用 Epipremnum aureum 叶提取物通过绿色合成方法合成的 V2O5 纳米棒的光催化和超级电容器性能透视

IF 4.3 4区 工程技术 Q3 ENERGY & FUELS Biomass Conversion and Biorefinery Pub Date : 2024-05-22 DOI:10.1007/s13399-024-05702-2
Vijay Dubey, Ketan D. Parikh, Devarshi H. Vyas, Ravirajsinh J. Jadav, Hamza Elsayed Ahmed Mohamed, Suresh Ghotekar
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引用次数: 0

摘要

采用绿色环保合成方法,以金穗叶提取物为原料制备了五氧化二钒针状纳米棒。采用XRD、FTIR、UVDRS、FESEM、EDX、HRTEM、BET和XPS等多种分析技术对V2O5核磁共振进行了分析。PXRD图显示V2O5核磁共振具有正交相,HRTEM图证实了V2O5核磁共振的针状结构。在779.2 cm−1的FTIR光谱中检测到V-O-V的拉伸振动。FESEM图像分析证实,合成材料具有纳米棒状形状。结果表明,V2O5 NRs的光带隙为1.83 eV。在可见光照射下,研究了V2O5 NRs对甲基蓝(MB)染料的光催化降解。采用绿色工艺制备的V2O5 nr对MB染料具有良好的光催化活性。此外,利用循环伏安法(CV)、恒流充放电法(GCD)和电化学阻抗谱(EIS)等技术研究了其电化学性能。这些研究结果为超级电容器的应用提供了良好的电容性能。这些发现可能为开发用于储能应用和废水处理的新材料开辟新的途径。
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Insights into the photocatalytic and supercapacitor performance of V2O5 nanorods synthesized by green synthetic approach using Epipremnum aureum leaves extract

Vanadium pentoxide (V2O5) needle-shaped nanorods (NRs) were prepared using an environmentally friendly green synthesis method using Epipremnum aureum leaf extract. Diverse techniques, including XRD, FTIR, UVDRS, FESEM, EDX, HRTEM, BET, and XPS analyses, analyzed the V2O5 NRs. The PXRD pattern revealed that the V2O5 NRs have an orthorhombic phase, and the HRTEM pattern confirmed the needle-shaped NRs' structure. The stretching vibration of V–O-V was detected at 779.2 cm−1 in the FTIR spectrum. FESEM image analysis confirms that the as-synthesized material has a nanorod-like shape. It was observed that the optical bandgap of V2O5 NRs was 1.83 eV. Under visible light irradiation, the photocatalytic degradation study of V2O5 NRs about the Methyl Blue (MB) dye was examined. Excellent photocatalytic activity against MB dye was demonstrated by V2O5 NRs manufactured through a green approach. Further, the electrochemical capabilities have been studied using techniques such as cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS). The results of these studies show excellent capacitance performance for supercapacitor applications. These findings might open up new avenues for developing novel materials for energy storage applications and waste-water treatment.

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来源期刊
Biomass Conversion and Biorefinery
Biomass Conversion and Biorefinery Energy-Renewable Energy, Sustainability and the Environment
CiteScore
7.00
自引率
15.00%
发文量
1358
期刊介绍: Biomass Conversion and Biorefinery presents articles and information on research, development and applications in thermo-chemical conversion; physico-chemical conversion and bio-chemical conversion, including all necessary steps for the provision and preparation of the biomass as well as all possible downstream processing steps for the environmentally sound and economically viable provision of energy and chemical products.
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