甲醇羰基化生产醋酸工艺综述

Qingyi Yan
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摘要

酸性腐蚀在化合物业务中发挥着重要作用,尤其是在新型物质纤维的生产中。目前,制造酸性腐蚀剂的主要技术是利用铱或铑的有机金属结构对甲醇进行羰基化反应。本文从均相催化和异相催化两部分对甲醇羰基化制备酸性腐蚀剂的代表技术和最新进展进行了有效探讨。首先介绍了目前使用两种不同催化体系的均相催化法和异相催化合成法,然后按时间顺序介绍了化学工业史上甲醇羰基化生产醋酸的传统方法。研究了使用传统技术生产醋酸的主要问题,包括产品分离和昂贵的催化剂回收。这些问题可以通过开发和完善异相催化系统来解决。对传统技术的优点和缺点进行了分析,对以前的研究进行了全面总结和批判性分析,提供了全面的背景知识,未来的探索方向是研究异质增效剂框架,以实现更高的选择性和保存率,并努力提高经济效益。
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A review of process of methanol carbonylation to produce acetic acid
Acidic corrosion plays a significant part in the compound business, particularly in the production of new substance fiber. As of now, the primary technique for creating acidic corrosive is the carbonylation of methanol utilizing iridium or rhodium organometallic edifices. The delegate techniques and the most recent advancement of methanol carbonylation to deliver acidic corrosion from two parts of homogeneous catalysis and heterogeneous catalysis are explored efficiently. The present homogeneous catalytic method and heterogeneous catalytic synthesis method using two different catalytic systems are introduced, followed in chronological order by the traditional method of producing acetic acid by carbonylation of methanol in the history of the chemical industry. The primary issues with producing acetic acid using conventional techniques are examined, including the product separation and the costly catalyst recovery. These issues can be resolved by developing and perfecting heterogeneous catalytic systems. The benefits and drawbacks of conventional techniques are broken down, the comprehensive summary and critical analysis of previous research provide comprehensive background knowledge, and the future exploration bearing is to work on the heterogeneous synergist framework to accomplish higher selectivity and preservation rate and work on financial proficiency.
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