Jago G. Love-Jennings , Aidan P. McKay , David B. Cordes , William T. A. Harrison , E. R. T. Tiekink (Editor)
{"title":"聚[3-甲基吡啶鎓[(μ2-二氢磷)双(μ3-氢磷)二锌]]。","authors":"Jago G. Love-Jennings , Aidan P. McKay , David B. Cordes , William T. A. Harrison , E. R. T. Tiekink (Editor)","doi":"10.1107/S2414314624003456","DOIUrl":null,"url":null,"abstract":"<div><p>The title compound features bifurcated template-to-framework N—H⋯(O,O) hydrogen bonds.</p></div><div><p>In the title compound, {(C<sub>6</sub>H<sub>8</sub>N)[Zn<sub>2</sub>(HPO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>PO<sub>3</sub>)]}<sub>\nn\n</sub>, the constituent ZnO<sub>4</sub>, HPO<sub>3</sub> and H<sub>2</sub>PO<sub>3</sub> polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H⋯O hydrogen bonds. The protonated templates are anchored to the inorganic sheets <em>via</em> bifurcated N—H⋯(O,O) hydrogen bonds. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (233KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11074543/pdf/","citationCount":"0","resultStr":"{\"title\":\"Poly[3-methylpyridinium [(μ2-dihydrogen phosphito)bis(μ3-hydrogen phosphito)dizinc]]\",\"authors\":\"Jago G. Love-Jennings , Aidan P. McKay , David B. Cordes , William T. A. Harrison , E. R. T. Tiekink (Editor)\",\"doi\":\"10.1107/S2414314624003456\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The title compound features bifurcated template-to-framework N—H⋯(O,O) hydrogen bonds.</p></div><div><p>In the title compound, {(C<sub>6</sub>H<sub>8</sub>N)[Zn<sub>2</sub>(HPO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>PO<sub>3</sub>)]}<sub>\\nn\\n</sub>, the constituent ZnO<sub>4</sub>, HPO<sub>3</sub> and H<sub>2</sub>PO<sub>3</sub> polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H⋯O hydrogen bonds. The protonated templates are anchored to the inorganic sheets <em>via</em> bifurcated N—H⋯(O,O) hydrogen bonds. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (233KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11074543/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000233\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000233","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The title compound features bifurcated template-to-framework N—H⋯(O,O) hydrogen bonds.
In the title compound, {(C6H8N)[Zn2(HPO3)2(H2PO3)]}
n
, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H⋯O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N—H⋯(O,O) hydrogen bonds.
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