V. A. Makhova, L. A. Kulikov, A. V. Akopyan, E. A. Karakhanov
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Molybdenum Catalysts Supported on Porous Aromatic Frameworks in Epoxidation of Olefins
A novel catalyst was synthesized by immobilizing a MoO2(acac)2 complex on the surface of a porous aromatic framework functionalized with pyridine-2-carboxaldehyde (PAF-30-NPy). The immobilization was confirmed by IR spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis. The synthesized catalyst was tested in the epoxidation of cyclohexene, cycloheptene, 1-hexene, 1-octene, styrene, and trans-stilbene. The effects of the solvent type and the oxidant content on the olefin conversion were described. The catalyst reusability was further tested, and its activity was evaluated.
期刊介绍：
Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas.
Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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