用纳米纤维素稳定的银纳米粒子作为检测汞 (II) 的传感探针及其在铁 (III) 干扰下的反应

IF 4.9 2区 工程技术 Q1 MATERIALS SCIENCE, PAPER & WOOD Cellulose Pub Date : 2024-05-22 DOI:10.1007/s10570-024-05963-0
Junya Jettanasen, Pavara Silakhao, Sunisa Lohakarok, Banthittaya Poka, Peerada Yingyuad
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引用次数: 0

摘要

本研究的重点是纳米纤维素稳定银纳米粒子(AgNPs)作为比色传感探针在汞(II)检测中的应用。为此,研究人员采用了具有双重功能的纤维素纳米晶体(CNCs)和纤维素纳米纤维(CNFs):稳定剂和分散基质。通过 XRD、傅立叶变换红外光谱、TEM 和紫外可见光谱等多种技术分析了样品的化学和结构特性。由于每种纳米纤维素的形态和表面官能团不同,研究了它们对 AgNP 形成的影响及其对汞(II)离子的反应。研究发现,两种纳米纤维素稳定的 AgNPs 对汞(II)离子都具有很高的灵敏度和选择性。不过,也观察到了铁(III)离子造成的一些干扰。如果在制备 AgNP 的过程中使用 CNF,这种干扰会大大减少。因此,我们将详细讨论使用 CNFs 作为稳定剂和分散基质的优势。此外,还将展示将 CNFs 制成固态平台(纳米纸)的可能性以及对汞(II)离子的反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Silver nanoparticles stabilized by nanocellulose as a sensing probe for mercury (II) detection and their response with iron (III) interference

This research focuses on the application of nanocellulose-stabilized silver nanoparticles (AgNPs) as a colorimetric sensing probe for mercury (II) detection. For this purpose, cellulose nanocrystals (CNCs) and cellulose nanofibers (CNFs) were employed with dual functions: a stabilizing agent and a dispersing matrix. The chemical and structural properties of the samples were analysed by various techniques such as XRD, FTIR, TEM and UV–Vis Spectroscopy. Due to different morphologies and surface functional groups in each type of nanocellulose, their effects on the AgNP formation as well as their response against mercury (II) ions were studied. It was discovered that the AgNPs stabilized by both types of nanocellulose can provide high sensitivity and selectivity towards mercury (II) ions. However, some interference caused by iron (III) ions was observed. This interference could be significantly reduced if the CNFs were employed during the AgNP preparation. Therefore, the advantage of using the CNFs as a stabilizing agent as well as a dispersing matrix will be discussed in detail. Furthermore, the possibility of fabrication into solid-state platforms (nanopapers) and response to mercury (II) ions will be demonstrated.

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来源期刊
Cellulose
Cellulose 工程技术-材料科学:纺织
CiteScore
10.10
自引率
10.50%
发文量
580
审稿时长
3-8 weeks
期刊介绍: Cellulose is an international journal devoted to the dissemination of research and scientific and technological progress in the field of cellulose and related naturally occurring polymers. The journal is concerned with the pure and applied science of cellulose and related materials, and also with the development of relevant new technologies. This includes the chemistry, biochemistry, physics and materials science of cellulose and its sources, including wood and other biomass resources, and their derivatives. Coverage extends to the conversion of these polymers and resources into manufactured goods, such as pulp, paper, textiles, and manufactured as well natural fibers, and to the chemistry of materials used in their processing. Cellulose publishes review articles, research papers, and technical notes.
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