{"title":"以 Al-B-C 作为烧结添加剂的浆料浸渍热压烧结碳化硅纳米纤维/碳化硅复合材料","authors":"Jiyu Tao, Yongwei Lou, Jinxia Li, Hao Chen, Jianjun Chen","doi":"10.1111/ijac.14800","DOIUrl":null,"url":null,"abstract":"<p>Silicon carbide nanofiber/silicon carbide (SiC<sub>nf</sub>/SiC) composites with a laminar stacking structure were prepared by the slurry impregnation hot-press sintering using aluminum (Al) powder, boron (B) powder, and carbon black as sintering aids. SiC<sub>nf</sub> paper was fabricated using nanofibers and impregnated with the slurry of SiC<sub>np</sub> and sintering aids, and the SiC<sub>nf</sub>/SiC preforms were fabricated by the alternating stack of the SiC<sub>nf</sub> paper and SiC<sub>np</sub>. The pyrolysis carbon and boron nitride interface layers were deposited on the surface of SiC<sub>nf</sub> by chemical vapor deposition and vacuum impregnation-pyrolysis methods. The effects of different sintering temperatures on the relative density, porosity, sectional microscopic morphology, and mechanical properties of the composites were investigated. The results show that the fracture toughness of SiC<sub>nf</sub>/SiC composites is significantly improved. The mechanical properties of the composites were optimized at a sintering temperature of 1950°C and a sintering pressure of 30 MPa, with flexural strength and fracture toughness of 548 MPa and 15.86 MPa·m<sup>1/2</sup>, respectively. The liquid phase Al<sub>8</sub>B<sub>4</sub>C<sub>7</sub> compound generated at the high temperature promoted the densification of the composites.</p>","PeriodicalId":13903,"journal":{"name":"International Journal of Applied Ceramic Technology","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Slurry-impregnating hot-press sintered silicon carbide nanofiber/silicon carbide composites with Al-B-C as sintering additives\",\"authors\":\"Jiyu Tao, Yongwei Lou, Jinxia Li, Hao Chen, Jianjun Chen\",\"doi\":\"10.1111/ijac.14800\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Silicon carbide nanofiber/silicon carbide (SiC<sub>nf</sub>/SiC) composites with a laminar stacking structure were prepared by the slurry impregnation hot-press sintering using aluminum (Al) powder, boron (B) powder, and carbon black as sintering aids. SiC<sub>nf</sub> paper was fabricated using nanofibers and impregnated with the slurry of SiC<sub>np</sub> and sintering aids, and the SiC<sub>nf</sub>/SiC preforms were fabricated by the alternating stack of the SiC<sub>nf</sub> paper and SiC<sub>np</sub>. The pyrolysis carbon and boron nitride interface layers were deposited on the surface of SiC<sub>nf</sub> by chemical vapor deposition and vacuum impregnation-pyrolysis methods. The effects of different sintering temperatures on the relative density, porosity, sectional microscopic morphology, and mechanical properties of the composites were investigated. The results show that the fracture toughness of SiC<sub>nf</sub>/SiC composites is significantly improved. The mechanical properties of the composites were optimized at a sintering temperature of 1950°C and a sintering pressure of 30 MPa, with flexural strength and fracture toughness of 548 MPa and 15.86 MPa·m<sup>1/2</sup>, respectively. The liquid phase Al<sub>8</sub>B<sub>4</sub>C<sub>7</sub> compound generated at the high temperature promoted the densification of the composites.</p>\",\"PeriodicalId\":13903,\"journal\":{\"name\":\"International Journal of Applied Ceramic Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-05-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Applied Ceramic Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1111/ijac.14800\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Ceramic Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/ijac.14800","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Slurry-impregnating hot-press sintered silicon carbide nanofiber/silicon carbide composites with Al-B-C as sintering additives
Silicon carbide nanofiber/silicon carbide (SiCnf/SiC) composites with a laminar stacking structure were prepared by the slurry impregnation hot-press sintering using aluminum (Al) powder, boron (B) powder, and carbon black as sintering aids. SiCnf paper was fabricated using nanofibers and impregnated with the slurry of SiCnp and sintering aids, and the SiCnf/SiC preforms were fabricated by the alternating stack of the SiCnf paper and SiCnp. The pyrolysis carbon and boron nitride interface layers were deposited on the surface of SiCnf by chemical vapor deposition and vacuum impregnation-pyrolysis methods. The effects of different sintering temperatures on the relative density, porosity, sectional microscopic morphology, and mechanical properties of the composites were investigated. The results show that the fracture toughness of SiCnf/SiC composites is significantly improved. The mechanical properties of the composites were optimized at a sintering temperature of 1950°C and a sintering pressure of 30 MPa, with flexural strength and fracture toughness of 548 MPa and 15.86 MPa·m1/2, respectively. The liquid phase Al8B4C7 compound generated at the high temperature promoted the densification of the composites.
期刊介绍:
The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas:
Nanotechnology applications;
Ceramic Armor;
Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors);
Ceramic Matrix Composites;
Functional Materials;
Thermal and Environmental Barrier Coatings;
Bioceramic Applications;
Green Manufacturing;
Ceramic Processing;
Glass Technology;
Fiber optics;
Ceramics in Environmental Applications;
Ceramics in Electronic, Photonic and Magnetic Applications;