通过催化转移加氢制备生物质基 2,5-双(羟甲基)呋喃的最新进展

Q3 Energy 燃料化学学报 Pub Date : 2024-05-01 DOI:10.1016/S1872-5813(23)60403-7
LI Wei , GONG Honghui , SHI Xianlei
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引用次数: 0

摘要

生物质基 2,5-双(羟甲基)呋喃(BHMF)是重要的高附加值化学品之一,可由廉价的可再生碳水化合物通过催化转化和选择性氢化的方式制备,作为一种广泛应用的化学中间体和燃料前体,在改善传统聚酯性能和合成新型可生物降解的生物基聚酯方面具有独特的优势。近年来,以碳水化合物为原料生产 BHMF 等高附加值化学品的研究一直备受学术界和工业界的关注。然而,清洁、高效、高选择性和低成本仍然是这一领域的主要挑战,尤其是在实际应用中。在 BHMF 的生产过程中,传统的氢化方法需要消耗大量的高能氢气,并且由于高压氢气的安全隐患,会产生过高的基础设施投资。鉴于催化转移加氢的优势,本综述系统讨论了利用甲酸、醇类和其他类型的氢供体,通过催化转移加氢的方法选择性加氢制备 BHMF 的进展。针对催化转移加氢过程中不同类型供氢体、催化剂和反应过程的特点和问题,研究了反应条件和过程强化对 BHMF 选择性和产率的影响,以及反应体系的优缺点。在此基础上,提出了转移加氢制备 BHMF 的新型催化体系的未来发展方向,预测了生产 BHMF 的更清洁、更高效、更基本的安全技术,为生物质转化领域相关催化体系的研究与开发提供了一定的科学参考。
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Recent advances in preparing biomass-based 2,5-bis(hydroxymethyl)furan by catalytic transfer hydrogenation

Biomass-based 2,5-bis(hydroxymethyl)furan (BHMF) is one of the important high value-added chemicals, which can be prepared from inexpensive and renewable carbohydrates through the way of catalytic conversion and selective hydrogenation, and as a widely used chemical intermediate and fuel precursor, it has unique advantages in improving the performance of traditional polyesters and synthesizing new biodegradable bio-based polyesters. In recent years, the research on the production of high value-added chemicals such as BHMF from carbohydrate has been attracting much attention from both academia and industry. However, cleanliness, high efficiency, high selectivity and low-cost remain key challenges in this area, especially for practical applications. In the process of BHMF production, the traditional hydrogenation method consumed a large amount of high-grade energy of hydrogen, and an excessive investment in infrastructure would be generated due to the security risks of higher pressure of hydrogen. On account of the advantages of catalytic transfer hydrogenation, the advances in selective hydrogenation to prepare BHMF using formic acid, alcohols and other types of hydrogen donors by the approach of catalytic transfer hydrogenation is systematically discussed in this review. In view of the features and problems of different types of hydrogen donors, catalysts and reaction processes during the catalytic transfer hydrogenation process, the effects of reaction conditions and process intensifications on the selectivity and yield of BHMF, and the merits and demerits of the reaction system were all investigated. On this basis, the future directions of new catalytic systems for preparation of BHMF by transfer hydrogenation is proposed, and the cleaner, more efficient and essential safety technologies for the production of BHMF is predicted, which will provide some scientific reference for the research and development of related catalytic systems in biomass conversion.

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来源期刊
燃料化学学报
燃料化学学报 Chemical Engineering-Chemical Engineering (all)
CiteScore
2.80
自引率
0.00%
发文量
5825
期刊介绍: Journal of Fuel Chemistry and Technology (Ranliao Huaxue Xuebao) is a Chinese Academy of Sciences(CAS) journal started in 1956, sponsored by the Chinese Chemical Society and the Institute of Coal Chemistry, Chinese Academy of Sciences(CAS). The journal is published bimonthly by Science Press in China and widely distributed in about 20 countries. Journal of Fuel Chemistry and Technology publishes reports of both basic and applied research in the chemistry and chemical engineering of many energy sources, including that involved in the nature, processing and utilization of coal, petroleum, oil shale, natural gas, biomass and synfuels, as well as related subjects of increasing interest such as C1 chemistry, pollutions control and new catalytic materials. Types of publications include original research articles, short communications, research notes and reviews. Both domestic and international contributors are welcome. Manuscripts written in Chinese or English will be accepted. Additional English titles, abstracts and key words should be included in Chinese manuscripts. All manuscripts are subject to critical review by the editorial committee, which is composed of about 10 foreign and 50 Chinese experts in fuel science. Journal of Fuel Chemistry and Technology has been a source of primary research work in fuel chemistry as a Chinese core scientific periodical.
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