垂直超声振动下 Cu/Sn/Cu 互连系统中 Cu6Sn5 金属间化合物的非对称生长

IF 4.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Intermetallics Pub Date : 2024-05-25 DOI:10.1016/j.intermet.2024.108337
H.W. Niu , H. Bian , X. Liu , X.G. Song , H.Y. Zhao
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引用次数: 0

摘要

在垂直超声波振动的辅助下,研究了瞬态液相(TLP)焊接过程中 Cu/Sn/Cu 互连系统中 Cu6Sn5 金属间化合物(IMC)的非对称生长。与无超声波(USW)等温老化过程中的对称生长不同,在垂直超声波的作用下,Cu6Sn5 在上锡/下铜界面的生长高度不对称,即在上锡/下铜界面(超声波作用的一侧),Cu6Sn5 晶粒呈现扇贝型形态,并且是离散的;而在下锡/下铜界面(超声波作用的另一侧),Cu6Sn5 晶粒呈现柱型形态,并且是连在一起的。在 USW 的辅助下,Cu6Sn5 晶粒明显细化,接头的剪切强度提高,断裂模式从跨晶断裂转变为跨晶和晶间断裂。这种反常行为完全归因于整个锡中间层的非对称超声效应。
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Asymmetric growth of Cu6Sn5 intermetallic compound in Cu/Sn/Cu interconnection system under the vertical ultrasonic vibration

The asymmetric growth of Cu6Sn5 intermetallic compound (IMC) in a Cu/Sn/Cu interconnection system was studied during the transient liquid phase (TLP) soldering process with the assistance of the vertical ultrasonic vibration. Being different from the symmetrical growth during isothermal aging without ultrasonic waves (USW), highly asymmetrical growth of Cu6Sn5 at the upper and down Sn/Cu interfaces was observed with the vertical USW, i.e., Cu6Sn5 grains exhibited scallop-type morphology, and were discrete at the upper Sn/Cu interface (the side of ultrasonic action); while that at the lower Sn/Cu interface (the opposite side of ultrasonic action) exhibited column-type morphology, and were conterminous. Under the assistance of USW, the Cu6Sn5 grains were remarkably refined, the shear strength of joint was increased, and the fracture mode was changed from transgranular fracture to transgranular and intergranular fracture. This anomalous behavior can be completely ascribed to the asymmetrical ultrasonic effects across the entire Sn the intermediate layer of Sn.

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来源期刊
Intermetallics
Intermetallics 工程技术-材料科学:综合
CiteScore
7.80
自引率
9.10%
发文量
291
审稿时长
37 days
期刊介绍: This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys. The journal reports the science and engineering of metallic materials in the following aspects: Theories and experiments which address the relationship between property and structure in all length scales. Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations. Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties. Technological applications resulting from the understanding of property-structure relationship in materials. Novel and cutting-edge results warranting rapid communication. The journal also publishes special issues on selected topics and overviews by invitation only.
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