低阶煤样的多级气化重力分离过程

IF 1.4 4区 工程技术 Q3 ENGINEERING, CHEMICAL Asia-Pacific Journal of Chemical Engineering Pub Date : 2024-05-02 DOI:10.1002/apj.3089
Thuan Duc Mai, Emese Sebe, Tamás Koós, András Arnold Kállay
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引用次数: 0

摘要

分选工艺是一种成熟的低阶煤选矿技术方法,特别是在热化学工艺中的利用。在本研究中,三个煤样(包括原始低阶煤样和原始煤样重力分选过程中产生的两个煤样(C1 和 C2))在多级气化过程中进行了气化,气化温度为 900°C,蒸汽碳比(S/C)为 1.00 和 1.25。分离过程显著提高了煤样的质量。与原煤相比,这种改善尤其表现在碳和挥发分含量更高,灰分含量更低。这可能是 C1 和 C2 煤样实验中气化性能较高的主要原因。从 C1 和 C2 煤样气化实验中获得的合成气体积是原煤样的 1.3 至 1.5 倍。在所有 S/C 比率和 900°C 温度条件下,C2 煤样的气化实验产生的合成气产量最高,其次是 C1 煤样的气化实验。从化学角度来看,生成气体的 H2/CO 比率接近 2.00 的理想比率,适合化学合成工艺。在 C1 样品的实验中,当 S/C 比率为 1.00 和 1.25 时,H2/CO 比率分别为 2.11 和 2.18。在 C2 样品的实验中,当 S/C 比率为 1.00 和 1.25 时,H2/CO 比率分别达到 1.88 和 2.00。
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The multi-stage gasification process of low-rank coal samples from gravity separation process

The separation process is a well-established method for beneficiation technologies of low-rank coal, especially in the case of utilization in the thermochemical processes. In this study, three coal samples, including the original low-rank coal sample and two coal samples (C1 and C2) from the gravity separation process of the original coal sample, were gasified in a multi-stage gasification process at the gasification temperature of 900°C and the steam-to-carbon (S/C) ratio of 1.00 and 1.25. The separation process led to a significant improvement in the quality of coal samples. This improvement is particularly characterized by a higher carbon and volatile fractions and a lower ash content compared with the original coal. This could be the main reason for the higher gasification performance in the case of the experiment of C1 and C2 coal samples. The volume of syngas obtained from gasification experiments of C1 and C2 samples increased between 1.3 and 1.5 times that of the original coal sample. At all S/C ratios and 900°C, the gasification experiment of the C2 sample produced the highest produced gas yield followed by the gasification experiment of the C1 sample. From the chemical point of view, the produced gas had an H2/CO ratio close to the desired ratio of 2.00, which is suitable for chemical synthesis processes. In the case of C1 sample experiments, the H2/CO ratios were 2.11 and 2.18 at S/C ratios of 1.00 and 1.25, respectively. For the experiments of the C2 sample, the H2/CO ratio reached 1.88 and 2.00 at S/C ratios of 1.00 and 1.25, respectively.

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来源期刊
自引率
11.10%
发文量
111
期刊介绍: Asia-Pacific Journal of Chemical Engineering is aimed at capturing current developments and initiatives in chemical engineering related and specialised areas. Publishing six issues each year, the journal showcases innovative technological developments, providing an opportunity for technology transfer and collaboration. Asia-Pacific Journal of Chemical Engineering will focus particular attention on the key areas of: Process Application (separation, polymer, catalysis, nanotechnology, electrochemistry, nuclear technology); Energy and Environmental Technology (materials for energy storage and conversion, coal gasification, gas liquefaction, air pollution control, water treatment, waste utilization and management, nuclear waste remediation); and Biochemical Engineering (including targeted drug delivery applications).
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