从脱水蓖麻油 (DCO) 中合成羟基端基脂肪酸酯酰胺 (DFEAm) 及其在各种聚氨酯涂料中的应用

IF 2.4 3区 化学 Q3 POLYMER SCIENCE Iranian Polymer Journal Pub Date : 2024-04-09 DOI:10.1007/s13726-024-01310-z
Debarati Maity, Akash B. Borkar, Aarti P. More, Anagha S. Sabnis
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引用次数: 0

摘要

植物油作为可再生资源,因其容易获得、价格低廉、无毒性和可生物降解性,如今越来越受到人们的青睐。在全球范围内,科学家们一直在努力减少对石油原料的依赖。脱水蓖麻油(DCO)以生物为基础,不可食用,与蓖麻油相比干燥速度快,具有柔韧性和出色的保色性,因此被用作本研究的主要原料来源。本研究旨在通过脱水蓖麻油(DCO)与二乙醇胺(DEA)的反应,避免甲酯合成步骤,一步合成脱水蓖麻油脂肪酰胺(DFAm)。获得的产品随后被纯化,并进行了化学和分析表征。此外,还使用癸二酸(SA)和异氰尿酸三-2-羟乙基酯(THEIC)成功地将 DFAm 改性为羟基封端脂肪酯酰胺(DFEAm)衍生物。THEIC 是杂环化合物,具有出色的耐热性和耐化学性,因此适合用于涂料应用,而且具有新颖性。随后,DFEAm 成功地与各种异氰酸酯加合物一起固化在低碳钢基材上。在同时进行的条件下,还选择了市售的羟基封端短油醇酸树脂进行对比研究。根据 ASTM 标准,对这些聚氨酯涂料的光学、机械、化学、热和防腐性能进行了评估。与商用聚氨酯涂料相比,DFEAm 聚氨酯涂料的机械性能相当,化学性能较差,但热性能和防腐性能优越。
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Synthesis of Hydroxyl Terminated Fatty Ester Amide (DFEAm) from Dehydrated Castor Oil (DCO) and its Utilization in Various Polyurethane Coating Applications

Vegetable oils have gained popularity now-a-days as renewable resources due to their accessibility, affordability, non-toxicity and biodegradability. Globally, scientists have been making efforts to lessen dependency on feed stocks derived from petroleum-based resources. Dehydrated castor oil (DCO) being bio-based, non-edible, quick-drying compared to castor oil, imparting flexibility and excellent color retention was used as the main source of raw material in this work. Present study aims at single-step synthesis of dehydrated castor oil fatty amide (DFAm) by reacting dehydrated castor oil (DCO) with diethanolamine (DEA) avoiding the methyl ester synthesis step. The product obtained was then purified and characterized chemically and analytically. Further, DFAm was modified successfully to its hydroxyl-terminated fatty ester amide (DFEAm) derivative using sebacic acid (SA) and tris-2-hydroxyethyl isocyanurate (THEIC). THEIC, being heterocyclic in nature and imparting excellent thermal and chemical resistance, makes it suitable and novel to be used in coating applications. DFEAm was then successfully cured with various isocyanate adducts on mild steel substrates. Commercially available hydroxyl-terminated short oil alkyd was selected for comparative study under simultaneous conditions. These polyurethane coatings were evaluated as per ASTM standards for their optical, mechanical, chemical, thermal and anti-corrosive properties. DFEAm PU coatings exhibited comparable mechanical and inferior chemical properties but superior thermal and anti-corrosion properties than that of the commercial PU coatings.

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来源期刊
Iranian Polymer Journal
Iranian Polymer Journal 化学-高分子科学
CiteScore
4.90
自引率
9.70%
发文量
107
审稿时长
2.8 months
期刊介绍: Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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