粉煤灰作为添加剂对转酯化楝树油粘度的影响

Mubarak Musa Zakari, Auwalu Musa, U. I. Ismail
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摘要

生物柴油作为一种可再生能源,已成为解决使用化石燃料发电相关问题的替代方案之一。大多数通过坦塞斯特化工艺生产的生物柴油的粘度都超过了柴油的极限。使用固体材料作为添加剂可以缓解这一问题。本文研究了粉煤灰作为添加剂对转酯化楝树油粘度的影响。使用扫描电子显微镜(SEM)和 X 射线荧光分析仪(XRF)对粉煤灰的形态和化学成分进行了研究。对粗楝树油进行提纯、酯交换,并使用 0.1wt%、0.2wt%、0.3wt%、0.4wt% 和 0.5wt% 的粉煤灰作为添加剂。使用布鲁克菲尔德数字粘度计测量了粗酯、纯化酯、转酯和添加 0.1wt%、0.2wt%、0.3wt%、0.5wt% 和 0.5wt% 粉煤灰的转酯的粘度。扫描电子显微镜显示,粉煤灰的结构为分散颗粒,结构浑浊;XRF 显示,粉煤灰中的主要化合物为氧化硅。样品的粘度随着温度的升高和粉煤灰的添加而降低。但当添加量为 0.3wt% 时,在相同的温度范围内,粘度有显著变化。这表明粉煤灰可用作楝树油的生物柴油添加剂,因为它会降低油的粘度水平。
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Influence of fly ash as additive on the viscosity of transesterified neem oil
Biodiesel as the renewable source of energy has become one of the alternative solutions towards the problems associated with the use of fossil fuels in energy generation. Most of the biodiesel produced via tansesterification process are associated with viscosity that is above diesel limit. This problem can be mitigated through the use of solid materials as additive. This paper investigates the influence of fly ash as additive on the viscosity of transesterified neem oil. The morphology and chemical constituent of fly ash were studied using Scanning Electron Microscopy (SEM) and Xray Fluoroscopy (XRF). The crude neem oil was purified; transesterified and 0.1 wt%, 0.2 wt%, 0.3wt%, 0.4wt% and 0.5wt% of fly ash were used as additive. The viscosity of crude, purified, transesterified and transesterified with 0.1 wt%, 0.2 wt%, 0.3wt%, 0.5wt% and 0.5wt% of fly ash as additive were measured using brookfield digital viscometer. SEM shows that the mophorlogy of fly ash was dispersed particle with cloudy structure while XRF shows that the major compound presence on fly ash was silicon oxide. The viscosity of the samples decreases as the temperature increases and with the addition of fly ash. But on the addition of 0.3wt% it shows significant variation at equal range of temperature. This indicated that the fly ash can be used as biodiesel additive on neem oil as it decreases the level of viscosity presence on the oil.
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