用于透明可穿戴传感器的生物兼容聚合物上的高柔性透明非晶掺铟氧化锡

Yu-Kyung Oh , Minchul Sung , Jin Woong Kim , Han-Ki Kim
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摘要

利用直流磁控溅射技术在室温下在柔性和生物兼容的环烯烃聚合物(COP)基底上沉积的高透明柔性非晶掺杂锡 In2O3(a-ITO)薄膜被用作透明可穿戴传感器的柔性透明电极。通过改变直流电功率、工作压力、氧气流速和 a-ITO 厚度,计算了优点值 (FoM),以确定 a-ITO 电极的最佳溅射工艺。优化后的 a-ITO/COP 具有 8.9 的高 FoM 值,其薄片电阻低至 36 欧姆/平方,在可见光波长区域的平均透射率为 89.5%,临界弯曲半径小至 7 毫米,是可用于制造可穿戴和透明可穿戴传感器的透明电极。为了证明 a-ITO/COP 衬底作为一种有前途的可穿戴传感器的可行性,我们对可穿戴温度传感器、可穿戴加热器和可穿戴葡萄糖传感器的性能进行了研究。基于 a-ITO/COP 的高灵敏度温度传感器、6 V 饱和温度为 87.8 ℃ 的透明加热器和高灵敏度葡萄糖传感器的成功运行表明,a-ITO/COP 是下一代可穿戴仿生电子产品中一种很有前途的生物兼容电极。
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Highly flexible and transparent amorphous indium doped tin oxide on bio-compatible polymers for transparent wearable sensors

Highly transparent and flexible amorphous Sn-doped In2O3 (a-ITO) films deposited on flexible and bio-compatible cyclic olefin polymer (COP) substrate using a direct-current magnetron sputtering at room temperature were used as flexible and transparent electrodes for transparent wearable sensors. The figure of merits (FoM) value was calculated to determine the optimal sputtering process for the a-ITO electrodes by varying the direct current power, working pressure, oxygen flow rate, and a-ITO thickness. The optimized a-ITO/COP with a high FoM value of 8.9 exhibited a low sheet resistance of 36 Ohm/square, average transmittances of 89.5 % in the visible wavelength region, and a small critical bending radius of 7 mm, which are acceptable transparent electrodes for fabrication of wearable and transparent wearable sensors. To demonstrate the feasibility of the a-ITO/COP substrate as a promising wearable sensor, we examined the performance of wearable temperature sensors, wearable heaters, and wearable glucose sensors. The successful operation of a-ITO/COP-based temperature sensors with high sensitivity, transparent heaters with a saturation temperature of 87.8 °C at 6 V, and glucose sensors with high sensitivity indicates that a-ITO/COP is a promising bio-compatible electrode for next-generation wearable bionic electronics.

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