放射性铂-氧化铈-水混合物在振动里加通道中的化学动力学,受突然压力梯度的影响

IF 1.7 3区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Mathematical Chemistry Pub Date : 2024-06-05 DOI:10.1007/s10910-024-01625-5
Sanatan Das, Poly Karmakar, Tilak Kumar Pal, Soumitra Sarkar, Asgar Ali, Rabindra Nath Jana
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引用次数: 0

摘要

在可再生能源领域,铂(Pt)纳米粒子是燃料电池的重要组成部分。它们在氢燃料电池中尤其出色,其催化剂作用大大提高了电化学反应的效率。氧化铈纳米粒子因其卓越的催化能力而在工程和工业领域备受推崇。它们在减少汽车尾气排放、促进一氧化碳和碳氢化合物氧化方面的作用尤为显著。它们的储氧能力对于在催化反应过程中调节氧气水平至关重要,在汽车排气系统中也至关重要。在这一极具吸引力的领域,我们探索了一种特殊混合纳米流体的动态行为--在垂直延伸的振动里加通道中,放射性铂、氧化铈和水的混合物。该模型是在压力梯度突然发生、电磁力、电磁辐射和化学反应的累积影响下建立的。该物理模型由静止的右壁和发生横向振动的左壁组成。这种流动情况使用随时间变化的偏微分方程进行数学描述。通过利用拉普拉斯变换(LT)方法,获得了流动调节方程的闭式解。研究采用图形和表格的形式,详细说明了各种关键参数对模型功能和数量的影响,特别是对混合纳米流体(HNF)和纳米流体(NF)的影响。我们的研究结果表明,修正哈特曼数的扩大显著提高了流体在里加通道中的流速。与 NF 相比,HNF 中的流体温度始终较低。HNF 和 NF 中的物种浓度水平随着施密特数和化学反应参数的增加而降低。在 HNF 和 NF 中,磁体和电极宽度的增加导致里加壁的剪应力降低。此外,HNF 振动壁的传热速率(RHT)值始终高于 NF。这些新见解对各种工业和工程应用具有深远影响,包括催化转换器的开发、氢燃料电池的优化、一氧化碳和碳氢化合物的高效氧化以及材料加工技术的进步。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Chemical dynamics in a radioactive platinum -cerium oxide-water mixture within a vibrating Riga channel subject to sudden pressure gradient onset

In the realm of renewable energy, platinum (Pt) nanoparticles are crucial components in fuel cells. They particularly excel in hydrogen fuel cells, where their role as catalysts significantly boosts the efficiency of electrochemical reactions. Cerium oxide nanoparticles are highly prized in engineering and industry for their exceptional catalytic abilities. They are particularly notable for their role in reducing vehicle emissions and facilitating the oxidation of carbon monoxide and hydrocarbons. Their oxygen storage capacity, crucial in regulating oxygen levels during catalytic reactions, is vital in automotive exhaust systems. Such an appealing area has led us to explore the dynamic behaviours of a specialized hybrid nanofluid- a mixture of radioactive platinum, cerium oxide, and water within a vertically extended vibrating Riga channel. This model is set under the cumulative consequences of sudden pressure gradient onset, electromagnetic forces, electromagnetic radiation, and chemical reactions. This physical model consists of a static right wall and a left wall that undergoes transverse vibrations. This flow scenario is mathematically described using time-dependent partial differential equations. A closed-form solution for the flow-regulating equations is obtained by harnessing the Laplace transform (LT) method. The study meticulously details the ascendancy of various critical parameters on the functions and quantities of the model, particularly for hybrid nanofluid (HNF) and nanofluid (NF), using graphical and tabular representations. Our findings manifest an expansion in the modified Hartmann number notably boosts the fluid velocity across the Riga channel. The fluid temperature in HNF is consistently lower in HNF compared to NF. The species concentration levels in HNF and NF lower with rising Schmidt numbers and chemical reaction parameters. A widened width of magnets and electrodes results in lowered shear stresses at the Riga wall in both HNF and NF. Furthermore, the rate of heat transfer (RHT) at the vibrating wall for HNF consistently shows higher values than for NF. These novel insights have far-reaching implications in various industrial and engineering applications, including the development of catalytic converters, the optimization of hydrogen fuel cells, the efficient oxidation of carbon monoxide and hydrocarbons, and advancements in materials processing techniques.

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来源期刊
Journal of Mathematical Chemistry
Journal of Mathematical Chemistry 化学-化学综合
CiteScore
3.70
自引率
17.60%
发文量
105
审稿时长
6 months
期刊介绍: The Journal of Mathematical Chemistry (JOMC) publishes original, chemically important mathematical results which use non-routine mathematical methodologies often unfamiliar to the usual audience of mainstream experimental and theoretical chemistry journals. Furthermore JOMC publishes papers on novel applications of more familiar mathematical techniques and analyses of chemical problems which indicate the need for new mathematical approaches. Mathematical chemistry is a truly interdisciplinary subject, a field of rapidly growing importance. As chemistry becomes more and more amenable to mathematically rigorous study, it is likely that chemistry will also become an alert and demanding consumer of new mathematical results. The level of complexity of chemical problems is often very high, and modeling molecular behaviour and chemical reactions does require new mathematical approaches. Chemistry is witnessing an important shift in emphasis: simplistic models are no longer satisfactory, and more detailed mathematical understanding of complex chemical properties and phenomena are required. From theoretical chemistry and quantum chemistry to applied fields such as molecular modeling, drug design, molecular engineering, and the development of supramolecular structures, mathematical chemistry is an important discipline providing both explanations and predictions. JOMC has an important role in advancing chemistry to an era of detailed understanding of molecules and reactions.
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