环保离子液体在淀粉塑化和改性中的可行性

Shilpi Agarwal, Shailey Singhal
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摘要

离子液体(IL)已成为各种化学过程和反应(包括淀粉的糊化和化学修饰)的潜在溶剂。通过各种研究发现,使用离子液体/水混合物而非纯离子液体,可以平衡离子液体的昂贵性质。由于它们的同步效应和合理的粘度,IL/水体系具有更有效地塑化淀粉的优势。可以根据淀粉的具体类型,通过选择特定的阳离子/阴离子来调节 IL 的特性,这可能有助于淀粉的方便溶解和改性。淀粉可在 IL 介质中通过酯化或醚化反应进行改性,以改变其特性并用于各种应用领域。淀粉的溶解受多种参数的影响,如淀粉的类型、IL 的性质、IL/水的比例和温度,本综述论文对此进行了详细讨论。
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Viability of Ecofriendly Ionic Liquids in Starch Plasticization and Modification
Ionic liquids (IL) have emerged as the potential class of solvents for various chemical processes and reactions, including gelatinization and chemical modification of starch. Through various studies it has been established that expensive nature of ILs can be counter balanced by employing the mixture of IL/water instead of pure ILs. The IL/water system has the advantage to plasticize starch more effectively due to their synchronal effect and rational viscosity. The properties of ILs can be tempered by preferring particular cations/anions according to the specific type of starch which may be helpful in convenient dissolution and modification of starch. Starch can be modified by esterification or etherification reaction in IL medium to alter their properties and to use it in various application areas. Starch dissolution is subjected to various parameters like type of starch, nature of IL, ratio of IL/water, and temperature which has been discussed elaborately in the present review paper.
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