{"title":"用 WO3/Ag 和 TiO2/NiO 复合电极组装的高性能电致变色装置，可用于智能窗户","authors":"Haorui Liu, Jikai Yang, Decai Nie, Chunlei Liu, Liumenghan Zheng, Yining Mu, Weijun Chen","doi":"10.1007/s11706-024-0674-z","DOIUrl":null,"url":null,"abstract":"<div><p>The choice of cathode and anode materials for electrochromic devices plays a key role in the performance of electrochromic smart windows. In this research, WO<sub>3</sub>/Ag and TiO<sub>2</sub>/NiO composite thin films were separately prepared by the hydrothermal method combined with electrodeposition. The electrochromic properties of the single WO<sub>3</sub> thin film were optimized, and TiO<sub>2</sub>/NiO composite films showed better electrochromic performance than that of the single NiO film. WO<sub>3</sub>/Ag and TiO<sub>2</sub>/NiO composite films with excellent electrochromic properties were respectively chosen as the cathode and the anode to construct a WO<sub>3</sub>/Ag-TiO<sub>2</sub>/NiO electrochromic device. The response time (<i>t</i><sub>c</sub> = 4.08 s, <i>t</i><sub>b</sub> = 1.08 s), optical modulation range (35.91%), and coloration efficiency (30.37 cm<sup>2</sup>·C<sup>−1</sup>) of this electrochromic device are better than those of WO<sub>3</sub>-NiO and WO<sub>3</sub>/Ag-NiO electrochromic devices. This work provides a novel research idea for the performance enhancement of electrochromic smart windows.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 1","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A high-performance electrochromic device assembled with WO3/Ag and TiO2/NiO composite electrodes towards smart window\",\"authors\":\"Haorui Liu, Jikai Yang, Decai Nie, Chunlei Liu, Liumenghan Zheng, Yining Mu, Weijun Chen\",\"doi\":\"10.1007/s11706-024-0674-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The choice of cathode and anode materials for electrochromic devices plays a key role in the performance of electrochromic smart windows. In this research, WO<sub>3</sub>/Ag and TiO<sub>2</sub>/NiO composite thin films were separately prepared by the hydrothermal method combined with electrodeposition. The electrochromic properties of the single WO<sub>3</sub> thin film were optimized, and TiO<sub>2</sub>/NiO composite films showed better electrochromic performance than that of the single NiO film. WO<sub>3</sub>/Ag and TiO<sub>2</sub>/NiO composite films with excellent electrochromic properties were respectively chosen as the cathode and the anode to construct a WO<sub>3</sub>/Ag-TiO<sub>2</sub>/NiO electrochromic device. The response time (<i>t</i><sub>c</sub> = 4.08 s, <i>t</i><sub>b</sub> = 1.08 s), optical modulation range (35.91%), and coloration efficiency (30.37 cm<sup>2</sup>·C<sup>−1</sup>) of this electrochromic device are better than those of WO<sub>3</sub>-NiO and WO<sub>3</sub>/Ag-NiO electrochromic devices. This work provides a novel research idea for the performance enhancement of electrochromic smart windows.</p></div>\",\"PeriodicalId\":572,\"journal\":{\"name\":\"Frontiers of Materials Science\",\"volume\":\"18 1\",\"pages\":\"\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-05-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11706-024-0674-z\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Materials Science","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11706-024-0674-z","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
A high-performance electrochromic device assembled with WO3/Ag and TiO2/NiO composite electrodes towards smart window
The choice of cathode and anode materials for electrochromic devices plays a key role in the performance of electrochromic smart windows. In this research, WO3/Ag and TiO2/NiO composite thin films were separately prepared by the hydrothermal method combined with electrodeposition. The electrochromic properties of the single WO3 thin film were optimized, and TiO2/NiO composite films showed better electrochromic performance than that of the single NiO film. WO3/Ag and TiO2/NiO composite films with excellent electrochromic properties were respectively chosen as the cathode and the anode to construct a WO3/Ag-TiO2/NiO electrochromic device. The response time (tc = 4.08 s, tb = 1.08 s), optical modulation range (35.91%), and coloration efficiency (30.37 cm2·C−1) of this electrochromic device are better than those of WO3-NiO and WO3/Ag-NiO electrochromic devices. This work provides a novel research idea for the performance enhancement of electrochromic smart windows.
期刊介绍：
Frontiers of Materials Science is a peer-reviewed international journal that publishes high quality reviews/mini-reviews, full-length research papers, and short Communications recording the latest pioneering studies on all aspects of materials science. It aims at providing a forum to promote communication and exchange between scientists in the worldwide materials science community.
The subjects are seen from international and interdisciplinary perspectives covering areas including (but not limited to):
Biomaterials including biomimetics and biomineralization;
Nano materials;
Polymers and composites;
New metallic materials;
Advanced ceramics;
Materials modeling and computation;
Frontier materials synthesis and characterization;
Novel methods for materials manufacturing;
Materials performance;
Materials applications in energy, information and biotechnology.
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