{"title":"惰性相二维惰性金属氧化物：合成与先进催化剂","authors":"Yue Wang, Qi Shao","doi":"10.1016/j.trechm.2024.03.008","DOIUrl":null,"url":null,"abstract":"<p>Metastable-phase 2D noble-metal oxides, combining the advantages of noble-metal oxides, 2D materials, and metastable-phase materials are considered some of the most promising new catalysts for catalytic reactions. However, the thermodynamic instability of metastable-phase materials can lead to their transition to a stable phase resulting in the decay of catalytic activity, which is far from satisfactory in practical applications. In this review, research progress on metastable-phase 2D noble-metal oxides towards electrocatalysis is reported, including IrO<sub>2</sub>, RuO<sub>2</sub>, RhO<sub>2</sub> and PtO<sub>2</sub>, with emphasis on the advantages of metastable-phase 2D noble-metal oxides, detailed synthesis methods and catalyst-design strategies. Finally, the future prospects and challenges of metastable-phase 2D noble-metal oxide catalysts are provided.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"54 1","pages":""},"PeriodicalIF":14.0000,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metastable-phase 2D noble-metal oxides: syntheses and advanced catalysts\",\"authors\":\"Yue Wang, Qi Shao\",\"doi\":\"10.1016/j.trechm.2024.03.008\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Metastable-phase 2D noble-metal oxides, combining the advantages of noble-metal oxides, 2D materials, and metastable-phase materials are considered some of the most promising new catalysts for catalytic reactions. However, the thermodynamic instability of metastable-phase materials can lead to their transition to a stable phase resulting in the decay of catalytic activity, which is far from satisfactory in practical applications. In this review, research progress on metastable-phase 2D noble-metal oxides towards electrocatalysis is reported, including IrO<sub>2</sub>, RuO<sub>2</sub>, RhO<sub>2</sub> and PtO<sub>2</sub>, with emphasis on the advantages of metastable-phase 2D noble-metal oxides, detailed synthesis methods and catalyst-design strategies. Finally, the future prospects and challenges of metastable-phase 2D noble-metal oxide catalysts are provided.</p>\",\"PeriodicalId\":48544,\"journal\":{\"name\":\"Trends in Chemistry\",\"volume\":\"54 1\",\"pages\":\"\"},\"PeriodicalIF\":14.0000,\"publicationDate\":\"2024-04-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Trends in Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1016/j.trechm.2024.03.008\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Trends in Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.trechm.2024.03.008","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Metastable-phase 2D noble-metal oxides: syntheses and advanced catalysts
Metastable-phase 2D noble-metal oxides, combining the advantages of noble-metal oxides, 2D materials, and metastable-phase materials are considered some of the most promising new catalysts for catalytic reactions. However, the thermodynamic instability of metastable-phase materials can lead to their transition to a stable phase resulting in the decay of catalytic activity, which is far from satisfactory in practical applications. In this review, research progress on metastable-phase 2D noble-metal oxides towards electrocatalysis is reported, including IrO2, RuO2, RhO2 and PtO2, with emphasis on the advantages of metastable-phase 2D noble-metal oxides, detailed synthesis methods and catalyst-design strategies. Finally, the future prospects and challenges of metastable-phase 2D noble-metal oxide catalysts are provided.
期刊介绍：
Trends in Chemistry serves as a new global platform for discussing significant and transformative concepts across all areas of chemistry. It recognizes that breakthroughs in chemistry hold the key to addressing major global challenges. The journal offers readable, multidisciplinary articles, including reviews, opinions, and short pieces, designed to keep both students and leading scientists updated on pressing issues in the field.
Covering analytical, inorganic, organic, physical, and theoretical chemistry, the journal highlights major themes such as biochemistry, catalysis, environmental chemistry, materials, medicine, polymers, and supramolecular chemistry. It also welcomes articles on chemical education, health and safety, policy and public relations, and ethics and law.
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