Nadeem Abad , Joel T. Mague , Abdulsalam Alsubari , El Mokhtar Essassi , Abdullah Yahya Abdullah Alzahrani , Youssef Ramli , L. Van Meervelt (Editor)
{"title":"1-[3-(2-氧代-3-苯基-1,2-二氢喹喔啉-1-基)丙基]-3-苯基-1,2-二氢喹喔啉-2-酮的合成、晶体结构和 Hirshfeld 表面分析","authors":"Nadeem Abad , Joel T. Mague , Abdulsalam Alsubari , El Mokhtar Essassi , Abdullah Yahya Abdullah Alzahrani , Youssef Ramli , L. Van Meervelt (Editor)","doi":"10.1107/S2056989024004377","DOIUrl":null,"url":null,"abstract":"<div><p>In the title compound, the dihydroquinoxaline units are both essentially planar and the dihedral angle between their mean planes is 64.82 (2)°. In the crystal, C—H⋯O hydrogen bonds form chains along the <em>b</em>-axis direction which are joined by π-stacking and C—H⋯π(ring) interactions into the full three-dimensional network structure.</p></div><div><p>In the title compound, C<sub>31</sub>H<sub>24</sub>N<sub>4</sub>O<sub>2</sub>, the dihydroquinoxaline units are both essentially planar with the dihedral angle between their mean planes being 64.82 (4)°. The attached phenyl rings differ significantly in their rotational orientations with respect to the dihydroquinoxaline planes. In the crystal, one set of C—H⋯O hydrogen bonds form chains along the <em>b</em>-axis direction, which are connected in pairs by a second set of C—H⋯O hydrogen bonds. Two sets of π-stacking interactions and C—H⋯π(ring) interactions join the double chains into the final three-dimensional structure.</p></div>","PeriodicalId":7367,"journal":{"name":"Acta Crystallographica Section E: Crystallographic Communications","volume":"80 6","pages":"Pages 610-614"},"PeriodicalIF":0.5000,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, crystal structure and Hirshfeld surface analysis of 1-[3-(2-oxo-3-phenyl-1,2-dihydroquinoxalin-1-yl)propyl]-3-phenyl-1,2-dihydroquinoxalin-2-one\",\"authors\":\"Nadeem Abad , Joel T. Mague , Abdulsalam Alsubari , El Mokhtar Essassi , Abdullah Yahya Abdullah Alzahrani , Youssef Ramli , L. Van Meervelt (Editor)\",\"doi\":\"10.1107/S2056989024004377\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the title compound, the dihydroquinoxaline units are both essentially planar and the dihedral angle between their mean planes is 64.82 (2)°. In the crystal, C—H⋯O hydrogen bonds form chains along the <em>b</em>-axis direction which are joined by π-stacking and C—H⋯π(ring) interactions into the full three-dimensional network structure.</p></div><div><p>In the title compound, C<sub>31</sub>H<sub>24</sub>N<sub>4</sub>O<sub>2</sub>, the dihydroquinoxaline units are both essentially planar with the dihedral angle between their mean planes being 64.82 (4)°. The attached phenyl rings differ significantly in their rotational orientations with respect to the dihydroquinoxaline planes. In the crystal, one set of C—H⋯O hydrogen bonds form chains along the <em>b</em>-axis direction, which are connected in pairs by a second set of C—H⋯O hydrogen bonds. Two sets of π-stacking interactions and C—H⋯π(ring) interactions join the double chains into the final three-dimensional structure.</p></div>\",\"PeriodicalId\":7367,\"journal\":{\"name\":\"Acta Crystallographica Section E: Crystallographic Communications\",\"volume\":\"80 6\",\"pages\":\"Pages 610-614\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2024-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Crystallographica Section E: Crystallographic Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2056989024001282\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section E: Crystallographic Communications","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2056989024001282","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
Synthesis, crystal structure and Hirshfeld surface analysis of 1-[3-(2-oxo-3-phenyl-1,2-dihydroquinoxalin-1-yl)propyl]-3-phenyl-1,2-dihydroquinoxalin-2-one
In the title compound, the dihydroquinoxaline units are both essentially planar and the dihedral angle between their mean planes is 64.82 (2)°. In the crystal, C—H⋯O hydrogen bonds form chains along the b-axis direction which are joined by π-stacking and C—H⋯π(ring) interactions into the full three-dimensional network structure.
In the title compound, C31H24N4O2, the dihydroquinoxaline units are both essentially planar with the dihedral angle between their mean planes being 64.82 (4)°. The attached phenyl rings differ significantly in their rotational orientations with respect to the dihydroquinoxaline planes. In the crystal, one set of C—H⋯O hydrogen bonds form chains along the b-axis direction, which are connected in pairs by a second set of C—H⋯O hydrogen bonds. Two sets of π-stacking interactions and C—H⋯π(ring) interactions join the double chains into the final three-dimensional structure.
期刊介绍:
Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.