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Influence of sodium chloride on corrosion resistance of ever silver vessels in the presence of curd rice 氯化钠对有凝乳米存在的银制容器耐腐蚀性的影响
Pub Date : 2024-07-26 DOI: 10.62638/zasmat1173
Thangarajan Umamathi, Venkatachalam Prathipa, Arockiam Roslin, Arockiaraj Little Jewelcy, Micheal Velankanni Jeevithe Clara, Nilavan Anitha, Mohamed Ibrahim Nasrin Sahana, Rajendran Susai, Arjunan Krishnaveni
The present work is undertaken to investigate the corrosion resistance of ever silver in the presence of water, water+curd system, water+curd+rice system, water+curd+rice+Salt system. The corrosion resistance has been evaluated by AC impedance spectra . AC impedance spectra have been employed to investigate the corrosion resistance of ever silver electrode when it is immersed in various test solutions like water, curd, curd rice recipe, curd rice recipe with salt (sodium chloride 500 ppm). The corrosion resistance of ever silver electrode when it is immersed in various test solutions like water, water+curd, water+curd+rice and water+curd+rice+salt have been evaluated by AC impedance spectroscopy. If a protective film is formed, the charge transfer resistance increases, impedance value increases, phase angle value increases and double layer capacitance (Cdl) value decreases. When Ever silver electrode is immersed in water + curd rice system + 500ppmsodium chloride system, the corrosion resistance of ever silver electrode decreases. This is due to the presence of chloride ion introduced into the curd rice system. It implies that when curd rice is packed in vessels made of ever silver, we should avoid adding salt to the curd rice. It is better to keep the salt and curd rice separately. It is to be noted that this corrosion resistance is better than the corrosion resistance in water alone. The corrosion resistance decreases in the following order: Water + Curd + Rice system > Water + Curd + Rice + Salt system (sodium chloride 500ppm) > Water+ Curd system > Water
本研究旨在探讨银在水、水+腐乳体系、水+腐乳+大米体系、水+腐乳+大米+盐体系中的抗腐蚀性。耐腐蚀性通过交流阻抗光谱进行评估。交流阻抗光谱用于研究银电极浸入各种测试溶液(如水、凝乳、凝乳米配方、凝乳米配方加盐(氯化钠 500 ppm))时的耐腐蚀性。通过交流阻抗光谱法评估了银电极浸入水、水+凝乳、水+凝乳+大米和水+凝乳+大米+盐等各种测试溶液时的耐腐蚀性。如果形成了保护膜,电荷转移电阻会增加,阻抗值会增加,相位角值会增加,双层电容 (Cdl) 值会降低。当 Ever 银电极浸入水+凝乳米体系+500ppms 氯化钠体系时,银电极的耐腐蚀性会降低。这是由于凝乳米体系中引入了氯离子。这意味着,在用恒银制成的容器包装凝乳米时,应避免在凝乳米中加盐。最好将盐和咖喱饭分开保存。值得注意的是,这种耐腐蚀性优于单独在水中的耐腐蚀性。耐腐蚀性按以下顺序递减:水+凝乳+大米系统 > 水+凝乳+大米+盐系统(氯化钠 500ppm) > 水+凝乳系统 > 水
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引用次数: 0
Protection from ballistic threats: an exploration of textile materials for bullet-resistant outerwear 防范弹道威胁:防弹外衣纺织材料探讨
Pub Date : 2024-07-26 DOI: 10.62638/zasmat1202
Subrata Das, Kaliappan Prathasana, Pathipalayam Arumugam Nitin, Krishnan Ramamoorthi Lakshimi JayaPriya, Vemban Mathivanan
Bullet-resistant jackets are one of the innovations that demonstrate how textile engineering and technology can work together to protect people from ballistic threats. To improve the protective qualities of bulletproof jackets, it is imperative to comprehend the wide variety of textile materials that are used in them. This study aims to clarify the complex interplay between protection, flexibility, and comfort that is inherent in these kinds of clothes by a thorough analysis of a variety of fibers, fabrics and composites, each offering unique characteristics that contribute to the overall effectiveness of these types of garments. Important factors were determined to take into account when choosing the best material based on particular needs like flexibility, comfort, weight, and degree of protection through careful analysis and comparison. This exploration shall provide valuable insights for researchers, manufacturers, and consumers alike, fostering advancements in protective garment design and promoting informed decision-making in the realm of personal safety.
