{"title":"通过 CeZrOx/Cu-SSZ-39 混合催化剂增强一氧化氮还原:提高活性和水热稳定性","authors":"Yunhui Li, Kunting Li, Xingdong Zhu, Xinyan Zhang, Xin Zhang","doi":"10.1002/apj.3109","DOIUrl":null,"url":null,"abstract":"<p>This study aimed to improve the catalytic activity and hydrothermal stability of Cu-SSZ-39 zeolite by coupling it with cerium zirconium oxides (CeZrO<sub>x</sub>), which possesses excellent oxidizing ability, and a hybrid catalyst CeZrO<sub>x</sub>/Cu-SSZ-39 was prepared. It is found that it exhibited enhanced low-temperature activity, high-temperature activity, and a wider effective temperature range compared to Cu-SSZ-39. Characterization results showed that the CeZrO<sub>x</sub>/Cu-SSZ-39 catalyst had a higher concentration of active Cu<sup>2+</sup> ion species and improved redox properties, which could potentially promote the NH<sub>3</sub>-SCR reaction. Additionally, the CeZrO<sub>x</sub>/Cu-SSZ-39 catalyst had increased chemisorbed oxygen species on its surface, facilitating the oxidation of NO to NO<sub>2</sub> and enhancing the rate of the SCR reaction. Moreover, even after undergoing hydrothermal aging treatment, the CeZrO<sub>x</sub>/Cu-SSZ-39 catalyst exhibited superior catalytic activity and improved hydrothermal stability, surpassing the performance of Cu-SSZ-39. It is found the CeZrO<sub>x</sub> coupling allowed the hybrid catalyst to maintain a better specific surface area and pore structure during hydrothermal aging, resulting in reduced activity loss. Therefore, the addition of CeZrO<sub>x</sub> enhanced the NH<sub>3</sub>-SCR activity of Cu-SSZ-39 zeolite, leading to improved catalytic activity and hydrothermal stability. CeZrO<sub>x</sub>/Cu-SSZ-39 catalyst has shown promising aspect for reducing NOx emissions from diesel vehicle exhaust.</p>","PeriodicalId":49237,"journal":{"name":"Asia-Pacific Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhancement of nitric oxide reduction via CeZrOx/Cu-SSZ-39 hybrid catalyst: Improving activity and hydrothermal stability\",\"authors\":\"Yunhui Li, Kunting Li, Xingdong Zhu, Xinyan Zhang, Xin Zhang\",\"doi\":\"10.1002/apj.3109\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study aimed to improve the catalytic activity and hydrothermal stability of Cu-SSZ-39 zeolite by coupling it with cerium zirconium oxides (CeZrO<sub>x</sub>), which possesses excellent oxidizing ability, and a hybrid catalyst CeZrO<sub>x</sub>/Cu-SSZ-39 was prepared. It is found that it exhibited enhanced low-temperature activity, high-temperature activity, and a wider effective temperature range compared to Cu-SSZ-39. Characterization results showed that the CeZrO<sub>x</sub>/Cu-SSZ-39 catalyst had a higher concentration of active Cu<sup>2+</sup> ion species and improved redox properties, which could potentially promote the NH<sub>3</sub>-SCR reaction. Additionally, the CeZrO<sub>x</sub>/Cu-SSZ-39 catalyst had increased chemisorbed oxygen species on its surface, facilitating the oxidation of NO to NO<sub>2</sub> and enhancing the rate of the SCR reaction. Moreover, even after undergoing hydrothermal aging treatment, the CeZrO<sub>x</sub>/Cu-SSZ-39 catalyst exhibited superior catalytic activity and improved hydrothermal stability, surpassing the performance of Cu-SSZ-39. It is found the CeZrO<sub>x</sub> coupling allowed the hybrid catalyst to maintain a better specific surface area and pore structure during hydrothermal aging, resulting in reduced activity loss. Therefore, the addition of CeZrO<sub>x</sub> enhanced the NH<sub>3</sub>-SCR activity of Cu-SSZ-39 zeolite, leading to improved catalytic activity and hydrothermal stability. CeZrO<sub>x</sub>/Cu-SSZ-39 catalyst has shown promising aspect for reducing NOx emissions from diesel vehicle exhaust.</p>\",\"PeriodicalId\":49237,\"journal\":{\"name\":\"Asia-Pacific Journal of Chemical Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-05-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Asia-Pacific Journal of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/apj.3109\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Asia-Pacific Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/apj.3109","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Enhancement of nitric oxide reduction via CeZrOx/Cu-SSZ-39 hybrid catalyst: Improving activity and hydrothermal stability
This study aimed to improve the catalytic activity and hydrothermal stability of Cu-SSZ-39 zeolite by coupling it with cerium zirconium oxides (CeZrOx), which possesses excellent oxidizing ability, and a hybrid catalyst CeZrOx/Cu-SSZ-39 was prepared. It is found that it exhibited enhanced low-temperature activity, high-temperature activity, and a wider effective temperature range compared to Cu-SSZ-39. Characterization results showed that the CeZrOx/Cu-SSZ-39 catalyst had a higher concentration of active Cu2+ ion species and improved redox properties, which could potentially promote the NH3-SCR reaction. Additionally, the CeZrOx/Cu-SSZ-39 catalyst had increased chemisorbed oxygen species on its surface, facilitating the oxidation of NO to NO2 and enhancing the rate of the SCR reaction. Moreover, even after undergoing hydrothermal aging treatment, the CeZrOx/Cu-SSZ-39 catalyst exhibited superior catalytic activity and improved hydrothermal stability, surpassing the performance of Cu-SSZ-39. It is found the CeZrOx coupling allowed the hybrid catalyst to maintain a better specific surface area and pore structure during hydrothermal aging, resulting in reduced activity loss. Therefore, the addition of CeZrOx enhanced the NH3-SCR activity of Cu-SSZ-39 zeolite, leading to improved catalytic activity and hydrothermal stability. CeZrOx/Cu-SSZ-39 catalyst has shown promising aspect for reducing NOx emissions from diesel vehicle exhaust.
期刊介绍:
Asia-Pacific Journal of Chemical Engineering is aimed at capturing current developments and initiatives in chemical engineering related and specialised areas. Publishing six issues each year, the journal showcases innovative technological developments, providing an opportunity for technology transfer and collaboration.
Asia-Pacific Journal of Chemical Engineering will focus particular attention on the key areas of: Process Application (separation, polymer, catalysis, nanotechnology, electrochemistry, nuclear technology); Energy and Environmental Technology (materials for energy storage and conversion, coal gasification, gas liquefaction, air pollution control, water treatment, waste utilization and management, nuclear waste remediation); and Biochemical Engineering (including targeted drug delivery applications).