制备用于超级电容器电极的铜掺杂石墨烯氧化物-谷氨酰胺纳米复合材料:实验与理论研究

IF 4.7 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-06-12 DOI:10.1021/acsaelm.4c00224
Samira Mohammadi,  and , Seyed Morteza Mousavi-Khoshdel*, 
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引用次数: 0

摘要

本研究利用氧化石墨烯(GO)、谷氨酰胺(G)和铜(II)纳米粒子制备了一种纳米复合材料。然后,利用 X 射线衍射、傅立叶变换红外线、拉曼光谱、扫描电子显微镜和能量色散 X 射线等多种技术对制备的纳米复合材料进行了检测,结果表明成功制备了所需的结构。此外,还利用三电极系统测量了电化学特性。在电流密度为 3 A g-1 的 1 M H2SO4 水电解质中,掺铜氧化石墨烯-谷氨酰胺纳米复合材料(Cu/G-GO)的比电容为 1838 F g-1。此外,在 20 A g-1 条件下循环 5000 次后,电极初始电容的 85.43% 得以保留(循环 10000 次,73.12%)。此外,还利用密度泛函理论计算了 GO 和 G-GO 的量子电容和层间距。
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Preparation of a Cu-Doped Graphene Oxide–Glutamine Nanocomposite for Supercapacitor Electrode Applications: An Experimental and Theoretical Study

In this study, using graphene oxide (GO), glutamine (G), and Cu(II) nanoparticles, a nanocomposite was prepared. Then, the prepared nanocomposite was checked out by various techniques such as X-ray diffraction, Fourier transform infrared, Raman spectrum, scanning electron microscopy, and energy-dispersive X-ray, and the results showed that the desired structure was successfully prepared. Also, a three-electrode system was utilized to measure the electrochemical properties. The specific capacitance of a Cu-doped graphene oxide-glutamine nanocomposite (Cu/G-GO) of 1838 F g–1 was obtained in a 1 M H2SO4 aqueous electrolyte under a current density of 3 A g–1. Moreover, 85.43% of the initial capacitance of the electrode was preserved after 5000 cycles at 20 A g–1 (10,000 cycles, 73.12%). Also, the quantum capacitance and the layer distance of GO and G-GO using density functional theory were calculated.

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来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
期刊介绍: ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric. Indexed/​Abstracted: Web of Science SCIE Scopus CAS INSPEC Portico
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