研究混合纳米填料含量对环氧基纳米复合材料的 X 射线衍射和导热性能的影响

Hajer Alhussiny, M. Albozahid
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摘要

使用不同尺寸纳米填料的高性能聚合物纳米复合材料最近引起了广泛关注。因为它们具有独特的结构和热特性。多壁碳纳米管(MWCNT)和纳米粘土(NC)作为聚合物的填料元素,在众多增强材料中最受关注。本研究评估了不同负载量(0.5%、1% 和 2wt%)的多壁碳纳米管和纳米粘土形成的混合体对环氧聚合物特性的影响。试样采用溶液混合程序制作,在分散纳米填料时加入比例为 1:1 的溶剂乙醇,然后与环氧树脂重新混合。X 射线衍射(XRD)和热导率等测试用于确定环氧树脂的特性。测试结果表明,在填料含量为 1wt% 时,热导率随着填料含量的增加而上升,1wt% 后开始下降。混合填料含量为 1wt% 的样品性能最佳。由于混合环氧树脂的热导率比 MWNT 高出 135%,因此混合环氧树脂的热导率最佳,而 NC 纳米复合材料的热导率在 1 wt.% 时达到 0.3568 W/m.K。通过观察 EP 纳米复合材料的 XRD 图谱。环氧纳米复合材料的混合物显示出所有 NC 和 MWCNT 的特征峰。由于填料与环氧树脂之间的相互作用会导致 1wt% 的峰值位置发生偏移。由于纳米填料在整个环氧基体中的均匀性,在 2θ= 20.13°(相当于层间距离 d=0.461nm)为 1%时,峰的强度或位置可能会发生变化。
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Study the Effect of Hybrid Nanofillers Content on the X-ray Diffraction and Thermal Conductivity Properties of Epoxy-Based Nanocomposites
High-performance polymer nanocomposites utilizing different-sized nanofillers had a lot of interest recently. Due to their distinct structural, and thermal characteristics. Multi-wall carbon nanotubes (MWCNT) and nanoclay (NC) have the most interest among the numerous types of reinforcing as filler elements for a polymer. The formation of hybrid from MWCNT and NC at various loadings (0.5%, 1%, and 2wt%) on the characteristics of epoxy polymer have been assessed in this work. The specimens have been created using solution blending procedures with the addition of solvent ethanol at a ratio of 1:1 for dispersed nanofillers, and then they have been re-mixed with epoxy. Tests like X-Ray diffraction (XRD), and thermal conductivity were used to identify properties of epoxy. According to the test results, the thermal conductivity rise as the filler content rises at 1wt%, then start to decrease after 1wt%. The sample with the hybrid filler loading of 1 wt% produced the best performance. Since hybrid epoxy exhibits the best result of the thermal conductivity 135% over MWNT and NC nanocomposites of 1 wt.% reached 0.3568 W/m.K in the increased thermal conductivity property. By examining the EP nanocomposites XRD pattern. The hybrid of epoxy nanocomposites exhibits all of the NC and MWCNT characteristic peaks. Since interactions between the filler and the epoxy cause a shift in the peak location of 1wt%. Due to the homogeneity of the nanofillers entire epoxy matrix, there may be changes in the intensity or location of the peaks at 1% for 2θ= 20.13°, which corresponds to an interlayer distance of d=0.461nm.
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