究的重点是通过在高密度聚乙烯(HDPE)基体中添加热固性聚合物废料(TPW)作为填料,开发一种产品(头盔外壳)。使用双螺杆挤压机将高密度聚乙烯和 TPW 转化为挤出物。然后,将挤出物造粒,用作注塑机的原材料。高密度聚乙烯/热塑性硫化弹性体复合材料是用注射成型法制造的。马来酸酐接枝聚乙烯被用作相容剂。在复合材料中,TPW 体积以不同的重量百分比被增强,从 0 到 35 wt%。通过在高密度聚乙烯基体中均匀分散 TPW,可以增强复合材料的机械、热和粘弹性能。然而,由于团聚效应,在 TPW 体积较大时很难实现均匀分散。根据这些研究结果,TPW 的添加量最高可达 30 wt%,从而提高了机械性能。研究结果表明,所提议的复合材料具有足够的机械性能,适合用于头盔外壳的制造。
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Assessing the recycling potential of thermosetting polymer waste in high-density polyethylene composites for safety helmet applications
The rising demand for thermosetting polymers has resulted in the production of large amounts of industrial waste. Environmental issues due to waste landfills and increased raw material costs for new product development have led to the development of innovative recycling methods. This study focuses on the development of a product (helmet shell) by reinforcing thermosetting polymer waste (TPW) as a filler in a high-density polyethylene (HDPE) matrix. The HDPE and TPW were converted into extrudates using a twin-screw extruder. Then, the extrudate was pelletized to use as raw material for the injection molding machine. The HDPE/TPW composites were fabricated using injection molding. Maleic anhydride-grafted polyethylene was employed as a compatibilizer. In the composite, the TPW volume was reinforced at various weight percentages, ranging from 0 to 35 wt%. The mechanical, thermal, and viscoelastic properties of the composites can be enhanced by uniformly dispersing TPW in the HDPE matrix. However, it is difficult to achieve uniform dispersion at higher TPW volumes owing to the agglomeration effect. According to these findings, the mechanical properties were enhanced by up to 30 wt% addition of TPW. The findings suggest that the proposed composite has sufficient mechanical properties to be suitable for the fabrication of helmet shells.
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来源期刊
e-Polymers
e-Polymers 化学-高分子科学
CiteScore
5.90
自引率
10.80%
发文量
64
审稿时长
6.4 months
期刊介绍: e-Polymers is a strictly peer-reviewed scientific journal. The aim of e-Polymers is to publish pure and applied polymer-science-related original research articles, reviews, and feature articles. It includes synthetic methodologies, characterization, and processing techniques for polymer materials. Reports on interdisciplinary polymer science and on applications of polymers in all areas are welcome. The present Editors-in-Chief would like to thank the authors, the reviewers, the editorial staff, the advisory board, and the supporting organization that made e-Polymers a successful and sustainable scientific journal of the polymer community. The Editors of e-Polymers feel very much engaged to provide best publishing services at the highest possible level.
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