锂离子电池负极材料的特性和性能

Xinghao Lu
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摘要

锂离子二次电池 (LIB) 是一种高能量密度的电池系统。它们是当今信息丰富的移动社会便携、娱乐、计算和电信技术的重要组成部分。1981 年以后,大多数负极材料研究主要集中在含锂负极上,如 LiAl 合金、LiC 合金等。这些材料价格高、循环性能不稳定,难以实现商业化。LIB 的成功商业化始于 1991 年 SONY 公司生产的石油焦基阳极材料。其中,阳极在 LIB 中起着至关重要的作用。已实现商业化的负极材料包括碳、合金和钛酸锂。使用碳负极材料和钛酸锂负极材料的锂离子电池可以在一定程度上满足电动汽车(EV)和大规模储能应用的需求,而合金负极材料则可以提高锂离子电池的能量密度。本文介绍了商业化阳极材料的特性。本文还介绍了下一代阳极材料,如硅阳极材料。
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Characteristics and properties of anode materials for lithium-ion batteries
Lithium-ion secondary batteries (LIBs) are battery systems with high energy densities. They are essential components of todays information-rich, mobile societys portable, entertainment, computing, and telecommunications technology. After 1981, most of the research on anode materials mainly focused on the anode containing Li, such as LiAl alloy, LiC alloy, etc. These materials have high prices, unstable cycling performance, and are difficult to be commercialized. The successful commercialization of LIBs began in 1991 with SONYs manufacturing of petroleum coke-based anode materials. Among them, anode plays a crucial role in LIBs. Anode materials that have been commercialized include carbon, alloys, and lithium titanate. Lithium-ion batteries using carbon anode materials and lithium titanate anode materials can meet the needs of electric vehicles (EVs) and large-scale energy storage applications to a certain extent, and alloy anode materials can promote the energy density of LIBs. The properties of the commercialized anode materials are covered in this paper. Next generation anode materials such as silicon anode materials are also introduced.
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