防弹夹克是展示纺织工程与技术如何共同保护人们免受弹道威胁的创新产品之一。要提高防弹夹克的防护质量,就必须了解防弹夹克所使用的各种纺织材料。本研究旨在通过对各种纤维、织物和复合材料的全面分析,阐明此类服装固有的防护性、灵活性和舒适性之间复杂的相互作用。通过仔细分析和比较,确定了根据特定需求(如灵活性、舒适性、重量和保护程度)选择最佳材料时应考虑的重要因素。这一探索将为研究人员、制造商和消费者提供有价值的见解,推动防护服设计的进步,促进在人身安全领域做出明智的决策。
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引用次数: 0
Evaluating the water quality of a Kondakarla Ava Lake for agricultural endeavours in Visakhapatnam, India 评估印度维萨卡帕特南 Kondakarla Ava 湖的水质,促进农业发展
Pub Date : 2024-07-18 DOI: 10.62638/zasmat1172
Sirisha Korrai, B.Vinay Sagar, Madhavi Earle, Sangeetha Sankhyayani Achanta, Hemanshu Mediboyana
Global population growth is placing a pressure on freshwater resources. Freshwater resources are becoming scarcer in terms of both quantity and quality due to the rising demand. Assessing water quality of surface water bodies for irrigation is essential as water with poor quality can pose health risks. The study involved observing the physicochemical parameters of Kondakarla Ava Lake from six different sampling locations. The study revealed that it could not use directly for drinking purposes as per NSFWQI. According to parameters like RSC, SAR, PI, % Na, and IWQI, water quality is appropriate for irrigation. It is further strengthened by the USSL diagram showing that the Kondakarla Ava Lake samples fall under the categories C3S1 and C4S1, which indicates that water has low sodium peril and high to very high salinity. The Wilcox diagram showed the grouping of the samples under three categories: excellent, good to permissible, and doubtful.
全球人口增长给淡水资源带来了压力。由于需求不断增加,淡水资源在数量和质量上都变得越来越稀缺。评估地表水灌溉水体的水质至关重要,因为水质差的水会对健康造成危害。这项研究从六个不同的取样点观察了孔达卡拉阿瓦湖的理化参数。研究结果表明,根据《国家可持续发展水质指标》(NSFWQI),湖水不能直接用于饮用。根据 RSC、SAR、PI、Na% 和 IWQI 等参数,水质适合灌溉。USSL 图显示,Kondakarla Ava 湖的水样属于 C3S1 和 C4S1 类,这进一步证实了这一点。威尔科克斯图显示样本分为三类:极佳、良好至允许和可疑。
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引用次数: 0
The effect of anodization and subsequent treatments on corrosion resistance of aluminium 阳极氧化及后续处理对铝抗腐蚀性能的影响
Pub Date : 2024-07-18 DOI: 10.62638/zasmat1174
Marija Mitrović, Milena Milovanović, Nebojša Vasiljević, Milorad Тоmić
Aluminium samples were chemically prepared by following operations: degreasing, etching I, etching II, and brightening), prior to anodizing in sulfuric acid. Aluminium surface area was 0.2 dm2. The composition of used aluminium samples was determined by the energy dispersive X-ray spectroscopy. Chemically prepared aluminium samples were electrochemically anodized for 45 minutes in a solution of 190 gdm-3 H2SO4 at room temperature, at a current density of 1.7 Adm-2. In the anodizing process, the aluminium sample served as the anode, with lead cathodes. After anodizing, the aluminium samples underwent a colouring process in five pairs of solutions (systems), where each system consisted of two solutions of inorganic salts RxA + RxB (x = 1-5, numbers of solutions). Colouring of the anodized aluminium was carried out at room temperature by immersing the samples in each solution for 7 minutes (e.g., R1A + R1B, τ =7 min + 7 min). Each used colouring system provides a different colour: green-yellow, brown, light-grey, blue, and orange-gold. After colouring, the samples were treated in a special solution to improve corrosion resistance and silication, resulting in a change in the obtained colour shade. All obtained colours were stable with very nice appearance, allowing such coloured aluminium to be used for decorative purposes. The corrosion resistance of the coloured anodized aluminium samples was investigated by determining the corrosion potential, corrosion current and polarization resistance using potentiodynamic polarization method, as well as by electrochemical impedance spectroscopy. A common feature of all tested samples is a significant improvement in the corrosion resistance of the anodized aluminium after colouring and subsequent treatment in the corrosion resistance improvement solution, particularly after the additional silane treatment.
