使用商用炭黑作为催化剂进行过氧化氢电合成:表面特性和吸附性能的影响

IF 2.8 4区 生物学 Q3 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Journal of chemical technology and biotechnology Pub Date : 2024-05-24 DOI:10.1002/jctb.7680
Xinyu Han, Shiyu Yuan, Zhaolian Zhu, Jiawen Mei, Qiyuan Huang, Liya Ji, Hailing Wang
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引用次数: 0

摘要

碳材料的表面特性和吸附性能在电化学双电子氧还原产生 H2O2 的过程中起着至关重要的作用。然而,目前在这一领域还缺乏对商用炭黑的深入研究。本文采用四种典型的商用炭黑(乙炔黑(AB)、Ketjen 黑 EC 600JD、Vulcan XC 72 和 Black Pearls 2000)作为阴极催化剂来生成 H2O2。对四种炭黑电极的表面化学性质和孔隙结构进行了系统表征,并研究了它们对 H2O2 吸附、电化学生成和降解的影响。在四种炭黑中,AB 的 C-O-C/COOH 和 CO 含量最高,它们是催化双电子氧还原反应生成 H2O2 的活性基团。AB 具有最低的缺陷水平和最高的石墨化程度,AB 改性石墨毡电极(AB-Ele)具有最大的平均孔径、最小的比表面积和较小的电荷转移电阻。总之,丰富的含氧官能团(如 C-O-C、COOH 和 CO)、高石墨化程度、合适的比表面积和孔隙率以及弱 H2O2 吸附性能有利于双电子氧还原反应生成 H2O2。AB 改性石墨毡电极在 H2O2 电合成中表现出良好的催化活性和可重复使用性,具有广阔的应用前景。© 2024 化学工业学会(SCI)。
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Hydrogen peroxide electrosynthesis using commercial carbon blacks as catalysts: the influence of surface properties and adsorption performance

BACKGROUND

Surface properties and adsorption performance of carbon materials play a crucial role in the electrochemical two-electron oxygen reduction to produce H2O2. However, there is still a lack of in-depth research on commercial carbon blacks in this area. Herein, four typical commercial carbon blacks (Acetylene black (AB), Ketjen black EC 600JD, Vulcan XC 72 and Black Pearls 2000) were used as cathode catalysts to generate H2O2. Surface chemistry and pore structure of electrodes of the four carbon blacks were systematically characterized, and their effects on H2O2 adsorption, electrochemical generation and degradation were investigated.

RESULTS

Among the four carbon blacks, AB has the highest content of C–O–C/COOH and CO, which are active groups catalyzing the two-electron oxygen reduction reaction to generate H2O2. AB has the lowest level of defects and highest degree of graphitization, and AB-modified graphite felt electrode (AB-Ele) has the largest average pore diameter, smallest specific surface area and smaller charge transfer resistance. H2O2 production using AB-Ele is the largest and reaches 567.7 mg L−1 at 180 min under a current density of 5 mA cm−2, and only decreases by 17.6% after 10 repeated uses.

CONCLUSION

Overall, rich oxygen-containing functional groups such as C–O–C, COOH and CO, high degree of graphitization, suitable surface area and porosity as well as weak H2O2 adsorption performance are beneficial for the two-electron oxygen reduction reaction to generate H2O2. AB-modified graphite felt electrode exhibits good catalytic activity and reusability in H2O2 electrosynthesis, demonstrating promising application prospects. © 2024 Society of Chemical Industry (SCI).

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来源期刊
CiteScore
7.00
自引率
5.90%
发文量
268
审稿时长
1.7 months
期刊介绍: Journal of Chemical Technology and Biotechnology(JCTB) is an international, inter-disciplinary peer-reviewed journal concerned with the application of scientific discoveries and advancements in chemical and biological technology that aim towards economically and environmentally sustainable industrial processes.
期刊最新文献
Issue Information Adsorption behavior of graphite‐like walnut shell biochar modified with ammonia for ciprofloxacin in aqueous solution Eco‐friendly approaches for synthesis of indolyl 1H‐pyrroles using rice‐husk‐derived carbonaceous sulfonation as the green catalyst Impact of neutrophil‐activating protein conservation on diagnostic tests and vaccine design Issue Information
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