{"title":"评估安全头盔用高密度聚乙烯复合材料中热固性聚合物废料的回收潜力","authors":"Diwahar Periasamy, Prakalathan Karuppiah, Bharathi Manoharan, Felix Sahayaraj Arockiasamy, Sathish Kannan, Vinayagam Mohanavel, Palanivel Velmurugan, Natarajan Arumugam, Abdulrahman I. Almansour, Subpiramaniyam Sivakumar","doi":"10.1515/epoly-2023-0080","DOIUrl":null,"url":null,"abstract":"The rising demand for thermosetting polymers has resulted in the production of large amounts of industrial waste. Environmental issues due to waste landfills and increased raw material costs for new product development have led to the development of innovative recycling methods. This study focuses on the development of a product (helmet shell) by reinforcing thermosetting polymer waste (TPW) as a filler in a high-density polyethylene (HDPE) matrix. The HDPE and TPW were converted into extrudates using a twin-screw extruder. Then, the extrudate was pelletized to use as raw material for the injection molding machine. The HDPE/TPW composites were fabricated using injection molding. Maleic anhydride-grafted polyethylene was employed as a compatibilizer. In the composite, the TPW volume was reinforced at various weight percentages, ranging from 0 to 35 wt%. The mechanical, thermal, and viscoelastic properties of the composites can be enhanced by uniformly dispersing TPW in the HDPE matrix. However, it is difficult to achieve uniform dispersion at higher TPW volumes owing to the agglomeration effect. According to these findings, the mechanical properties were enhanced by up to 30 wt% addition of TPW. The findings suggest that the proposed composite has sufficient mechanical properties to be suitable for the fabrication of helmet shells.","PeriodicalId":11806,"journal":{"name":"e-Polymers","volume":null,"pages":null},"PeriodicalIF":3.2000,"publicationDate":"2024-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Assessing the recycling potential of thermosetting polymer waste in high-density polyethylene composites for safety helmet applications\",\"authors\":\"Diwahar Periasamy, Prakalathan Karuppiah, Bharathi Manoharan, Felix Sahayaraj Arockiasamy, Sathish Kannan, Vinayagam Mohanavel, Palanivel Velmurugan, Natarajan Arumugam, Abdulrahman I. Almansour, Subpiramaniyam Sivakumar\",\"doi\":\"10.1515/epoly-2023-0080\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The rising demand for thermosetting polymers has resulted in the production of large amounts of industrial waste. Environmental issues due to waste landfills and increased raw material costs for new product development have led to the development of innovative recycling methods. This study focuses on the development of a product (helmet shell) by reinforcing thermosetting polymer waste (TPW) as a filler in a high-density polyethylene (HDPE) matrix. The HDPE and TPW were converted into extrudates using a twin-screw extruder. Then, the extrudate was pelletized to use as raw material for the injection molding machine. The HDPE/TPW composites were fabricated using injection molding. Maleic anhydride-grafted polyethylene was employed as a compatibilizer. In the composite, the TPW volume was reinforced at various weight percentages, ranging from 0 to 35 wt%. The mechanical, thermal, and viscoelastic properties of the composites can be enhanced by uniformly dispersing TPW in the HDPE matrix. However, it is difficult to achieve uniform dispersion at higher TPW volumes owing to the agglomeration effect. According to these findings, the mechanical properties were enhanced by up to 30 wt% addition of TPW. The findings suggest that the proposed composite has sufficient mechanical properties to be suitable for the fabrication of helmet shells.\",\"PeriodicalId\":11806,\"journal\":{\"name\":\"e-Polymers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-04-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"e-Polymers\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1515/epoly-2023-0080\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"e-Polymers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/epoly-2023-0080","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Assessing the recycling potential of thermosetting polymer waste in high-density polyethylene composites for safety helmet applications
The rising demand for thermosetting polymers has resulted in the production of large amounts of industrial waste. Environmental issues due to waste landfills and increased raw material costs for new product development have led to the development of innovative recycling methods. This study focuses on the development of a product (helmet shell) by reinforcing thermosetting polymer waste (TPW) as a filler in a high-density polyethylene (HDPE) matrix. The HDPE and TPW were converted into extrudates using a twin-screw extruder. Then, the extrudate was pelletized to use as raw material for the injection molding machine. The HDPE/TPW composites were fabricated using injection molding. Maleic anhydride-grafted polyethylene was employed as a compatibilizer. In the composite, the TPW volume was reinforced at various weight percentages, ranging from 0 to 35 wt%. The mechanical, thermal, and viscoelastic properties of the composites can be enhanced by uniformly dispersing TPW in the HDPE matrix. However, it is difficult to achieve uniform dispersion at higher TPW volumes owing to the agglomeration effect. According to these findings, the mechanical properties were enhanced by up to 30 wt% addition of TPW. The findings suggest that the proposed composite has sufficient mechanical properties to be suitable for the fabrication of helmet shells.
期刊介绍:
e-Polymers is a strictly peer-reviewed scientific journal. The aim of e-Polymers is to publish pure and applied polymer-science-related original research articles, reviews, and feature articles. It includes synthetic methodologies, characterization, and processing techniques for polymer materials. Reports on interdisciplinary polymer science and on applications of polymers in all areas are welcome.
The present Editors-in-Chief would like to thank the authors, the reviewers, the editorial staff, the advisory board, and the supporting organization that made e-Polymers a successful and sustainable scientific journal of the polymer community. The Editors of e-Polymers feel very much engaged to provide best publishing services at the highest possible level.