在硫酸阳极氧化之前,对铝样品进行了以下化学制备:脱脂、蚀刻 I、蚀刻 II 和增亮)。铝的表面积为 0.2 dm2。使用过的铝样品的成分是通过能量色散 X 射线光谱测定的。化学制备的铝样品在室温下于 190 gdm-3 H2SO4 溶液中电化学阳极氧化 45 分钟,电流密度为 1.7 Adm-2。在阳极氧化过程中,铝样作为阳极,阴极为铅。阳极氧化后,铝样在五对溶液(系统)中进行着色,每个系统由两种无机盐溶液 RxA + RxB 组成(x = 1-5,溶液数量)。阳极氧化铝的着色在室温下进行,将样品浸入每种溶液中 7 分钟(例如,R1A + R1B,τ =7 分钟 + 7 分钟)。所使用的每种着色系统都提供了不同的颜色:黄绿色、棕色、浅灰色、蓝色和橙金色。着色后,样品在特殊溶液中进行处理,以提高耐腐蚀性和硅化效果,从而改变所获得的颜色。所有获得的颜色都很稳定,外观也非常漂亮,因此这种彩色铝可用于装饰目的。通过使用电位极化法和电化学阻抗光谱法测定腐蚀电位、腐蚀电流和极化电阻,对彩色阳极氧化铝样品的耐腐蚀性能进行了研究。所有测试样品的一个共同特点是,经过着色和随后在耐腐蚀性改进溶液中处理后,阳极氧化铝的耐腐蚀性能显著提高,特别是在经过额外的硅烷处理后。
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引用次数: 0
Waste tyres pyrolysis oil (WTPO) as an alternative source of fuel and chemicals: a review 废轮胎热解油(WTPO)作为燃料和化学品的替代来源:综述
Pub Date : 2024-07-18 DOI: 10.62638/zasmat1153
Bashir Abdu Muzakkari, Amina Salihi Bayero, Musa Ibrahim Mohammed, Pramod K. Singh, Umar Muhammad Jibreel
Waste tyres are dumped and common kind of abandon solid waste. Almost 3 billion tyres are produced each year and each tyre produced will eventually join the waste products and if not properly handled will become pollutant. In many countries disposal of waste tyres is prohibited; as an alternative they should be recovered and recycled instead. In this review pyrolysis was introduced as an alternative way of recycling waste tyres, Pyrolysis allows the dissolution of the waste and it also produces useful by-products. The products obtained during the process are pyrolysis oil, pyrolysis char and condensable gas. Pyrolysis oil is the major product among them, this paper reviewed pyrolysis oil as an alternative sources of fuel to diesel engines and as well to highlight the chemicals obtained in the waste tyres from the pyrolysis oil which mainly depends on the kind of feedstock (i.e. type of tyres e.g truck, cars, bicycle) used in the pyrolysis process. Most of the compounds obtained are Aliphatic and Aromatic hydrocarbons (especially the Polycyclic Aromatic Hydrocarbon PAHs) such as Naphthalene – NAP, Acenaphthylene – ACY, Acenaphthene –ACE, Fluorene – FLU, Phenanthrene – PHE, Anthracene – ANT, Fluoranthene–FLT, Pyrene–PYR, Benzo[a]anthracene – BAA, Chrysene – CRY, Benzo[b]fluoranthene – BBF, Benzo[k[fluoranthene – BKF, Benzo[a]pyrene – BAP, Dibenzo[a,h]anthracene – DBA, Benzo[g,h,i]perylene – BGP, Indeno[1,2,3-cd]pyrene – IND among others. Consequently, the pyrolysis oil obtained need further upgrading via a reaction pathways are hydrodesulfurization (HDS), hydrodearomatization (HDA) and hydrocracking (HC) which can be achieved through a 2-stage hydroprocessing strategy regarding WTPO composition in terms of HDS, HAD and HC. Pyrolysis oil from waste tyres can be used as a substitute for diesel and as well as sources of raw materials and fuel to organic chemical industries.
