通过二氧化碳与环氧化物的光驱动羧化反应合成羟基酸

IF 1.4 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Chemistry Letters Pub Date : 2024-05-06 DOI:10.1093/chemle/upae086

Chihiro Maeda, Ren Kumemoto, Rio Tanaka, Tadashi Ema

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引用次数: 0

摘要

环氧化物与二氧化碳的光驱动开环羧化反应通过顺序单电子转移（SET）提供了 β-羟基酸，随后与二氧化碳发生反应。这种反应条件适用于芳基环氧化物和含有（杂）多环芳烃的氧杂环丁烷，可分别得到相应的 β- 和 γ- 羟基酸，且化学选择性高。

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Synthesis of Hydroxy Acids via the Light-Driven Carboxylation of Epoxides with CO2

Light-driven ring-opening carboxylation of epoxides with CO2 provided β-hydroxy acids via the sequential single electron transfer (SET), followed by the reaction with CO2. This reaction condition was applicable to aryl epoxides and oxetanes with (hetero)polycyclic aromatics to give the corresponding β- and γ-hydroxy acids, respectively, with the high chemoselectivity.

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来源期刊

Chemistry Letters 化学-化学综合

CiteScore

3.00

自引率

6.20%

发文量

260

审稿时长

1.2 months

期刊介绍： Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry