{"title":"深入了解钕铁硼污泥中 REEs 和铁的共浸出机制:阐明相变和共沥滤动力学","authors":"Xinglan Li, Zishuai Liu, Xiu Liu, Xuekun Tang, Huiyang Lin, Lushuai Yao, Wanting Bai, Jiangfeng Guo","doi":"10.37190/ppmp/189908","DOIUrl":null,"url":null,"abstract":"The NdFeB sludge is a secondary rare earth resource abundant in both REEs and Fe elements. However, there tends to be a focus on recovering only high-value rare earths while neglecting the recycling of high-content iron, leading to a low comprehensive utilization of this secondary rare earth resource. The present study builds upon previous research on the separation and coextraction of REEs and Fe from NdFeB sludge, further investigating the phase transformation behavior during oxidation roasting and elucidating the kinetics of simultaneous leaching of REEs and Fe. The results suggest that NdFeB waste exhibited a loose morphology and demonstrated high susceptibility to dissolution in hydrochloric acid when subjected to roasting temperatures below 500℃. The morphology of NdFeB waste becomes denser and more spherical, hindering its dissolution in hydrochloric acid when the roasting temperature exceeded 500℃, resulting in a reduction in the leaching efficiencies of both roasting. The co-leaching of REEs and Fe in NdFeB sludge is governed by internal diffusion for REEs and chemical reaction for Fe, as evidenced by the kinetic results. Furthermore, it is observed that the apparent activation energy of rare earth surpasses that of iron, leading to the attainment of equilibrium for rare earth prior to that of iron during the synchronous leaching process. The findings of this study hold theoretical significance in enhancing the overall efficiency of secondary rare earth resource utilization.","PeriodicalId":20169,"journal":{"name":"Physicochemical Problems of Mineral Processing","volume":"82 6","pages":""},"PeriodicalIF":1.5000,"publicationDate":"2024-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Insight into the mechanism on co-leaching of REEs and Fe from NdFeB sludge: Elucidating phase transformation and co-leaching kinetics\",\"authors\":\"Xinglan Li, Zishuai Liu, Xiu Liu, Xuekun Tang, Huiyang Lin, Lushuai Yao, Wanting Bai, Jiangfeng Guo\",\"doi\":\"10.37190/ppmp/189908\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The NdFeB sludge is a secondary rare earth resource abundant in both REEs and Fe elements. 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The co-leaching of REEs and Fe in NdFeB sludge is governed by internal diffusion for REEs and chemical reaction for Fe, as evidenced by the kinetic results. Furthermore, it is observed that the apparent activation energy of rare earth surpasses that of iron, leading to the attainment of equilibrium for rare earth prior to that of iron during the synchronous leaching process. 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引用次数: 0
摘要
钕铁硼污泥是一种富含稀土和铁元素的二次稀土资源。然而,人们往往只关注高价值稀土的回收,而忽视了高含量铁的回收,导致这种二次稀土资源的综合利用率较低。本研究在以往从钕铁硼污泥中分离和共萃取稀土和铁的研究基础上,进一步研究了氧化焙烧过程中的相变行为,并阐明了同时沥滤稀土和铁的动力学。结果表明,当焙烧温度低于 500℃时,钕铁硼废料呈现出松散的形态,并且极易溶解于盐酸中。当焙烧温度超过 500℃时,钕铁硼废料的形态变得更加致密和球形,阻碍了其在盐酸中的溶解,导致两种焙烧的浸出效率都降低。动力学结果表明,钕铁硼污泥中 REEs 和 Fe 的共同浸出受 REEs 内部扩散和 Fe 化学反应的支配。此外,还观察到稀土的表观活化能超过了铁的表观活化能,导致在同步浸出过程中稀土先于铁达到平衡。该研究结果对于提高二次稀土资源利用的整体效率具有重要的理论意义。
Insight into the mechanism on co-leaching of REEs and Fe from NdFeB sludge: Elucidating phase transformation and co-leaching kinetics
The NdFeB sludge is a secondary rare earth resource abundant in both REEs and Fe elements. However, there tends to be a focus on recovering only high-value rare earths while neglecting the recycling of high-content iron, leading to a low comprehensive utilization of this secondary rare earth resource. The present study builds upon previous research on the separation and coextraction of REEs and Fe from NdFeB sludge, further investigating the phase transformation behavior during oxidation roasting and elucidating the kinetics of simultaneous leaching of REEs and Fe. The results suggest that NdFeB waste exhibited a loose morphology and demonstrated high susceptibility to dissolution in hydrochloric acid when subjected to roasting temperatures below 500℃. The morphology of NdFeB waste becomes denser and more spherical, hindering its dissolution in hydrochloric acid when the roasting temperature exceeded 500℃, resulting in a reduction in the leaching efficiencies of both roasting. The co-leaching of REEs and Fe in NdFeB sludge is governed by internal diffusion for REEs and chemical reaction for Fe, as evidenced by the kinetic results. Furthermore, it is observed that the apparent activation energy of rare earth surpasses that of iron, leading to the attainment of equilibrium for rare earth prior to that of iron during the synchronous leaching process. The findings of this study hold theoretical significance in enhancing the overall efficiency of secondary rare earth resource utilization.
期刊介绍:
Physicochemical Problems of Mineral Processing is an international, open access journal which covers theoretical approaches and their practical applications in all aspects of mineral processing and extractive metallurgy.
Criteria for publication in the Physicochemical Problems of Mineral Processing journal are novelty, quality and current interest. Manuscripts which only make routine use of minor extensions to well established methodologies are not appropriate for the journal.
Topics of interest
Analytical techniques and applied mineralogy
Computer applications
Comminution, classification and sorting
Froth flotation
Solid-liquid separation
Gravity concentration
Magnetic and electric separation
Hydro and biohydrometallurgy
Extractive metallurgy
Recycling and mineral wastes
Environmental aspects of mineral processing
and other mineral processing related subjects.