废轮胎是一种常见的废弃固体废物。每年产生近 30 亿条轮胎,每条轮胎最终都会成为废品,如果处理不当,就会成为污染物。在许多国家,废弃轮胎的处理是被禁止的;作为一种替代方法,应该对其进行回收和循环利用。在本综述中,热解被介绍为回收废轮胎的一种替代方法,热解可以使废物溶解,还能产生有用的副产品。热解过程中产生的产品有热解油、热解炭和冷凝气体。热解油是其中的主要产品,本文对热解油作为柴油发动机的替代燃料来源进行了评述,并重点介绍了从热解油中获得的废轮胎化学物质,这主要取决于热解过程中使用的原料种类(即轮胎类型,如卡车、汽车、自行车)。获得的大部分化合物是脂肪族和芳香族碳氢化合物(尤其是多环芳香烃 PAHs),如萘-NAP、苊-ACY、苊-ACE、芴-FLU、菲-PHE、蒽-ANT、氟蒽-FLT、芘-PYR、苯并[a]蒽-BAA、菊烯-CRY、苯并[b]荧蒽-BBF、苯并[k]荧蒽-BKF、苯并[a]芘-BAP、二苯并[a,h]蒽-DBA、苯并[g,h,i]苝-BGP、茚并[1,2,3-cd]芘-IND 等。因此,获得的热解油需要通过加氢脱硫 (HDS)、加氢脱芳烃 (HDA) 和加氢裂化 (HC) 等反应途径进一步提纯。废轮胎热解油可用作柴油的替代品,也可作为有机化学工业的原料和燃料来源。
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引用次数: 0
Comparative study of various volcanic materials as fillers in polymer composites 将各种火山岩材料作为聚合物复合材料填料的比较研究
Pub Date : 2024-07-18 DOI: 10.62638/zasmat1171
L. Melnyk, Lev Chernyak, V. Sviderskyy, Ludmila Vovchenko, Viktoria Yevpak
The object of the study was composite materials using rocks of volcanic origin as a filler (60-90 wt.%) and aqueous dispersions of polymers Latex 2012 and Policril 590 as a matrix. The peculiarities of the chemical and mineralogical composition and surface properties of perlite and zeolite as factors of interaction with the binder in the formation of the composite structure are shown. Differences in lyophilicity coefficients and effective specific surface of zeolite and perlite were determined, which are 0.318 versus 0.189 and 11.68 versus 2.20 m2/g, respectively. The influence of a high concentration of fillers on the formation of the pore structure and indicators of physical and mechanical properties of composites is evaluated. The possibility of adjusting the properties of the composites in the following range was established: water absorption in the range of 2.63-14.16 wt.%, open porosity 3.58-21.35 %, residual strain 0.1-0.3, Young’s modulus 19.7-677.5 MPa.
