Alexey Ponaryadov, Olga Kotova, Shiyong Sun, Elena Kotova
{"title":"具有更好特性的高岭土和白云石二元正长石-堇青石陶瓷复合材料","authors":"Alexey Ponaryadov, Olga Kotova, Shiyong Sun, Elena Kotova","doi":"10.1111/ijac.14826","DOIUrl":null,"url":null,"abstract":"<p>Binary CaO-MgO-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> (CMAS) ceramics composites of anorthite-cordierite composition were synthesized from natural raw materials (kaolin and dolomite rock). The change of SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratio in kaolin/dolomite mixtures (12, 24, and 36 wt.%) and synthesized composites along with analysis of their phase composition transformations (X-ray diffraction) during heat treatment (thermogravimetric and differential thermal analysis) give the controlled design of aluminosilicate matrices. The obtained ceramic composites are represented by anorthite, a cordierite-like phase whose ratio varies from 1.3:1 to 2.8:1. Mullite crystals, also included in the composition, reinforce the anorthite-cordierite matrix. The morphostructural features of the samples were studied using optical and scanning electron microscopy. The porosity ranges from 7.8% to 24.2% depending on dolomite content. The impurities of iron and titanium interfering with obtaining a qualitative product are leveled by the presented technique including the heat treatment scheme justified by thermogravimetric analysis. Obtained CMAS-ceramics of anorthite-cordierite composition correspond to industrial international standards by their technical characteristics and exceed the requirements for heat-insulating and chemically resistant materials by compressive strength.</p>","PeriodicalId":13903,"journal":{"name":"International Journal of Applied Ceramic Technology","volume":"21 6","pages":"4026-4035"},"PeriodicalIF":1.8000,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Binary anorthite-cordierite ceramic composite from kaolin and dolomite rock with improved characteristics\",\"authors\":\"Alexey Ponaryadov, Olga Kotova, Shiyong Sun, Elena Kotova\",\"doi\":\"10.1111/ijac.14826\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Binary CaO-MgO-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> (CMAS) ceramics composites of anorthite-cordierite composition were synthesized from natural raw materials (kaolin and dolomite rock). The change of SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratio in kaolin/dolomite mixtures (12, 24, and 36 wt.%) and synthesized composites along with analysis of their phase composition transformations (X-ray diffraction) during heat treatment (thermogravimetric and differential thermal analysis) give the controlled design of aluminosilicate matrices. The obtained ceramic composites are represented by anorthite, a cordierite-like phase whose ratio varies from 1.3:1 to 2.8:1. Mullite crystals, also included in the composition, reinforce the anorthite-cordierite matrix. The morphostructural features of the samples were studied using optical and scanning electron microscopy. The porosity ranges from 7.8% to 24.2% depending on dolomite content. The impurities of iron and titanium interfering with obtaining a qualitative product are leveled by the presented technique including the heat treatment scheme justified by thermogravimetric analysis. Obtained CMAS-ceramics of anorthite-cordierite composition correspond to industrial international standards by their technical characteristics and exceed the requirements for heat-insulating and chemically resistant materials by compressive strength.</p>\",\"PeriodicalId\":13903,\"journal\":{\"name\":\"International Journal of Applied Ceramic Technology\",\"volume\":\"21 6\",\"pages\":\"4026-4035\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-06-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Applied Ceramic Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1111/ijac.14826\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Ceramic Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/ijac.14826","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Binary anorthite-cordierite ceramic composite from kaolin and dolomite rock with improved characteristics
Binary CaO-MgO-Al2O3-SiO2 (CMAS) ceramics composites of anorthite-cordierite composition were synthesized from natural raw materials (kaolin and dolomite rock). The change of SiO2/Al2O3 ratio in kaolin/dolomite mixtures (12, 24, and 36 wt.%) and synthesized composites along with analysis of their phase composition transformations (X-ray diffraction) during heat treatment (thermogravimetric and differential thermal analysis) give the controlled design of aluminosilicate matrices. The obtained ceramic composites are represented by anorthite, a cordierite-like phase whose ratio varies from 1.3:1 to 2.8:1. Mullite crystals, also included in the composition, reinforce the anorthite-cordierite matrix. The morphostructural features of the samples were studied using optical and scanning electron microscopy. The porosity ranges from 7.8% to 24.2% depending on dolomite content. The impurities of iron and titanium interfering with obtaining a qualitative product are leveled by the presented technique including the heat treatment scheme justified by thermogravimetric analysis. Obtained CMAS-ceramics of anorthite-cordierite composition correspond to industrial international standards by their technical characteristics and exceed the requirements for heat-insulating and chemically resistant materials by compressive strength.
期刊介绍:
The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas:
Nanotechnology applications;
Ceramic Armor;
Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors);
Ceramic Matrix Composites;
Functional Materials;
Thermal and Environmental Barrier Coatings;
Bioceramic Applications;
Green Manufacturing;
Ceramic Processing;
Glass Technology;
Fiber optics;
Ceramics in Environmental Applications;
Ceramics in Electronic, Photonic and Magnetic Applications;