{"title":"最前沿的灯笼形笼法","authors":"Zack T. Avery, Jess L. Algar, Dan Preston","doi":"10.1016/j.trechm.2024.03.002","DOIUrl":null,"url":null,"abstract":"<p>Lantern-shaped cages are generally comprised of two square planar metal ions linked by four ditopic ligands. They mainly form easily and predictably and make a structure with a small cavity well-suited for host–guest chemistry. These cages have been at the forefront of efforts by chemists to develop strategies for enhanced structural complexity in self-assembled metallo-supramolecular systems, which in the past few years have reached new heights. This review looks at the techniques employed to garner this complexity, with focus on the latest examples and the most recently developed methodologies.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"130 1","pages":""},"PeriodicalIF":14.0000,"publicationDate":"2024-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The cutting edge of lantern-shaped cage methodologies\",\"authors\":\"Zack T. Avery, Jess L. Algar, Dan Preston\",\"doi\":\"10.1016/j.trechm.2024.03.002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Lantern-shaped cages are generally comprised of two square planar metal ions linked by four ditopic ligands. They mainly form easily and predictably and make a structure with a small cavity well-suited for host–guest chemistry. These cages have been at the forefront of efforts by chemists to develop strategies for enhanced structural complexity in self-assembled metallo-supramolecular systems, which in the past few years have reached new heights. This review looks at the techniques employed to garner this complexity, with focus on the latest examples and the most recently developed methodologies.</p>\",\"PeriodicalId\":48544,\"journal\":{\"name\":\"Trends in Chemistry\",\"volume\":\"130 1\",\"pages\":\"\"},\"PeriodicalIF\":14.0000,\"publicationDate\":\"2024-04-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Trends in Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1016/j.trechm.2024.03.002\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Trends in Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.trechm.2024.03.002","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
The cutting edge of lantern-shaped cage methodologies
Lantern-shaped cages are generally comprised of two square planar metal ions linked by four ditopic ligands. They mainly form easily and predictably and make a structure with a small cavity well-suited for host–guest chemistry. These cages have been at the forefront of efforts by chemists to develop strategies for enhanced structural complexity in self-assembled metallo-supramolecular systems, which in the past few years have reached new heights. This review looks at the techniques employed to garner this complexity, with focus on the latest examples and the most recently developed methodologies.
期刊介绍：
Trends in Chemistry serves as a new global platform for discussing significant and transformative concepts across all areas of chemistry. It recognizes that breakthroughs in chemistry hold the key to addressing major global challenges. The journal offers readable, multidisciplinary articles, including reviews, opinions, and short pieces, designed to keep both students and leading scientists updated on pressing issues in the field.
Covering analytical, inorganic, organic, physical, and theoretical chemistry, the journal highlights major themes such as biochemistry, catalysis, environmental chemistry, materials, medicine, polymers, and supramolecular chemistry. It also welcomes articles on chemical education, health and safety, policy and public relations, and ethics and law.
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