比较不同前驱体通过 PECVD 制造的介电镜的光学特性:单硅烷和四乙氧基硅烷

IF 0.8 Q3 Engineering Nanotechnologies in Russia Pub Date : 2024-03-21 DOI:10.1134/S2635167623601134
I. M. Asharchuk, M. V. Shibalov, A. M. Mumlyakov, P. A. Nekludova, G. D. Diudbin, N. V. Minaev, A. A. Pavlov, M. A. Tarkhov
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引用次数: 0

摘要

摘要 比较了由气体前驱体(即单硅烷 SiH4)和有机硅前驱体(即四乙氧基硅烷 (TEOS))生成的氧化硅对电介质布拉格反射镜光学特性的影响。在等离子体增强化学气相沉积(PECVD)中使用四乙氧基硅烷作为前驱体,可以降低沉积薄膜的平均粗糙度。同样的薄膜沉积方法还能在一个工艺室中制造出一对 SiNx/SiOx 而不破坏真空。实验表明,用 TEOS 前驱体制作的镜子比用单硅烷制作的镜子具有更好的特性,因此反射率提高了 20%,光学损耗降低了两倍。与 SiNx/SiOx(SiH4)反射镜相比,SiNx/SiOx(TEOS)反射镜表面的平均粗糙度 Ra 降低了五倍。TEOS 前驱体的应用大大提高了沉积层界面的质量,从而提高了布拉格反射镜的反射率,并将平均粗糙度 Ra 从 11.04 纳米降至 2.31 纳米。因此,SiNx/SiOx 接口的改善使损耗降低了两倍。这些结果可被视为一项重大优势,可降低多层反射镜制造过程中的材料成本。
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Comparing the Optical Characteristics of Dielectric Mirrors Fabricated by PECVD from Different Precursors: Monosilane and Tetraethoxysilane

The influence of the application of silicon oxide produced from a gas precursor, i.e., monosilane SiH4 and an organosilicon precursor, i.e., tetraethoxysilane (TEOS) on the optical characteristics of dielectric Bragg mirrors is compared. The use of tetraethoxysilane as a precursor in plasma-enhanced chemical vapor deposition (PECVD) demonstrates a decrease in the average roughness of the deposited film. The same method of film deposition also makes it possible to fabricate a SiNx/SiOx pair in one process chamber without breaking vacuum. It is experimentally shown that a mirror fabricated from a TEOS precursor possesses better characteristics than a mirror fabricated using monosilane, thus, the reflectivity increases by 20% and optical losses decrease twofold. The roughness average Ra of the surface of a SiNx/SiOx (TEOS) mirror decreases fivefold when compared to a SiNx/SiOx (SiH4) mirror. The application of a TEOS precursor substantially increases the quality of the interfaces of the deposited layers which leads to a gain in the reflectivity of the Bragg mirror and a decrease in the roughness average Ra from 11.04 down to 2.31 nm. As a consequence, improvement of the SiNx/SiOx interfaces leads to a twofold reduction in the losses. These results can be considered as a significant advantage that leads to a drop in the costs of materials during the fabrication of multilayer mirrors.

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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
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0.00%
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期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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