研究对象是以火山岩为填料(60-90 wt.%),聚合物 Latex 2012 和 Policril 590 的水分散体为基质的复合材料。结果表明,珍珠岩和沸石的化学和矿物组成以及表面特性的特殊性是在形成复合结构时与粘合剂相互作用的因素。经测定,沸石和珍珠岩的冻干系数和有效比表面存在差异,分别为 0.318 对 0.189 和 11.68 对 2.20 m2/g。评估了高浓度填料对孔隙结构的形成以及复合材料物理和机械性能指标的影响。确定了在以下范围内调整复合材料性能的可能性:吸水率范围为 2.63-14.16 wt.%,开放孔隙率为 3.58-21.35%,残余应变为 0.1-0.3,杨氏模量为 19.7-677.5 兆帕。
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引用次数: 0
Antifungal coating for wood protection 保护木材的防霉涂层
Pub Date : 2024-07-18 DOI: 10.62638/zasmat1167
Guadalupe Canosa, C. Giúdice, P. V. Alfieri
Antifungal hydro-repellent coatings were formulated for Pinus ponderosa panels’ protection. The fomulated coatings were based on a hydroxylated acrylic resin chemically modified with n-octyltriethoxysilane (R8), n-octadecyltriethoxysilane (R18), and some mixtures of them as hybrid film-forming material. Diatomaceous silica was used as a pigment. The share of silane was 20% higher than the stoichiometric ratio to allow its interaction with cellulose hydroxyl groups (-OH). Results indicated that the best antifungal efficiency was reached with coating formulated with 70R8/30R18 ratio due to the chemical reaction of cellulose hydroxyl groups (causing its blocking) and the physical barrier created by the degree of compaction of the film itself. Moreover, Biodeterioration of the film caused by the specific fungi was not observed, whit confirms the durability effect of the treatment. The protection mechanism is related to the water repellency and the blocking of the substrate.
为保护松柏板材配制了抗真菌憎水涂料。所配制的涂料以羟基丙烯酸树脂为基础,用正十八烷基三乙氧基硅烷(R8)、正十八烷基三乙氧基硅烷(R18)和它们的一些混合物作为混合成膜材料进行化学改性。硅藻土被用作颜料。硅烷的比例比化学计量比高 20%,以便与纤维素羟基(-OH)相互作用。结果表明,采用 70R8/30R18 比率配制的涂层具有最佳的抗真菌效率,这是由于纤维素羟基发生了化学反应(导致其阻塞),以及薄膜本身的压实度产生了物理屏障。此外,没有观察到由特定真菌引起的薄膜生物退化,这证实了处理的耐久性效果。保护机制与基材的防水性和阻隔性有关。
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引用次数: 0
Effect of corrosion inhibitors on internal corrosion in oil pipelines: a brief review 缓蚀剂对石油管道内部腐蚀的影响:简要回顾
Pub Date : 2024-07-18 DOI: 10.62638/zasmat1161
Esraa Razaq, S. A. Abdulsada
The oil and gas industry primarily relies on pipelines to transport crude and refined petroleum, so transportation of crude oil is mostly handled by pipelines. In view of this, it is impossible to prevent the pipeline surfaces from being continuously exposed to corrosion sources, such as contaminants that contain traces of chromate and sulfur, which can cause corrosion to occur on the pipeline surfaces. It is known that corrosion inhibitors are chemicals that are used in low concentrations for the purpose of reducing or preventing corrosion.  The effectiveness of an inhibitor is determined by its ability to react with a metal's surface and produce a protective coating that reduces or prevents corrosion by reacting with the metal's surface. A review of corrosion mechanisms in oil pipelines is presented in this article, along with a description of how corrosion inhibitors can be selected according to the corrosion mechanisms in oil pipelines.
