硼烷的电子吸附效应和 CH 酸性：取代基的性质和位置的影响

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-04-02 DOI:10.1080/10426507.2024.2335982

Igor B. Sivaev , Sergey A. Anufriev , Akim V. Shmal’ko

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引用次数: 0

摘要

在碳硼烷笼不同位置的硼原子上不同性质的取代基对碳硼烷衍生物 CH 酸度的影响以及 C-碳硼烷衍生物的电子吸收效应。

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Electron-withdrawing effect and CH-acidity of carboranes: effect of nature and position of substituents

The effect of substituents of various natures at boron atoms in different positions of the carborane cage on the CH-acidity of carborane derivatives and the electron-withdrawing effect of C-carboranyl groups is considered using ¹H NMR spectroscopy data.

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来源期刊

Phosphorus, Sulfur, and Silicon and the Related Elements 化学-无机化学与核化学

CiteScore

2.60

自引率

7.70%

发文量

103

审稿时长

2.1 months

期刊介绍： Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.