{"title":"2-hydroxybenzothiazole substituted cyclotriphosphazenes 的合成：光谱特性","authors":"Saliha Begeç","doi":"10.1080/10426507.2024.2318600","DOIUrl":null,"url":null,"abstract":"<div><p>The nucleophilic substitution reactions of mono- and bis-spiro-2,2’-dioxybiphenyl cyclotriphosphazenes (<strong>1a</strong> and <strong>1b</strong>) with 2-hydroxybenzothiazole (<strong>2</strong>) were performed in the presence of metallic sodium in THF. Two novel 2-oxybenzothiazole-substituted spiro-2,2′-dioxybiphenyl cyclotriphosphazene derivatives (<strong>3a</strong> and <strong>3b</strong>) were obtained from these reactions. Both compounds (<strong>3a, 3b</strong>) have been characterized by elemental analysis as well as by <sup>1</sup>H, <sup>13</sup>C and <sup>31</sup>P NMR spectroscopy. Compounds <strong>3a</strong> and <strong>3b</strong> are reported for the first time in this study.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The syntheses of 2-hydroxybenzothiazole substituted cyclotriphosphazenes: Spectroscopic characterizations\",\"authors\":\"Saliha Begeç\",\"doi\":\"10.1080/10426507.2024.2318600\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The nucleophilic substitution reactions of mono- and bis-spiro-2,2’-dioxybiphenyl cyclotriphosphazenes (<strong>1a</strong> and <strong>1b</strong>) with 2-hydroxybenzothiazole (<strong>2</strong>) were performed in the presence of metallic sodium in THF. Two novel 2-oxybenzothiazole-substituted spiro-2,2′-dioxybiphenyl cyclotriphosphazene derivatives (<strong>3a</strong> and <strong>3b</strong>) were obtained from these reactions. Both compounds (<strong>3a, 3b</strong>) have been characterized by elemental analysis as well as by <sup>1</sup>H, <sup>13</sup>C and <sup>31</sup>P NMR spectroscopy. Compounds <strong>3a</strong> and <strong>3b</strong> are reported for the first time in this study.</p></div>\",\"PeriodicalId\":20056,\"journal\":{\"name\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-04-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1042650724000224\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650724000224","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
The syntheses of 2-hydroxybenzothiazole substituted cyclotriphosphazenes: Spectroscopic characterizations
The nucleophilic substitution reactions of mono- and bis-spiro-2,2’-dioxybiphenyl cyclotriphosphazenes (1a and 1b) with 2-hydroxybenzothiazole (2) were performed in the presence of metallic sodium in THF. Two novel 2-oxybenzothiazole-substituted spiro-2,2′-dioxybiphenyl cyclotriphosphazene derivatives (3a and 3b) were obtained from these reactions. Both compounds (3a, 3b) have been characterized by elemental analysis as well as by 1H, 13C and 31P NMR spectroscopy. Compounds 3a and 3b are reported for the first time in this study.
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Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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