Mohammad Abdullah, Luqman Chuah Abdullah, Abel Adekanmi Adeyi, Siti Nurul Ain Md Jamil, Thomas Shean Yaw Choong, Rohah A. Majid
{"title":"微晶纤维素生物吸附剂从液相环境中吸附铜离子和铁离子的洞察力:实验和模型分析","authors":"Mohammad Abdullah, Luqman Chuah Abdullah, Abel Adekanmi Adeyi, Siti Nurul Ain Md Jamil, Thomas Shean Yaw Choong, Rohah A. Majid","doi":"10.1007/s13738-024-03049-z","DOIUrl":null,"url":null,"abstract":"<div><p>The paper assesses batch system microcrystalline cellulose (MCC) adsorptive ability for copper and iron uptake from aquatic environment. Field emission scanning electron microscope (FESEM), point zero charge and Fourier transform infrared (FTIR) spectroscopy were used to examine the physicochemical and morphological features of MCC. The batch system of the sequestration progression for the elimination of Cu(II) and Fe(II) was used by varying the solution pH, MCC doses, initial copper and iron concentration, and resident time. The maximum removal percentage for Cu(II) and Fe(II) were 99.5% and 96.4%, respectively, at pH 7. The influence of MCC dosage showed the 1.0 g/L of adsorbents results the highest percentage of Cu(II) (99.8%) and Fe(II) (88.63%) correspondingly. Equilibrium data for both metals were well fitted with both Langmuir and Freundlich isotherms, representing monolayer and multilayer adsorption systems. The maximum sorption capacity of MCC was 534.61 mg/g and 845.75 mg/g, respectively, for Cu(II) and Fe(II) ions at room temperature. Pseudo-second-order model best describes the copper and iron kinetic data, signifying the dominance of chemisorption adsorption relation between the negatively charged MCC and adsorbates. After four successive regeneration cycles, the MCC polymer maintained its maximal adsorption capacity, demonstrating effective copper and iron ion separation from aqueous solution. According to the study’s findings, poisonous heavy metals can be successfully removed from aquatic environments using eco-friendly microcrystalline cellulose.</p></div>","PeriodicalId":676,"journal":{"name":"Journal of the Iranian Chemical Society","volume":"21 7","pages":"1843 - 1853"},"PeriodicalIF":2.2000,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Insight into copper and iron ion sequestration from liquid-phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses\",\"authors\":\"Mohammad Abdullah, Luqman Chuah Abdullah, Abel Adekanmi Adeyi, Siti Nurul Ain Md Jamil, Thomas Shean Yaw Choong, Rohah A. Majid\",\"doi\":\"10.1007/s13738-024-03049-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The paper assesses batch system microcrystalline cellulose (MCC) adsorptive ability for copper and iron uptake from aquatic environment. Field emission scanning electron microscope (FESEM), point zero charge and Fourier transform infrared (FTIR) spectroscopy were used to examine the physicochemical and morphological features of MCC. The batch system of the sequestration progression for the elimination of Cu(II) and Fe(II) was used by varying the solution pH, MCC doses, initial copper and iron concentration, and resident time. The maximum removal percentage for Cu(II) and Fe(II) were 99.5% and 96.4%, respectively, at pH 7. The influence of MCC dosage showed the 1.0 g/L of adsorbents results the highest percentage of Cu(II) (99.8%) and Fe(II) (88.63%) correspondingly. Equilibrium data for both metals were well fitted with both Langmuir and Freundlich isotherms, representing monolayer and multilayer adsorption systems. The maximum sorption capacity of MCC was 534.61 mg/g and 845.75 mg/g, respectively, for Cu(II) and Fe(II) ions at room temperature. Pseudo-second-order model best describes the copper and iron kinetic data, signifying the dominance of chemisorption adsorption relation between the negatively charged MCC and adsorbates. After four successive regeneration cycles, the MCC polymer maintained its maximal adsorption capacity, demonstrating effective copper and iron ion separation from aqueous solution. According to the study’s findings, poisonous heavy metals can be successfully removed from aquatic environments using eco-friendly microcrystalline cellulose.</p></div>\",\"PeriodicalId\":676,\"journal\":{\"name\":\"Journal of the Iranian Chemical Society\",\"volume\":\"21 7\",\"pages\":\"1843 - 1853\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-05-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Iranian Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13738-024-03049-z\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Iranian Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s13738-024-03049-z","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Insight into copper and iron ion sequestration from liquid-phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses
The paper assesses batch system microcrystalline cellulose (MCC) adsorptive ability for copper and iron uptake from aquatic environment. Field emission scanning electron microscope (FESEM), point zero charge and Fourier transform infrared (FTIR) spectroscopy were used to examine the physicochemical and morphological features of MCC. The batch system of the sequestration progression for the elimination of Cu(II) and Fe(II) was used by varying the solution pH, MCC doses, initial copper and iron concentration, and resident time. The maximum removal percentage for Cu(II) and Fe(II) were 99.5% and 96.4%, respectively, at pH 7. The influence of MCC dosage showed the 1.0 g/L of adsorbents results the highest percentage of Cu(II) (99.8%) and Fe(II) (88.63%) correspondingly. Equilibrium data for both metals were well fitted with both Langmuir and Freundlich isotherms, representing monolayer and multilayer adsorption systems. The maximum sorption capacity of MCC was 534.61 mg/g and 845.75 mg/g, respectively, for Cu(II) and Fe(II) ions at room temperature. Pseudo-second-order model best describes the copper and iron kinetic data, signifying the dominance of chemisorption adsorption relation between the negatively charged MCC and adsorbates. After four successive regeneration cycles, the MCC polymer maintained its maximal adsorption capacity, demonstrating effective copper and iron ion separation from aqueous solution. According to the study’s findings, poisonous heavy metals can be successfully removed from aquatic environments using eco-friendly microcrystalline cellulose.
期刊介绍:
JICS is an international journal covering general fields of chemistry. JICS welcomes high quality original papers in English dealing with experimental, theoretical and applied research related to all branches of chemistry. These include the fields of analytical, inorganic, organic and physical chemistry as well as the chemical biology area. Review articles discussing specific areas of chemistry of current chemical or biological importance are also published. JICS ensures visibility of your research results to a worldwide audience in science. You are kindly invited to submit your manuscript to the Editor-in-Chief or Regional Editor. All contributions in the form of original papers or short communications will be peer reviewed and published free of charge after acceptance.