利用乙二醇(EG)通过水热技术制备的掺杂 Ce3+/Ho3+ 的 LaPO4 纳米材料用于发光研究

IF 2.218 Q2 Chemistry Chemical Data Collections Pub Date : 2024-06-01 DOI:10.1016/j.cdc.2024.101145
Girija Venkateswara Koneru , Venkata Nagendra Kumar Putta , Sirisha Bandi
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引用次数: 0

摘要

利用水热技术合成了一系列三价 Ce3+/Ho3+ 共掺杂的 LaPO4 纳米磷酸盐,并在(UC)和(DC)模式下均表现出良好的发光品质。在 279-300 纳米波长的激发下,在 365 纳米、460 纳米、542 纳米和 650 纳米波长处出现了直流峰,同时还出现了轻微的非辐射共振能量转移和高度朦胧的 Ho3+ 离子 P-O 电荷转移(CT)带。我们发现,(UC)纳米磷 LaPO4: Ce3+/Ho3+ 允许 980 纳米激光的强烈刺激,从而使 UC 发射光谱显示出突出的 Ho3+ 离子,导致在 460、542 和 650 纳米波长处出现峰值,以及在 300-360 纳米波长处出现微弱的发射峰值。预计这些共掺杂 Ce3+ 和 Ho3+ 离子的单斜 LaPO4 纳米晶体的未来应用将包括更好的光学材料。最终,LaPO4 基质中的共掺杂 Ce3+/Ho3+ 离子纳米磷酸盐的生产和表征将使各行各业(从复杂的显示技术到生物医学成像等)的许多潜在用途成为可能。利用这些纳米晶体的特殊品质实现有用的系统和技术,可能需要在这些领域进行更多的研究和开发。
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Ce3+/Ho3+ doped LaPO4 nanomaterials produced by hydrothermal technique for luminescence studies using ethylene glycol (EG)

Using the Hydrothermal technique, a series of trivalent Ce3+/Ho3+co-doped LaPO4 nanophosphors were synthesised and exhibited good luminous qualities in both the (UC) and (DC) regimes. At 279–300 nm excitation, DC peaks at 365 nm, 460, 542, and 650 nm were seen, along with a minor non-radiative resonance energy transfer and a highly hazy P-O Charge Transfer (CT) band of Ho3+ions. We find that the (UC) nanophosphor LaPO4: Ce3+/Ho3+allows a strong 980 nm laser stimulation, causing the UC emission spectra to exhibit prominent Ho3+ ion resulting in peaks at 460, 542 and 650 nm as well as weak emission peaks at 300–360 nm. Future applications for these co-doped Ce3+ and Ho3+ ion monoclinic LaPO4 nanocrystals are anticipated to include better optical materials. Ultimately, many potential uses in various industries, from sophisticated display technologies to biomedical imaging and beyond, are made possible by the production and characterisation of co-doped Ce3+/Ho3+ ion nanophosphors in LaPO4 matrices. The realisation of useful systems and technologies utilising the special qualities of these nanocrystals may result from more study and development in these fields.

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来源期刊
Chemical Data Collections
Chemical Data Collections Chemistry-Chemistry (all)
CiteScore
6.10
自引率
0.00%
发文量
169
审稿时长
24 days
期刊介绍: Chemical Data Collections (CDC) provides a publication outlet for the increasing need to make research material and data easy to share and re-use. Publication of research data with CDC will allow scientists to: -Make their data easy to find and access -Benefit from the fast publication process -Contribute to proper data citation and attribution -Publish their intermediate and null/negative results -Receive recognition for the work that does not fit traditional article format. The research data will be published as ''data articles'' that support fast and easy submission and quick peer-review processes. Data articles introduced by CDC are short self-contained publications about research materials and data. They must provide the scientific context of the described work and contain the following elements: a title, list of authors (plus affiliations), abstract, keywords, graphical abstract, metadata table, main text and at least three references. The journal welcomes submissions focusing on (but not limited to) the following categories of research output: spectral data, syntheses, crystallographic data, computational simulations, molecular dynamics and models, physicochemical data, etc.
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