直流辉光放电等离子体暴露 ESAC 条件下用于储能装置的低成本电极材料混合物

Vijayalakshmi K. Arumugam, Judith Fennila, Thangavel K. Maheswari
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引用次数: 0

摘要

以桉树种子活性炭为形式的废弃生物质被用作电极材料,对环境无害,在目前的工作中具有良好的比电容,可用于储能应用。采用样品碳化和物理活化程序从桉树种子中制备活性炭。将制备好的活性炭暴露于直流辉光放电等离子体中,可在不改变其核心特性的情况下改变材料的表面。利用结构、形态和电化学技术对纯活性炭和经等离子体处理的活性炭进行了研究。X 射线衍射强度的增加表明活性炭具有无定形和无序的特性。根据傅立叶变换红外光谱分析,碳中含有更多的含氧官能团。FESEM/EDAX 研究表明,石墨孔隙较少,且具有更多随机取向的石墨孔隙。此外,还利用电化学阻抗谱(EIS)和伽尔伏静态充放电(GCD)对材料进行了电化学研究,在 1.5mA/g 的电流密度下,材料的比电容为 150F/g。结果表明,桉树种子经等离子体处理后制成的活性炭具有良好的表面特性,提高了比电容,是一种用于制造储能装置的低成本电极材料。
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Blend of low cost electrode material for energy storage device under DC glow discharge plasma exposed ESAC
The waste biomass in the form of eucalyptus globulus seeds activated carbon, which is employed as the electrode material and is environmentally acceptable, provides the good specific capacitance in the current work which is used for the energy storage application. A sample carbonization and physical activation procedure was used to create the activated carbon from the eucalyptus seeds. As prepared activated carbon was exposed to a DC glow discharge plasma, which modifies the surface of the material without altering its core characteristics. The investigation of the activated carbon was done utilizing structural, morphological, and electrochemical techniques of both pure and plasma treated. The increasing intensity of the X-ray diffraction indicates the carbon's amorphous and disorderly character. More oxygen-containing functional groups are present, according to an FTIR analysis. The FESEM/EDAX investigation has demonstrated the less appearance and more graphitic porosity with random orientation. Moreover, the electrochemical investigations were examined for utilization of the material of Electrochemical Impedance Spectroscopy (EIS) and Galvanostatic charge-discharge (GCD) which has a specific capacitance of 150F/g for a 1.5mA/g current density. The results revealed that the activated carbon made from Eucalyptus seeds after plasma treatment has good surface characteristics, improved specific capacitance, and is a low-cost electrode material for fabrication of energy storage device.
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Zastita materijala
Zastita materijala Materials Science-General Materials Science
CiteScore
0.80
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发文量
26
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