通过调节纤维形态协同优化芳纶复合绝缘纸的机械和电气性能

IF 3.8 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC IET Nanodielectrics Pub Date : 2024-04-01 DOI:10.1049/nde2.12081
Meng Huang, Yuanxin Yao, Lu Wang, Sai Li, Yanxiao Su, Jie Ma
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引用次数: 0

摘要

芳纶绝缘纸中的纤维具有良好的粘附能力。然而,人们对纤维形态对芳纶绝缘纸机械和电气性能的影响仍然知之甚少。通过改进制备工艺,制备出不同形态结构的芳纶纤维,并在相同条件下用于制造芳纶复合绝缘纸。结果表明,提高剪切速率和芳纶溶液浓度会影响剪切力的大小和双重扩散过程,从而影响纤维的平均长度、比表面积和结晶度。当转子频率为 25-30 赫兹、溶液浓度为 15%时,纤维的比表面积大,同时结晶度高,有利于提高击穿强度。当纤维的平均长度为 0.8-1.4 mm、细度含量为 1.3%-2.3%、比表面积为 57.5-62 m2 g-1、结晶度为 18.5%-27% 时,芳纶复合绝缘纸具有最佳的机械和电气性能。结合微观形态测试结果,得出了纤维性能对芳纶复合绝缘纸机械性能、介电性能、交直流击穿强度的影响机理。该结果对高性能芳纶复合绝缘纸的制备和应用具有重要的理论意义和实用价值。
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Synergetic optimisation of mechanical and electrical properties of aramid composite insulation paper by modulation of fibrid morphology
The fibrids in aramid insulation paper exhibit good adhesion ability. However, the effects of fibrids morphology on the mechanical and electrical properties of aramid insulation paper remains poorly understood. Aramid fibrids with different morphological structures were prepared by modifying the preparation process, and then they were used to fabricate aramid composite insulation paper under the same condition. The results showed that increasing the shear rate and aramid solution concentration affected the magnitude of the shear force and double diffusion process, thus affecting the average length, specific surface area, and crystallinity of the fibrids. When the rotor frequency is 25–30 Hz and the solution concentration is 15%, the fibrid has a large specific surface area while ensuring high crystallinity, which is beneficial to the improvement of breakdown strength. When the average length of fibrids is 0.8–1.4 mm, the fine content is 1.3%–2.3%, specific surface area is 57.5–62 m2 g−1, and crystallinity is 18.5%–27%, the aramid composite insulation paper has the optimal mechanical and electrical properties. Combined with the micromorphology test results, the influence mechanism of fibrids properties on the mechanical properties, dielectric properties, and AC and DC breakdown strength of aramid composite insulation paper was obtained. The result is of great theoretical significance and practical value for the preparation and application of high‐performance aramid composite insulation paper.
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来源期刊
IET Nanodielectrics
IET Nanodielectrics Materials Science-Materials Chemistry
CiteScore
5.60
自引率
3.70%
发文量
7
审稿时长
21 weeks
期刊最新文献
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