1-[3-(2-氧代-3-苯基-1,2-二氢喹喔啉-1-基)丙基]-3-苯基-1,2-二氢喹喔啉-2-酮的合成、晶体结构和 Hirshfeld 表面分析

Nadeem Abad , Joel T. Mague , Abdulsalam Alsubari , El Mokhtar Essassi , Abdullah Yahya Abdullah Alzahrani , Youssef Ramli , L. Van Meervelt (Editor)
{"title":"1-[3-(2-氧代-3-苯基-1,2-二氢喹喔啉-1-基)丙基]-3-苯基-1,2-二氢喹喔啉-2-酮的合成、晶体结构和 Hirshfeld 表面分析","authors":"Nadeem Abad ,&nbsp;Joel T. Mague ,&nbsp;Abdulsalam Alsubari ,&nbsp;El Mokhtar Essassi ,&nbsp;Abdullah Yahya Abdullah Alzahrani ,&nbsp;Youssef Ramli ,&nbsp;L. Van Meervelt (Editor)","doi":"10.1107/S2056989024004377","DOIUrl":null,"url":null,"abstract":"<div><p>In the title compound, the di­hydro­quinoxaline units are both essentially planar and the dihedral angle between their mean planes is 64.82 (2)°. In the crystal, C—H⋯O hydrogen bonds form chains along the <em>b</em>-axis direction which are joined by π-stacking and C—H⋯π(ring) inter­actions into the full three-dimensional network structure.</p></div><div><p>In the title compound, C<sub>31</sub>H<sub>24</sub>N<sub>4</sub>O<sub>2</sub>, the di­hydro­quinoxaline units are both essentially planar with the dihedral angle between their mean planes being 64.82 (4)°. The attached phenyl rings differ significantly in their rotational orientations with respect to the di­hydro­quinoxaline planes. In the crystal, one set of C—H⋯O hydrogen bonds form chains along the <em>b</em>-axis direction, which are connected in pairs by a second set of C—H⋯O hydrogen bonds. Two sets of π-stacking inter­actions and C—H⋯π(ring) inter­actions join the double chains into the final three-dimensional structure.</p></div>","PeriodicalId":7367,"journal":{"name":"Acta Crystallographica Section E: Crystallographic Communications","volume":"80 6","pages":"Pages 610-614"},"PeriodicalIF":0.5000,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, crystal structure and Hirshfeld surface analysis of 1-[3-(2-oxo-3-phenyl-1,2-di­hydro­quinoxalin-1-yl)prop­yl]-3-phenyl-1,2-di­hydro­quinoxalin-2-one\",\"authors\":\"Nadeem Abad ,&nbsp;Joel T. Mague ,&nbsp;Abdulsalam Alsubari ,&nbsp;El Mokhtar Essassi ,&nbsp;Abdullah Yahya Abdullah Alzahrani ,&nbsp;Youssef Ramli ,&nbsp;L. Van Meervelt (Editor)\",\"doi\":\"10.1107/S2056989024004377\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the title compound, the di­hydro­quinoxaline units are both essentially planar and the dihedral angle between their mean planes is 64.82 (2)°. In the crystal, C—H⋯O hydrogen bonds form chains along the <em>b</em>-axis direction which are joined by π-stacking and C—H⋯π(ring) inter­actions into the full three-dimensional network structure.</p></div><div><p>In the title compound, C<sub>31</sub>H<sub>24</sub>N<sub>4</sub>O<sub>2</sub>, the di­hydro­quinoxaline units are both essentially planar with the dihedral angle between their mean planes being 64.82 (4)°. The attached phenyl rings differ significantly in their rotational orientations with respect to the di­hydro­quinoxaline planes. In the crystal, one set of C—H⋯O hydrogen bonds form chains along the <em>b</em>-axis direction, which are connected in pairs by a second set of C—H⋯O hydrogen bonds. Two sets of π-stacking inter­actions and C—H⋯π(ring) inter­actions join the double chains into the final three-dimensional structure.</p></div>\",\"PeriodicalId\":7367,\"journal\":{\"name\":\"Acta Crystallographica Section E: Crystallographic Communications\",\"volume\":\"80 6\",\"pages\":\"Pages 610-614\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2024-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Crystallographica Section E: Crystallographic Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2056989024001282\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section E: Crystallographic Communications","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2056989024001282","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0

摘要

在标题化合物 C31H24N4O2 中,二氢喹喔啉单元基本上都是平面的,其平均平面之间的二面角为 64.82 (4)°。附着的苯基环相对于二氢喹喔啉平面的旋转方向差异很大。在晶体中,一组 C-H...O 氢键沿 b 轴方向形成链,这些链通过第二组 C-H...O 氢键成对连接。两组 π 堆积相互作用和 C-H...π(环)相互作用将双链连接成最终的三维结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Synthesis, crystal structure and Hirshfeld surface analysis of 1-[3-(2-oxo-3-phenyl-1,2-di­hydro­quinoxalin-1-yl)prop­yl]-3-phenyl-1,2-di­hydro­quinoxalin-2-one

In the title compound, the di­hydro­quinoxaline units are both essentially planar and the dihedral angle between their mean planes is 64.82 (2)°. In the crystal, C—H⋯O hydrogen bonds form chains along the b-axis direction which are joined by π-stacking and C—H⋯π(ring) inter­actions into the full three-dimensional network structure.

In the title compound, C31H24N4O2, the di­hydro­quinoxaline units are both essentially planar with the dihedral angle between their mean planes being 64.82 (4)°. The attached phenyl rings differ significantly in their rotational orientations with respect to the di­hydro­quinoxaline planes. In the crystal, one set of C—H⋯O hydrogen bonds form chains along the b-axis direction, which are connected in pairs by a second set of C—H⋯O hydrogen bonds. Two sets of π-stacking inter­actions and C—H⋯π(ring) inter­actions join the double chains into the final three-dimensional structure.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
1.90
自引率
0.00%
发文量
351
审稿时长
3 weeks
期刊介绍: Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.
期刊最新文献
Foreword to the AfCA collection: celebrating work published by African researchers in IUCr journals. Synthesis, crystal structure and Hirshfeld surface of ethyl 2-[2-(methyl­sulfan­yl)-5-oxo-4,4-diphenyl-4,5-di­hydro-1H-imidazol-1-yl]acetate (thio­phenytoin derivative) Synthesis, crystal structure and Hirshfeld surface analysis of 1-[(1-octyl-1H-1,2,3-triazol-4-yl)methyl]-3-phenyl-1,2-di­hydro­quinoxalin-2(1H)-one Crystal structure of bis­(β-alaninium) tetra­bromidoplumbate Puckering effects of 4-hy­droxy-l-proline isomers on the conformation of ornithine-free Gramicidin S
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1