石油和天然气行业主要依靠管道来运输原油和精炼石油,因此原油的运输主要由管道来完成。有鉴于此,不可能避免管道表面持续暴露在腐蚀源中,例如含有微量铬酸盐和硫的污染物会导致管道表面发生腐蚀。众所周知,腐蚀抑制剂是一种低浓度化学品,用于减少或防止腐蚀。 抑制剂的效果取决于其与金属表面发生反应并产生保护层的能力,通过与金属表面发生反应来减少或防止腐蚀。本文回顾了石油管道的腐蚀机理,并介绍了如何根据石油管道的腐蚀机理选择缓蚀剂。
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引用次数: 0
Examining the impact of anisotropic particle orientation in a polymer matrix on the electrical properties of composite materials 研究聚合物基体中各向异性颗粒取向对复合材料电气性能的影响
Pub Date : 2024-07-18 DOI: 10.62638/zasmat1110
Anna Stepashkina, Khurram Shehzad
A number of works have experimentally shown the significant influence of mechanical stretching on the electrically conductive properties of composite polymer materials. Thus, stretching polymer composite films and filaments can lead to deterioration in electrical conductivity properties which can significantly affect the characteristics of products made from such materials. The research conducted in this study focuses on simulation the impact of anisotropic particle orientation within a polymer matrix and mechanical stretching on the electrical properties of composite materials. Based on the Boltzmann statistics, an expression was obtained that allows predicting the change in electrical conductivity during the stretching of polymer composite samples. The Monte Carlo method was used to simulate the destruction of a percolation chain of conductive particles during stretching.
许多研究通过实验表明,机械拉伸对复合聚合物材料的导电性能有显著影响。因此,拉伸聚合物复合薄膜和长丝会导致导电性能下降,从而严重影响由此类材料制成的产品的特性。本研究的重点是模拟聚合物基体中各向异性粒子取向和机械拉伸对复合材料导电性能的影响。根据玻尔兹曼统计,得到了一个表达式,可以预测聚合物复合材料样品在拉伸过程中的电导率变化。使用蒙特卡罗方法模拟了拉伸过程中导电粒子渗流链的破坏。
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引用次数: 0
Influence of rice husk ash inclusion on electrical characteristics of dry cement mortar 稻壳灰对干水泥砂浆电气特性的影响
Pub Date : 2024-07-18 DOI: 10.62638/zasmat1051
Etuk Sunday Edet, Robert Ubong Williams, O. Agbasi, Inyang Namdie Joseph
Rice husk is usually generated as waste in large quantities but yet to be optimally utilized. Due to the pollution effects associated with poor approach prevalently adopted for its disposal, valorizing it into economical and sustainable material for building construction is a necessary option to provide solution for future generation. In this research, separate dry mortars were prepared using cement grades 32.5R and 42.5N and the influence of rice husk ash (RHA) inclusion on their electrical characteristics was investigated. The materials used were batched by volume and the RHA was utilized as a partial substitute for cement at 10 % level. All the samples were cured for 21 days and then allowed to dry completely prior to the tests implementation. The results showed decrease in electrical resistance with temperature (ranging from 20oC to 50oC) due to incorporation of the RHA. Though samples with the RHA content possessed ability to act as smart mortars for temperature monitoring/sensing, utilization of cement grade 42.5N ensured a better performance. By utilizing rice husks in such undertakings, their associated disposal problems could be tackled and construction of inexpensive but sustainable building with large temperature sensing capability could be enhanced. 
稻壳通常作为废物大量产生,但尚未得到最佳利用。由于普遍采用的处理方法不当会造成污染,因此将稻壳转化为经济、可持续的建筑材料是为下一代提供解决方案的必要选择。在这项研究中,使用等级为 32.5R 和 42.5N 的水泥分别制备了干灰泥,并研究了稻壳灰(RHA)的加入对其电气特性的影响。所使用的材料按体积配料,RHA 用作水泥的部分替代品,含量为 10%。所有样品都固化了 21 天,然后让其完全干燥后再进行测试。结果表明,由于加入了 RHA,电阻值随温度(20oC 至 50oC)的升高而降低。虽然含有 RHA 的样品具有作为温度监测/传感智能砂浆的能力,但使用等级为 42.5N 的水泥确保了更好的性能。通过在此类工程中使用稻壳,可以解决稻壳的相关处置问题,并能建造出价格低廉但具有较强温度传感能力的可持续建筑。
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引用次数: 0
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Zastita materijala
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