大功率太阳光模拟紫外线诱导的自由基聚合：自引发和自交联

IF 5.4 3区材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-05-16 DOI:10.1002/mame.202470009

Wenqing Yan, Jimena de la Vega, Özen Eroğlu, Lavinia Heisenberg, Deyi Wang

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引用次数: 0

摘要

封面：模拟太阳光的高功率紫外线可诱导以（甲基）丙烯酸酯为基础的单体发生自由基聚合反应。在此过程中，单自由基可通过氢萃取机制产生，而双自由基可通过光解离或氧引发机制产生。生成的自由基可促进自引发和自交联，使该技术无需添加引发剂或交联剂即可高效合成聚合物网络。严文清及其合作者在第 2399456 号文章中对此进行了报道。

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High Power Sunlight-Simulated UV-Induced Radical Polymerization: Self-Initiation and Self-Crosslinking

Front Cover: High power, sunlight-simulated UV light induces radical polymerizations of (meth)acrylate-based monomers. During this process, mono-radicals can be generated through the H-abstraction mechanism, while bi-radicals can arise from photodissociation or oxygen initiation mechanisms. The generated free radicals facilitate self-initiation and self-crosslinking, rendering this technology efficient for synthesizing polymer networks without the need for added initiators or crosslinkers. This is reported by Wenqing Yan and co-workers in article 2399456.

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来源期刊

ACS Applied Energy Materials Materials Science-Materials Chemistry

CiteScore

10.30

自引率

6.20%

发文量

1368

期刊介绍： ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.