Anastasia M. Zhirkova, Kirill V. Zaitsev, Andrey A. Prishchenko, Mikhail V. Vasiliev, Marina V. Kotova, Karina A. Uschakova, Laura A. Martirosyan, Irina V. Perminova
{"title":"简单有效地合成功能化（羟基亚甲基）双膦酸","authors":"Anastasia M. Zhirkova, Kirill V. Zaitsev, Andrey A. Prishchenko, Mikhail V. Vasiliev, Marina V. Kotova, Karina A. Uschakova, Laura A. Martirosyan, Irina V. Perminova","doi":"10.1016/j.mencom.2024.04.029","DOIUrl":null,"url":null,"abstract":"<div><p>‘Technical’ tris(trimethylsilyl) phosphite, (Me<sub>3</sub>SiO)<sub>3</sub>P, as a mixture with (Me<sub>3</sub>SiO)<sub>2</sub>P(O)H and (Me<sub>3</sub>SiO)<sub>3</sub>P(O) (71 : 20 : 9) was obtained upon the action of (Me Si) NH on phosphorous acid H<sub>3</sub>PO<sub>3</sub> in the presence of catalytic amount of Me<sub>3</sub>SiCl. The action of this material on acid chlorides RC(O)Cl affords (hydroxymethylene)bis(phosphonic) acids RC(OH)[P(O)(OH)<sub>2</sub>]<sub>2</sub> in preparative yields.</p></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Simple and effective synthesis of functionalized (hydroxymethylene)bis(phosphonic) acids\",\"authors\":\"Anastasia M. Zhirkova, Kirill V. Zaitsev, Andrey A. Prishchenko, Mikhail V. Vasiliev, Marina V. Kotova, Karina A. Uschakova, Laura A. Martirosyan, Irina V. Perminova\",\"doi\":\"10.1016/j.mencom.2024.04.029\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>‘Technical’ tris(trimethylsilyl) phosphite, (Me<sub>3</sub>SiO)<sub>3</sub>P, as a mixture with (Me<sub>3</sub>SiO)<sub>2</sub>P(O)H and (Me<sub>3</sub>SiO)<sub>3</sub>P(O) (71 : 20 : 9) was obtained upon the action of (Me Si) NH on phosphorous acid H<sub>3</sub>PO<sub>3</sub> in the presence of catalytic amount of Me<sub>3</sub>SiCl. The action of this material on acid chlorides RC(O)Cl affords (hydroxymethylene)bis(phosphonic) acids RC(OH)[P(O)(OH)<sub>2</sub>]<sub>2</sub> in preparative yields.</p></div>\",\"PeriodicalId\":18542,\"journal\":{\"name\":\"Mendeleev Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mendeleev Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0959943624001494\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mendeleev Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0959943624001494","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Simple and effective synthesis of functionalized (hydroxymethylene)bis(phosphonic) acids
‘Technical’ tris(trimethylsilyl) phosphite, (Me3SiO)3P, as a mixture with (Me3SiO)2P(O)H and (Me3SiO)3P(O) (71 : 20 : 9) was obtained upon the action of (Me Si) NH on phosphorous acid H3PO3 in the presence of catalytic amount of Me3SiCl. The action of this material on acid chlorides RC(O)Cl affords (hydroxymethylene)bis(phosphonic) acids RC(OH)[P(O)(OH)2]2 in preparative yields.
期刊介绍：
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
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