{"title":"利用乙二醇(EG)通过水热技术制备的掺杂 Ce3+/Ho3+ 的 LaPO4 纳米材料用于发光研究","authors":"Girija Venkateswara Koneru , Venkata Nagendra Kumar Putta , Sirisha Bandi","doi":"10.1016/j.cdc.2024.101145","DOIUrl":null,"url":null,"abstract":"<div><p>Using the Hydrothermal technique, a series of trivalent Ce<sup>3+</sup>/Ho<sup>3+</sup>co-doped LaPO<sub>4</sub> nanophosphors were synthesised and exhibited good luminous qualities in both the (UC) and (DC) regimes. At 279–300 nm excitation, DC peaks at 365 nm, 460, 542, and 650 nm were seen, along with a minor non-radiative resonance energy transfer and a highly hazy P-O Charge Transfer (CT) band of Ho<sup>3+</sup>ions. We find that the (UC) nanophosphor LaPO<sub>4</sub>: Ce<sup>3+</sup>/Ho<sup>3+</sup>allows a strong 980 nm laser stimulation, causing the UC emission spectra to exhibit prominent Ho<sup>3+</sup> ion resulting in peaks at 460, 542 and 650 nm as well as weak emission peaks at 300–360 nm. Future applications for these co-doped Ce<sup>3+</sup> and Ho<sup>3+</sup> ion monoclinic LaPO<sub>4</sub> nanocrystals are anticipated to include better optical materials. Ultimately, many potential uses in various industries, from sophisticated display technologies to biomedical imaging and beyond, are made possible by the production and characterisation of co-doped Ce<sup>3+</sup>/Ho<sup>3+</sup> ion nanophosphors in LaPO<sub>4</sub> matrices. The realisation of useful systems and technologies utilising the special qualities of these nanocrystals may result from more study and development in these fields.</p></div>","PeriodicalId":269,"journal":{"name":"Chemical Data Collections","volume":"51 ","pages":"Article 101145"},"PeriodicalIF":2.2180,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ce3+/Ho3+ doped LaPO4 nanomaterials produced by hydrothermal technique for luminescence studies using ethylene glycol (EG)\",\"authors\":\"Girija Venkateswara Koneru , Venkata Nagendra Kumar Putta , Sirisha Bandi\",\"doi\":\"10.1016/j.cdc.2024.101145\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Using the Hydrothermal technique, a series of trivalent Ce<sup>3+</sup>/Ho<sup>3+</sup>co-doped LaPO<sub>4</sub> nanophosphors were synthesised and exhibited good luminous qualities in both the (UC) and (DC) regimes. At 279–300 nm excitation, DC peaks at 365 nm, 460, 542, and 650 nm were seen, along with a minor non-radiative resonance energy transfer and a highly hazy P-O Charge Transfer (CT) band of Ho<sup>3+</sup>ions. We find that the (UC) nanophosphor LaPO<sub>4</sub>: Ce<sup>3+</sup>/Ho<sup>3+</sup>allows a strong 980 nm laser stimulation, causing the UC emission spectra to exhibit prominent Ho<sup>3+</sup> ion resulting in peaks at 460, 542 and 650 nm as well as weak emission peaks at 300–360 nm. Future applications for these co-doped Ce<sup>3+</sup> and Ho<sup>3+</sup> ion monoclinic LaPO<sub>4</sub> nanocrystals are anticipated to include better optical materials. Ultimately, many potential uses in various industries, from sophisticated display technologies to biomedical imaging and beyond, are made possible by the production and characterisation of co-doped Ce<sup>3+</sup>/Ho<sup>3+</sup> ion nanophosphors in LaPO<sub>4</sub> matrices. The realisation of useful systems and technologies utilising the special qualities of these nanocrystals may result from more study and development in these fields.</p></div>\",\"PeriodicalId\":269,\"journal\":{\"name\":\"Chemical Data Collections\",\"volume\":\"51 \",\"pages\":\"Article 101145\"},\"PeriodicalIF\":2.2180,\"publicationDate\":\"2024-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Data Collections\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2405830024000338\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Data Collections","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2405830024000338","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Chemistry","Score":null,"Total":0}
Ce3+/Ho3+ doped LaPO4 nanomaterials produced by hydrothermal technique for luminescence studies using ethylene glycol (EG)
Using the Hydrothermal technique, a series of trivalent Ce3+/Ho3+co-doped LaPO4 nanophosphors were synthesised and exhibited good luminous qualities in both the (UC) and (DC) regimes. At 279–300 nm excitation, DC peaks at 365 nm, 460, 542, and 650 nm were seen, along with a minor non-radiative resonance energy transfer and a highly hazy P-O Charge Transfer (CT) band of Ho3+ions. We find that the (UC) nanophosphor LaPO4: Ce3+/Ho3+allows a strong 980 nm laser stimulation, causing the UC emission spectra to exhibit prominent Ho3+ ion resulting in peaks at 460, 542 and 650 nm as well as weak emission peaks at 300–360 nm. Future applications for these co-doped Ce3+ and Ho3+ ion monoclinic LaPO4 nanocrystals are anticipated to include better optical materials. Ultimately, many potential uses in various industries, from sophisticated display technologies to biomedical imaging and beyond, are made possible by the production and characterisation of co-doped Ce3+/Ho3+ ion nanophosphors in LaPO4 matrices. The realisation of useful systems and technologies utilising the special qualities of these nanocrystals may result from more study and development in these fields.
期刊介绍:
Chemical Data Collections (CDC) provides a publication outlet for the increasing need to make research material and data easy to share and re-use. Publication of research data with CDC will allow scientists to: -Make their data easy to find and access -Benefit from the fast publication process -Contribute to proper data citation and attribution -Publish their intermediate and null/negative results -Receive recognition for the work that does not fit traditional article format. The research data will be published as ''data articles'' that support fast and easy submission and quick peer-review processes. Data articles introduced by CDC are short self-contained publications about research materials and data. They must provide the scientific context of the described work and contain the following elements: a title, list of authors (plus affiliations), abstract, keywords, graphical abstract, metadata table, main text and at least three references. The journal welcomes submissions focusing on (but not limited to) the following categories of research output: spectral data, syntheses, crystallographic data, computational simulations, molecular dynamics and models, physicochemical data, etc.