{"title":"同分异构双核四面体铜（I）配合物的存在及其与 [NiCl2(PPh3)2] 的反应","authors":"P. Kalaivani , F. Dallemer , R. Prabhakaran","doi":"10.1016/j.cinorg.2024.100057","DOIUrl":null,"url":null,"abstract":"<div><p>Reaction between 2-hydroxy-1-naphthaldehyde thiosemicarbazone and square planar dichloro bis triphenylphosphine Cu(II) resulted in two structurally different binuclear Cu(I) tetrahedral complexes which are co-crystallized together by exhibiting bonding isomerism. The reaction of co-crystallized complexes with [NiCl<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>] led to C–S and Cu–S activation of coordinated ligand to form [Cu<sub>2</sub>(μ<sub>2</sub>-Cl<sub>2</sub>)(PPh<sub>3</sub>)<sub>3</sub>] and [Cu<sub>2</sub>(μ<sub>2</sub>-S<sub>2</sub>)(PPh<sub>3</sub>)<sub>3</sub>] respectively along with a square planar [Ni(nap-tsc)(PPh<sub>3</sub>)] (where, nap-tsc =2-hydroxy-1-naphthaldehyde thiosemicarbazone) and triphenylphosphine sulfide.</p></div>","PeriodicalId":100233,"journal":{"name":"Chemistry of Inorganic Materials","volume":"3 ","pages":"Article 100057"},"PeriodicalIF":0.0000,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949746924000259/pdfft?md5=bf31a6f61cf30a3e041a31c896b262a7&pid=1-s2.0-S2949746924000259-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Co existence of isomeric binuclear tetrahedral Cu(I) complexes and their reaction with [NiCl2(PPh3)2]\",\"authors\":\"P. Kalaivani , F. Dallemer , R. Prabhakaran\",\"doi\":\"10.1016/j.cinorg.2024.100057\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Reaction between 2-hydroxy-1-naphthaldehyde thiosemicarbazone and square planar dichloro bis triphenylphosphine Cu(II) resulted in two structurally different binuclear Cu(I) tetrahedral complexes which are co-crystallized together by exhibiting bonding isomerism. The reaction of co-crystallized complexes with [NiCl<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>] led to C–S and Cu–S activation of coordinated ligand to form [Cu<sub>2</sub>(μ<sub>2</sub>-Cl<sub>2</sub>)(PPh<sub>3</sub>)<sub>3</sub>] and [Cu<sub>2</sub>(μ<sub>2</sub>-S<sub>2</sub>)(PPh<sub>3</sub>)<sub>3</sub>] respectively along with a square planar [Ni(nap-tsc)(PPh<sub>3</sub>)] (where, nap-tsc =2-hydroxy-1-naphthaldehyde thiosemicarbazone) and triphenylphosphine sulfide.</p></div>\",\"PeriodicalId\":100233,\"journal\":{\"name\":\"Chemistry of Inorganic Materials\",\"volume\":\"3 \",\"pages\":\"Article 100057\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-05-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2949746924000259/pdfft?md5=bf31a6f61cf30a3e041a31c896b262a7&pid=1-s2.0-S2949746924000259-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry of Inorganic Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2949746924000259\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Inorganic Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2949746924000259","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Co existence of isomeric binuclear tetrahedral Cu(I) complexes and their reaction with [NiCl2(PPh3)2]
Reaction between 2-hydroxy-1-naphthaldehyde thiosemicarbazone and square planar dichloro bis triphenylphosphine Cu(II) resulted in two structurally different binuclear Cu(I) tetrahedral complexes which are co-crystallized together by exhibiting bonding isomerism. The reaction of co-crystallized complexes with [NiCl2(PPh3)2] led to C–S and Cu–S activation of coordinated ligand to form [Cu2(μ2-Cl2)(PPh3)3] and [Cu2(μ2-S2)(PPh3)3] respectively along with a square planar [Ni(nap-tsc)(PPh3)] (where, nap-tsc =2-hydroxy-1-naphthaldehyde thiosemicarbazone) and triphenylphosphine sulfide.
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