双极悬浮液中链和带的现象学模型

IF 4.7 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-06-04 DOI:10.1122/8.0000823
Jeremy I. Kach, Lynn M Walker, Aditya S. Khair
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引用次数: 0

摘要

我们介绍了可极化粒子在外场作用下的双极相互作用现象学模型,其中粒子对相互作用的相对径向和旋转分量可以调整。我们的研究表明,这两个分量的相对强度控制着此类粒子悬浮液的微观结构和动力学。值得注意的是,占主导地位的径向相互作用会导致人字形带状图案的形成,而以前人们认为这种图案只会出现在流体力学相互作用占主导地位的系统中。通过这个现象学模型,我们证明了偶极相互作用可用于获得可极化粒子悬浮液中从链到带的一系列模式,这将极大地影响悬浮液的剪切流变等。
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A phenomenological model for chains and bands in dipolar suspensions
We introduce a phenomenological model for the dipolar interaction of polarizable particles under an external field, where the relative radial and rotational components of a particle pair interaction can be tuned. We show that the relative strengths of these two components govern the microstructure and dynamics of a suspension of such particles. Notably, dominant radial interactions give rise to the formation of zigzag band patterns, which were previously only thought to occur in systems where hydrodynamic interactions dominate. Through this phenomenological model, we show that dipolar interactions can be used to access an array of patterns in suspensions of polarizable particles, from chains to bands, which would dramatically affect suspension shear rheology, for instance.
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来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
期刊介绍: ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric. Indexed/​Abstracted: Web of Science SCIE Scopus CAS INSPEC Portico
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