Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao and Wei Zhang
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引用次数: 0
摘要
水氧化反应是太阳能转换的一个关键过程,已引起研究人员的极大关注。要实现高效的能量转换,就必须开发出具有成本效益且经久耐用的水氧化催化剂。要设计出有效的催化剂,就必须从根本上了解反应机理。本综述全面概述了在了解使用过渡金属基异质电催化剂(包括 Mn、Fe、Co、Ni 和 Cu 基催化剂)进行水氧化的机理方面取得的最新进展。报告重点介绍了不同过渡金属的催化机理,并强调了监测关键中间产物对探索反应途径的重要性。此外,还介绍了水氧化中间产物物理表征的先进技术,目的是为建立可靠的水氧化研究方法提供信息。对过渡金属基水氧化电催化剂的研究有助于为理解自然和人工能量转换过程提供新的见解。
The mechanism of water oxidation using transition metal-based heterogeneous electrocatalysts
The water oxidation reaction, a crucial process for solar energy conversion, has garnered significant research attention. Achieving efficient energy conversion requires the development of cost-effective and durable water oxidation catalysts. To design effective catalysts, it is essential to have a fundamental understanding of the reaction mechanisms. This review presents a comprehensive overview of recent advancements in the understanding of the mechanisms of water oxidation using transition metal-based heterogeneous electrocatalysts, including Mn, Fe, Co, Ni, and Cu-based catalysts. It highlights the catalytic mechanisms of different transition metals and emphasizes the importance of monitoring of key intermediates to explore the reaction pathway. In addition, advanced techniques for physical characterization of water oxidation intermediates are also introduced, for the purpose of providing information for establishing reliable methodologies in water oxidation research. The study of transition metal-based water oxidation electrocatalysts is instrumental in providing novel insights into understanding both natural and artificial energy conversion processes.
期刊介绍:
Chemical Society Reviews is published by: Royal Society of Chemistry.
Focus: Review articles on topics of current interest in chemistry;
Predecessors: Quarterly Reviews, Chemical Society (1947–1971);
Current title: Since 1971;
Impact factor: 60.615 (2021);
Themed issues: Occasional themed issues on new and emerging areas of research in the chemical sciences