{"title":"通过稳定的糖基二氮杂环丁烷驯服糖基碳烯,从而获得硼酮苷","authors":"Charles C.J. Loh","doi":"10.1016/j.checat.2024.100980","DOIUrl":null,"url":null,"abstract":"<p>In this issue of <em>Chem Catalysis</em>, He and co-workers demonstrate easy access to diverse glycosyl boro-ketosides via a rare glycosylidene carbene intermediate. They use stable glycosylidene diaziridines as precursors for carbene generation, leading to products convertible into rare sugars and pharmaceutically interesting derivatives, such as tofogliflozin.</p>","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":null,"pages":null},"PeriodicalIF":11.5000,"publicationDate":"2024-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Taming glycosylidene carbenes through bench-stable glycosylidene diaziridines to access boro-ketosides\",\"authors\":\"Charles C.J. Loh\",\"doi\":\"10.1016/j.checat.2024.100980\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this issue of <em>Chem Catalysis</em>, He and co-workers demonstrate easy access to diverse glycosyl boro-ketosides via a rare glycosylidene carbene intermediate. They use stable glycosylidene diaziridines as precursors for carbene generation, leading to products convertible into rare sugars and pharmaceutically interesting derivatives, such as tofogliflozin.</p>\",\"PeriodicalId\":53121,\"journal\":{\"name\":\"Chem Catalysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":11.5000,\"publicationDate\":\"2024-04-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chem Catalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1016/j.checat.2024.100980\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1016/j.checat.2024.100980","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Taming glycosylidene carbenes through bench-stable glycosylidene diaziridines to access boro-ketosides
In this issue of Chem Catalysis, He and co-workers demonstrate easy access to diverse glycosyl boro-ketosides via a rare glycosylidene carbene intermediate. They use stable glycosylidene diaziridines as precursors for carbene generation, leading to products convertible into rare sugars and pharmaceutically interesting derivatives, such as tofogliflozin.
期刊介绍:
Chem Catalysis is a monthly journal that publishes innovative research on fundamental and applied catalysis, providing a platform for researchers across chemistry, chemical engineering, and related fields. It serves as a premier resource for scientists and engineers in academia and industry, covering heterogeneous, homogeneous, and biocatalysis. Emphasizing transformative methods and technologies, the journal aims to advance understanding, introduce novel catalysts, and connect fundamental insights to real-world applications for societal benefit.