{"title":"电正思维：使用电正性金属催化二氮还原","authors":"Samuel M. Bhutto, Louise A. Berben","doi":"10.1016/j.checat.2024.101003","DOIUrl":null,"url":null,"abstract":"<p>In this issue of <em>Chem Catalysis</em>, Arnold and co-workers describe Lewis acidic f- and d-block metal complexes that are catalysts for the conversion of N<sub>2</sub> into secondary and tertiary amines. The origins of the remarkable selectivity and tunability of product formation are discussed in relation to molecular structure.</p>","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":null,"pages":null},"PeriodicalIF":11.5000,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electro-positive thinking: Catalytic dinitrogen reduction using electropositive metals\",\"authors\":\"Samuel M. Bhutto, Louise A. Berben\",\"doi\":\"10.1016/j.checat.2024.101003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this issue of <em>Chem Catalysis</em>, Arnold and co-workers describe Lewis acidic f- and d-block metal complexes that are catalysts for the conversion of N<sub>2</sub> into secondary and tertiary amines. The origins of the remarkable selectivity and tunability of product formation are discussed in relation to molecular structure.</p>\",\"PeriodicalId\":53121,\"journal\":{\"name\":\"Chem Catalysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":11.5000,\"publicationDate\":\"2024-05-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chem Catalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1016/j.checat.2024.101003\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1016/j.checat.2024.101003","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
在本期的《化学催化》（Chem Catalysis）杂志上，Arnold 及其合作者介绍了路易斯酸性 f 和 d 块金属复合物，它们是将 N2 转化为仲胺和叔胺的催化剂。他们结合分子结构讨论了产品形成的显著选择性和可调性的起源。
Electro-positive thinking: Catalytic dinitrogen reduction using electropositive metals
In this issue of Chem Catalysis, Arnold and co-workers describe Lewis acidic f- and d-block metal complexes that are catalysts for the conversion of N2 into secondary and tertiary amines. The origins of the remarkable selectivity and tunability of product formation are discussed in relation to molecular structure.
期刊介绍：
Chem Catalysis is a monthly journal that publishes innovative research on fundamental and applied catalysis, providing a platform for researchers across chemistry, chemical engineering, and related fields. It serves as a premier resource for scientists and engineers in academia and industry, covering heterogeneous, homogeneous, and biocatalysis. Emphasizing transformative methods and technologies, the journal aims to advance understanding, introduce novel catalysts, and connect fundamental insights to real-world applications for societal benefit.
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