对电子玻璃/碳纳米管/环氧树脂复合材料中天然橡胶增强材料的机械和动态特性的初步研究和支持

Selvaraj Anidha, Santhosh Mozhuguan Sekar, Elango Natarajan, M. Muthukkumar, K. Markandan, C. Ang, Gérald Franz
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摘要

本研究报告介绍了由电子玻璃纤维、环氧树脂和 2 wt.% 的碳纳米管(CNTs)以及不同比例的天然橡胶(NR)组成的杂化聚合物复合材料的合成和机械性能。研究人员对制备的混合聚合物复合材料的表面形态、热性能和机械性能进行了检测。本研究的结果表明,天然橡胶提高了杂化聚合物复合材料的机械性能,特别是 10 wt.% 的天然橡胶是产生 88 MPa 最高强度的最佳比例,而 5 wt.% 的天然橡胶的强度为 52 MPa。为了评估阻尼特性,在不同频率下对 E-Glass/CNT 与 NR 复合材料进行了动态机械分析,并进行了热重分析。结果发现,与其他复合材料相比,用 10 wt.% 天然橡胶增强的复合材料显示出更高的玻璃化转变温度(376.86 °C)和存储模量(2468 兆帕),这表明该复合材料的交联密度更高,聚合物模量更大。此外,还进行了 X 射线衍射分析,并报告了分析结果,以增进对结晶相的总体了解。
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Preliminary Investigations and Support for the Mechanical and Dynamic Characteristics of a Natural Rubber Reinforcement in E-Glass/CNT/Epoxy Composite
The present investigation reports the synthesis and mechanical properties of a hybrid polymer composite consisting of E-Glass fiber, epoxy and 2 wt.% carbon nanotubes (CNTs) with a varying percentage of natural rubber (NR). The prepared hybrid polymer composites were examined in terms of their surface morphology, thermal properties as well as mechanical properties. The findings from the present study indicate that natural rubber enhances the mechanical properties of the hybrid polymer composites and, in particular, 10 wt.% is the optimum percentage of NR that yields the highest strength of 88 MPa, while the strength is 52 MPa with 5 wt.% NR. In order to evaluate the damping properties, a dynamic mechanical analysis was carried out on the E-Glass/CNT with NR composites at various frequencies along with a thermogravimetric analysis. It was found that the composite reinforced with 10 wt.% natural rubber exhibited a higher glass transition temperature of 376.86 °C and storage modulus of 2468 MPa when compared to the other composites, which indicates the enhanced cross-linking density and higher polymer modulus of the composite. X-ray diffraction analysis was also conducted and the results are reported to improve the general understanding of crystalline phases.
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