{"title":"利用 TiO2-AgBr-Ag-SBA-15 纳米填料制备具有优异渗透性和防污性能的新型聚醚砜(PES)光催化膜,用于去除头孢克肟","authors":"Shahnaz Nayeri, Jalal Basiri Parsa","doi":"10.1007/s13738-024-03031-9","DOIUrl":null,"url":null,"abstract":"<div><p>This study aimed to enhance the permeability and antifouling properties of the polymer membrane of polyethersulfone (PES) through the modification with TiO<sub>2</sub>–AgBr–Ag–SBA-15. The hydrothermal process is used to create silica nanoparticles (SBA-15), which involved the use of tetraethylorthosilicate as a precursor and a copolymer Pluronic P123 (as a mold and the structure maintainer after solvent exiting). Then, SBA-15 nanoparticles are added to the preparation solution of TiO<sub>2</sub>–AgBr–Ag, resulting doping nanoparticles (TiO<sub>2</sub>–AgBr–Ag–SBA-15) were incorporated into the casting solution to achieve weight percentages of 0.4, 0.6, 0.8 and 1 in the final membranes. The nanoparticles were characterized using FESEM, FT-IR, XRD, XPS and EDX. Meanwhile, the membrane properties were studied using FESEM, FT-IR, CA, AFM and membrane performance tests. The hybrid membranes exhibited a less hydrophobic surface, which consequently resulted in water permeability. Moreover, the antifouling properties were notably improved, resulting in a considerable improvement in permeability without compromising the membrane's ability to remove unwanted substances. At 3.5 bar pressure, the pure water flux of the 0.8 wt% PES/TiO<sub>2</sub>–AgBr–Ag–SBA-15 membrane was two times higher than that of the pristine membrane. Flux recovery rate of 1 wt% PES/TiO<sub>2</sub>–AgBr–Ag–SBA-15 membrane can reach 90%, and the antifouling performance is excellent.</p></div>","PeriodicalId":676,"journal":{"name":"Journal of the Iranian Chemical Society","volume":"21 7","pages":"1897 - 1913"},"PeriodicalIF":2.2000,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication of novel polyethersulfone (PES) photocatalytic membranes with excellent permeability and antifouling properties using TiO2–AgBr–Ag–SBA-15 nanofillers for cefixime removal\",\"authors\":\"Shahnaz Nayeri, Jalal Basiri Parsa\",\"doi\":\"10.1007/s13738-024-03031-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study aimed to enhance the permeability and antifouling properties of the polymer membrane of polyethersulfone (PES) through the modification with TiO<sub>2</sub>–AgBr–Ag–SBA-15. The hydrothermal process is used to create silica nanoparticles (SBA-15), which involved the use of tetraethylorthosilicate as a precursor and a copolymer Pluronic P123 (as a mold and the structure maintainer after solvent exiting). Then, SBA-15 nanoparticles are added to the preparation solution of TiO<sub>2</sub>–AgBr–Ag, resulting doping nanoparticles (TiO<sub>2</sub>–AgBr–Ag–SBA-15) were incorporated into the casting solution to achieve weight percentages of 0.4, 0.6, 0.8 and 1 in the final membranes. The nanoparticles were characterized using FESEM, FT-IR, XRD, XPS and EDX. Meanwhile, the membrane properties were studied using FESEM, FT-IR, CA, AFM and membrane performance tests. The hybrid membranes exhibited a less hydrophobic surface, which consequently resulted in water permeability. Moreover, the antifouling properties were notably improved, resulting in a considerable improvement in permeability without compromising the membrane's ability to remove unwanted substances. At 3.5 bar pressure, the pure water flux of the 0.8 wt% PES/TiO<sub>2</sub>–AgBr–Ag–SBA-15 membrane was two times higher than that of the pristine membrane. Flux recovery rate of 1 wt% PES/TiO<sub>2</sub>–AgBr–Ag–SBA-15 membrane can reach 90%, and the antifouling performance is excellent.</p></div>\",\"PeriodicalId\":676,\"journal\":{\"name\":\"Journal of the Iranian Chemical Society\",\"volume\":\"21 7\",\"pages\":\"1897 - 1913\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-05-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Iranian Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13738-024-03031-9\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Iranian Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s13738-024-03031-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Fabrication of novel polyethersulfone (PES) photocatalytic membranes with excellent permeability and antifouling properties using TiO2–AgBr–Ag–SBA-15 nanofillers for cefixime removal
This study aimed to enhance the permeability and antifouling properties of the polymer membrane of polyethersulfone (PES) through the modification with TiO2–AgBr–Ag–SBA-15. The hydrothermal process is used to create silica nanoparticles (SBA-15), which involved the use of tetraethylorthosilicate as a precursor and a copolymer Pluronic P123 (as a mold and the structure maintainer after solvent exiting). Then, SBA-15 nanoparticles are added to the preparation solution of TiO2–AgBr–Ag, resulting doping nanoparticles (TiO2–AgBr–Ag–SBA-15) were incorporated into the casting solution to achieve weight percentages of 0.4, 0.6, 0.8 and 1 in the final membranes. The nanoparticles were characterized using FESEM, FT-IR, XRD, XPS and EDX. Meanwhile, the membrane properties were studied using FESEM, FT-IR, CA, AFM and membrane performance tests. The hybrid membranes exhibited a less hydrophobic surface, which consequently resulted in water permeability. Moreover, the antifouling properties were notably improved, resulting in a considerable improvement in permeability without compromising the membrane's ability to remove unwanted substances. At 3.5 bar pressure, the pure water flux of the 0.8 wt% PES/TiO2–AgBr–Ag–SBA-15 membrane was two times higher than that of the pristine membrane. Flux recovery rate of 1 wt% PES/TiO2–AgBr–Ag–SBA-15 membrane can reach 90%, and the antifouling performance is excellent.
期刊介绍:
JICS is an international journal covering general fields of chemistry. JICS welcomes high quality original papers in English dealing with experimental, theoretical and applied research related to all branches of chemistry. These include the fields of analytical, inorganic, organic and physical chemistry as well as the chemical biology area. Review articles discussing specific areas of chemistry of current chemical or biological importance are also published. JICS ensures visibility of your research results to a worldwide audience in science. You are kindly invited to submit your manuscript to the Editor-in-Chief or Regional Editor. All contributions in the form of original papers or short communications will be peer reviewed and published free of charge after acceptance.