{"title":"开发用于海洋生物地球化学循环观测的深海原位阴离子分析仪","authors":"Chao Chen , Feng Lyu , Bangchun Wu , Zhengwei Wu","doi":"10.1016/j.dsr.2024.104326","DOIUrl":null,"url":null,"abstract":"<div><p>A novel deep-sea <em>in-situ</em> anion analyzer (DIAA) is proposed and developed for long-term and continuous observation of marine biogeochemistry and ecology. The DIAA is designed to analyze the concentrations of various anions in seawater, such as F<sup>−</sup>, Cl<sup>−</sup>, Br<sup>−</sup>, NO<sub>3</sub><sup>−</sup>, SO<sub>4</sub><sup>2−</sup>, and PO<sub>4</sub><sup>3−</sup>, based on ion chromatography (IC) technology. The DIAA consists of a control circuit module, a conductivity signal acquisition module, and a flow analysis module. The control circuit module is installed in a sealed pressure-resistant vessel, while the conductivity signal acquisition module and the flow analysis module are housed in a sealed pressure-balanced vessel. The two vessels are capable of functioning at a water depth of up to 4000 m. A seawater <em>in-situ</em> dilution device is designed to solve the issue that the concentrations of Cl<sup>−</sup> and SO<sub>4</sub><sup>2−</sup> in seawater exceeds the IC detection limit. Moreover, an <em>in-situ</em> calibration device enables the DIAA to operate subsea for a long time without recovery. In addition, the DIAA can diagnose and isolate faults automatically. The operation status can be monitored remotely on the shore, and the scientific data can be acquired in real-time. During the sea trial, the DIAA was connected to Monterey Accelerated Research System (MARS) seafloor observatory at a water depth of approximately 900m and operated for six months successfully. The measurement accuracy and the long-term stability of the instrumentation have been verified.</p></div>","PeriodicalId":51009,"journal":{"name":"Deep-Sea Research Part I-Oceanographic Research Papers","volume":"208 ","pages":"Article 104326"},"PeriodicalIF":2.3000,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of a deep-sea in-situ anion analyzer for marine biogeochemical cycle observation\",\"authors\":\"Chao Chen , Feng Lyu , Bangchun Wu , Zhengwei Wu\",\"doi\":\"10.1016/j.dsr.2024.104326\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A novel deep-sea <em>in-situ</em> anion analyzer (DIAA) is proposed and developed for long-term and continuous observation of marine biogeochemistry and ecology. The DIAA is designed to analyze the concentrations of various anions in seawater, such as F<sup>−</sup>, Cl<sup>−</sup>, Br<sup>−</sup>, NO<sub>3</sub><sup>−</sup>, SO<sub>4</sub><sup>2−</sup>, and PO<sub>4</sub><sup>3−</sup>, based on ion chromatography (IC) technology. The DIAA consists of a control circuit module, a conductivity signal acquisition module, and a flow analysis module. The control circuit module is installed in a sealed pressure-resistant vessel, while the conductivity signal acquisition module and the flow analysis module are housed in a sealed pressure-balanced vessel. The two vessels are capable of functioning at a water depth of up to 4000 m. A seawater <em>in-situ</em> dilution device is designed to solve the issue that the concentrations of Cl<sup>−</sup> and SO<sub>4</sub><sup>2−</sup> in seawater exceeds the IC detection limit. Moreover, an <em>in-situ</em> calibration device enables the DIAA to operate subsea for a long time without recovery. In addition, the DIAA can diagnose and isolate faults automatically. The operation status can be monitored remotely on the shore, and the scientific data can be acquired in real-time. During the sea trial, the DIAA was connected to Monterey Accelerated Research System (MARS) seafloor observatory at a water depth of approximately 900m and operated for six months successfully. The measurement accuracy and the long-term stability of the instrumentation have been verified.</p></div>\",\"PeriodicalId\":51009,\"journal\":{\"name\":\"Deep-Sea Research Part I-Oceanographic Research Papers\",\"volume\":\"208 \",\"pages\":\"Article 104326\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2024-05-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Deep-Sea Research Part I-Oceanographic Research Papers\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0967063724000967\",\"RegionNum\":3,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"OCEANOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Deep-Sea Research Part I-Oceanographic Research Papers","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0967063724000967","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OCEANOGRAPHY","Score":null,"Total":0}
Development of a deep-sea in-situ anion analyzer for marine biogeochemical cycle observation
A novel deep-sea in-situ anion analyzer (DIAA) is proposed and developed for long-term and continuous observation of marine biogeochemistry and ecology. The DIAA is designed to analyze the concentrations of various anions in seawater, such as F−, Cl−, Br−, NO3−, SO42−, and PO43−, based on ion chromatography (IC) technology. The DIAA consists of a control circuit module, a conductivity signal acquisition module, and a flow analysis module. The control circuit module is installed in a sealed pressure-resistant vessel, while the conductivity signal acquisition module and the flow analysis module are housed in a sealed pressure-balanced vessel. The two vessels are capable of functioning at a water depth of up to 4000 m. A seawater in-situ dilution device is designed to solve the issue that the concentrations of Cl− and SO42− in seawater exceeds the IC detection limit. Moreover, an in-situ calibration device enables the DIAA to operate subsea for a long time without recovery. In addition, the DIAA can diagnose and isolate faults automatically. The operation status can be monitored remotely on the shore, and the scientific data can be acquired in real-time. During the sea trial, the DIAA was connected to Monterey Accelerated Research System (MARS) seafloor observatory at a water depth of approximately 900m and operated for six months successfully. The measurement accuracy and the long-term stability of the instrumentation have been verified.
期刊介绍:
Deep-Sea Research Part I: Oceanographic Research Papers is devoted to the publication of the results of original scientific research, including theoretical work of evident oceanographic applicability; and the solution of instrumental or methodological problems with evidence of successful use. The journal is distinguished by its interdisciplinary nature and its breadth, covering the geological, physical, chemical and biological aspects of the ocean and its boundaries with the sea floor and the atmosphere. In addition to regular "Research Papers" and "Instruments and Methods" papers, briefer communications may be published as "Notes". Supplemental matter, such as extensive data tables or graphs and multimedia content, may be published as electronic appendices.