{"title":"金属有机框架的加速水稳定性测试和寿命预测","authors":"Tetsushi Ohmura, Yusuke Mukae, Yoichi Hosokawa, Hiroshi Nakamura, Takafumi Yamauchi","doi":"10.1093/chemle/upae093","DOIUrl":null,"url":null,"abstract":"To predict the lifetime of metal-organic frameworks (MOFs) with high water capacity/stability as water harvesters and adsorption heat pumps, a simple accelerated water stability test was developed using liquid water and water vapor in an autoclave. The function obtained from Bnlnauer-Emmett-Teller (BET) surface area loss analysis of MOF-801-P was applied to lifetime prediction, and a long-term stability test of MOF-801-P with liquid water at 65 °C agreed well with the values predicted using the developed test.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Accelerated water stability test and lifetime prediction of metal-organic frameworks\",\"authors\":\"Tetsushi Ohmura, Yusuke Mukae, Yoichi Hosokawa, Hiroshi Nakamura, Takafumi Yamauchi\",\"doi\":\"10.1093/chemle/upae093\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"To predict the lifetime of metal-organic frameworks (MOFs) with high water capacity/stability as water harvesters and adsorption heat pumps, a simple accelerated water stability test was developed using liquid water and water vapor in an autoclave. The function obtained from Bnlnauer-Emmett-Teller (BET) surface area loss analysis of MOF-801-P was applied to lifetime prediction, and a long-term stability test of MOF-801-P with liquid water at 65 °C agreed well with the values predicted using the developed test.\",\"PeriodicalId\":9862,\"journal\":{\"name\":\"Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-05-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1093/chemle/upae093\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upae093","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
为了预测具有高水容量/稳定性的金属有机框架（MOFs）作为水收集器和吸附热泵的寿命，开发了一种在高压釜中使用液态水和水蒸气的简单加速水稳定性试验。从 MOF-801-P 的 Bnlnauer-Emmett-Teller (BET) 表面积损失分析中获得的函数被应用于寿命预测，MOF-801-P 在 65 °C 下与液态水进行的长期稳定性测试与使用所开发的测试预测的值非常吻合。
Accelerated water stability test and lifetime prediction of metal-organic frameworks
To predict the lifetime of metal-organic frameworks (MOFs) with high water capacity/stability as water harvesters and adsorption heat pumps, a simple accelerated water stability test was developed using liquid water and water vapor in an autoclave. The function obtained from Bnlnauer-Emmett-Teller (BET) surface area loss analysis of MOF-801-P was applied to lifetime prediction, and a long-term stability test of MOF-801-P with liquid water at 65 °C agreed well with the values predicted using the developed test.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
