将废弃蜗牛壳升级再利用为高性能纳米催化剂,优化生物柴油生产:一种可持续的方法

Invention Disclosure Pub Date : 2024-01-01 Epub Date: 2024-05-31 DOI:10.1016/j.inv.2024.100024
Shikhasmita Das , Jasha Momo H. Anal , Pranjal Kalita , Lakshi Saikia , Samuel Lalthazuala Rokhum
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引用次数: 0

摘要

这项研究报告了利用从废弃蜗牛壳中提取的碱性 CaO 纳米催化剂将大豆油(SO)酯交换转化为生物柴油的过程。由于全球石油消耗量不断攀升,温室气体排放量持续增加,加剧了环境污染,对人类生活构成了严重威胁。因此,生物柴油成为替代石油柴油的潜在液体燃料。在这里,我们利用废弃的蜗牛壳作为一种具有成本效益的材料,从而降低了生物柴油的总体制造成本。我们以极低的活化能(30.45 kJ mol-1)获得了 96.1 % 的生物柴油产量。该催化剂表现出了极高的稳定性,在连续六个循环中保持了稳定的催化活性,没有出现明显的衰退。通过生命周期成本分析(LCCA)发现,生产 1 千克生物柴油的估计成本仅为 0.935 美元,这凸显了其广泛商业应用的巨大潜力。
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Upcycling waste snail shells into high-performance nanocatalyst for optimized biodiesel production: A sustainable approach

The transesterification of soybean oil (SO) to biodiesel utilizing a basic CaO nanocatalyst derived from waste snail shells has been reported in this work. The steady rise in greenhouse gas emissions contributes to environmental pollution, posing a significant threat to human life due to the escalating rates of petroleum consumption worldwide. Thus, biodiesel appears as a potential liquid fuel for replacing petroleum diesel. Here we have utilized waste snail shells as a cost-effective material which will reduce the overall biodiesel manufacturing cost. We obtained a remarkable biodiesel yield of 96.1 % with a very low activation energy (30.45 kJ mol−1). The catalyst displayed exceptional stability, maintaining consistent catalytic activity over six consecutive cycles without experiencing a notable decline. Using life cycle cost analysis (LCCA) it has been discovered that the estimated cost of producing 1 kg of biodiesel is merely $ 0.935, highlighting its robust potential for extensive commercial adoption.

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