{"title":"含芴和硫醚基团的高折射率芳香族聚酯的设计、合成和表征","authors":"Zihao Wu, Jian Wang, Jingwei Jiang, Jinhua Lei, Heran Nie, Guangyuan Zhou, Qiliang Yuan","doi":"10.1177/09540083241246766","DOIUrl":null,"url":null,"abstract":"9,9-bis(4-hydroxyphenyl)fluorene (BPF) is a highly structurally symmetric bisphenol with excellent optical properties of low birefringence and high refractive index, however, the glass transition temperature ( T<jats:sub>g</jats:sub>) of its polyester is high ( T<jats:sub>g</jats:sub>>300°C), which makes it difficult to be thermally processed and limits its application. On the other hand, 4,4′-Thiobis (2-methylphenol) (T2MP) has a flexible thioether group, its introduction not only brings high refractive index, but also can appropriately reduce the T<jats:sub>g</jats:sub> of the polymer. Therefore, by combining the advantages of both of them, we prepared aromatic polyesters with high refractive index and stabilization. This study provides a route that can appropriately reduce T<jats:sub>g</jats:sub> without loss of refractive index.","PeriodicalId":12932,"journal":{"name":"High Performance Polymers","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Design, synthesis and characterization of high refractive index aromatic polyesters containing fluorene and thioether groups\",\"authors\":\"Zihao Wu, Jian Wang, Jingwei Jiang, Jinhua Lei, Heran Nie, Guangyuan Zhou, Qiliang Yuan\",\"doi\":\"10.1177/09540083241246766\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"9,9-bis(4-hydroxyphenyl)fluorene (BPF) is a highly structurally symmetric bisphenol with excellent optical properties of low birefringence and high refractive index, however, the glass transition temperature ( T<jats:sub>g</jats:sub>) of its polyester is high ( T<jats:sub>g</jats:sub>>300°C), which makes it difficult to be thermally processed and limits its application. On the other hand, 4,4′-Thiobis (2-methylphenol) (T2MP) has a flexible thioether group, its introduction not only brings high refractive index, but also can appropriately reduce the T<jats:sub>g</jats:sub> of the polymer. Therefore, by combining the advantages of both of them, we prepared aromatic polyesters with high refractive index and stabilization. This study provides a route that can appropriately reduce T<jats:sub>g</jats:sub> without loss of refractive index.\",\"PeriodicalId\":12932,\"journal\":{\"name\":\"High Performance Polymers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-04-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"High Performance Polymers\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1177/09540083241246766\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Performance Polymers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/09540083241246766","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Design, synthesis and characterization of high refractive index aromatic polyesters containing fluorene and thioether groups
9,9-bis(4-hydroxyphenyl)fluorene (BPF) is a highly structurally symmetric bisphenol with excellent optical properties of low birefringence and high refractive index, however, the glass transition temperature ( Tg) of its polyester is high ( Tg>300°C), which makes it difficult to be thermally processed and limits its application. On the other hand, 4,4′-Thiobis (2-methylphenol) (T2MP) has a flexible thioether group, its introduction not only brings high refractive index, but also can appropriately reduce the Tg of the polymer. Therefore, by combining the advantages of both of them, we prepared aromatic polyesters with high refractive index and stabilization. This study provides a route that can appropriately reduce Tg without loss of refractive index.
期刊介绍:
Health Services Management Research (HSMR) is an authoritative international peer-reviewed journal which publishes theoretically and empirically rigorous research on questions of enduring interest to health-care organizations and systems throughout the world. Examining the real issues confronting health services management, it provides an independent view and cutting edge evidence-based research to guide policy-making and management decision-making. HSMR aims to be a forum serving an international community of academics and researchers on the one hand and healthcare managers, executives, policymakers and clinicians and all health professionals on the other. HSMR wants to make a substantial contribution to both research and managerial practice, with particular emphasis placed on publishing studies which offer actionable findings and on promoting knowledge mobilisation toward theoretical advances. All papers are expected to be of interest and relevance to an international audience. HSMR aims at enhance communication between academics and practitioners concerned with developing, implementing, and analysing health management issues, reforms and innovations primarily in European health systems and in all countries with developed health systems. Papers can report research undertaken in a single country, but they need to locate and explain their findings in an international context, and in international literature.